Abstract: The present invention provides an apparatus and method for measuring carbon (any one or all of TC, TOC, or TIC) in a sample matrix. In an embodiment, a method for measuring carbon in a sample composition is provided. The method comprises providing an apparatus comprising a reaction chamber and a diamond coated electrode, wherein the diamond coated electrode is doped with boron. The apparatus further comprises a detector. In addition, the method comprises contacting the sample composition with the electrode. The method further comprises applying an alternating current to the electrode at a sufficient voltage to produce carbon dioxide. Moreover, the method comprises measuring the amount of carbon dioxide produced.

Abstract: Disclosed are a system and method for regulating flow in an exemplary fluidic device comprising a fluidic stream carrying a transport medium, sample and one or more reagents for analysis and synthesis of reaction products. The flow rate of the fluidic stream is maintained constant by adjusting the flow rate of transport medium to compensate for the introduction of sample and reagents. An embodiment controls the flow rate of transport medium using a pump, a back pressure regulator, and a variable-sized orifice. Single and multiple channel embodiments are disclosed.

Abstract: Disclosed are a system and method for regulating flow in an exemplary fluidic device comprising a fluidic stream carrying a transport medium, sample and one or more reagents for analysis and synthesis of reaction products. The flow rate of the fluidic stream is maintained constant by adjusting the flow rate of transport medium to compensate for the introduction of sample and reagents. An embodiment controls the flow rate of transport medium using a pump, a back pressure regulator, and a variable-sized orifice. Single and multiple channel embodiments are disclosed.

Abstract: The present invention provides an apparatus and method for measuring carbon (any one or all of TC, TOC, or TIC) in a sample matrix. In an embodiment, a method for measuring carbon in a sample composition is provided. The method comprises providing an apparatus comprising a reaction chamber and a diamond coated electrode, wherein the diamond coated electrode is doped with boron. The apparatus further comprises a detector. In addition, the method comprises contacting the sample composition with the electrode. The method further comprises applying an alternating current to the electrode at a sufficient voltage to produce carbon dioxide. Moreover, the method comprises measuring the amount of carbon dioxide produced.

Abstract: This invention relates to nickel-cobalt based alloys comprising the following elements in percent by weight: from about 0.002 to about 0.07 percent carbon, from about 0 to about 0.04 percent boron, from about 0 to about 2.5 percent columbium, from about 12 to about 19 percent chromium, from about 0 to about 6 percent molybdenum, from about 20 to about 35 percent cobalt, from about 0 to about 5 percent aluminum, from about 0 to about 5 percent titanium, from about 0 to about 6 percent tantalum, from about 0 to about 6 percent tungsten, from about 0 to about 2.5 percent vanadium, from about 0 to about 0.06 percent zirconium, and the balance nickel plus incidental impurities, the alloys having a phasial stability number N.sub.v3B less than about 2.60. Furthermore, the alloys have at least one element selected from the group consisting of aluminum, titanium, columbium, tantalum and vanadium. Also, the alloys have at least one element selected from the group consisting of tantalum and tungsten.

Abstract: This invention relates to nickel-cobalt based alloys comprising the following elements in percent by weight: from about 0.002 to about 0.07 percent carbon, from about 0 to about 0.04 percent boron, from about 0 to about 2.5 percent columbium, from about 12 to about 19 percent chromium, from about 0 to about 6 percent molybdenum, from about 20 to about 35 percent cobalt, from about 0 to about 5 percent aluminum, from about 0 to about 5 percent titanium, from about 0 to about 6 percent tantalum, from about 0 to about 6 percent tungsten, from about 0 to about 2.5 percent vanadium, from about 0 to about 0.06 percent zirconium, and the balance nickel plus incidental impurities, the alloys having a phasial stability number N.sub.v3B less than about 2.60. Furthermore, the alloys have at least one element selected from the group consisting of aluminum, titanium, columbium, tantalum and vanadium. Also, the alloys have at least one element selected from the group consisting of tantalum and tungsten.

Abstract: This invention relates to a single crystal casting to be used under high stress, high temperature conditions up to about 2030.degree. F., characterized by an increased resistance to creep under such conditions. The casting is made from a nickel-based superalloy consisting essentially of the following elements in percent by weight: from 6.2 to 6.8 percent rhenium, from 1.8 to 2.5 percent chromium, from 1.5 to 2.5 percent cobalt, from 8 to 9 percent tantalum, from 3.5 to 6 percent tungsten, from 5.5 to 6.1 percent aluminum, from 0.1 to 0.5 percent titanium, from 0.01 to 0.1 percent columbium, from 0.25 to 0.60 percent molybdenum, from 0 to 0.05 percent hafnium, from 0 to 0.04 percent carbon, from 0 to 0.01 percent boron, from 0 to 0.01 percent yttrium, from 0 to 0.01 percent cerium, from 0 to 0.01 percent lanthanum, from 0 to 0.04 percent manganese, from 0 to 0.05 percent silicon, form 0 to 0.01 percent zirconium, from 0 to 0.001 percent sulfur, from 0 to 0.

Abstract: This invention relates to a hot corrosion resistant nickel-based superalloy comprising the following elements in percent by weight: from about 11.5 to about 13.5 percent chromium, from about 5.5 to about 8.5 percent cobalt, from about 0.40 to about 0.55 percent molybdenum, from about 4.5 to about 5.5 percent tungsten, from about 4.5 to about 5.8 percent tantalum, from about 0.05 to about 0.25 percent columbium, from about 3.4 to about 3.8 percent aluminum, from about 4.0 to about 4.4 percent titanium, from about 0.01 to about 0.06 percent hafnium, and the balance nickel plus incidental impurities, the superalloy having a phasial stability number N.sub.V3B less than about 2.45. Single crystal articles can be suitably made from the superalloy of this invention. The article can be a component for a gas turbine engine and, more particularly, the component can be a gas turbine blade or gas turbine vane.

Abstract: This invention relates to nickel-cobalt based alloys comprising the following elements in percent by weight: from about 0.002 to about 0.07 percent carbon, from about 0 to about 0.04 percent boron, from about 0 to about 2.5 percent columbium, from about 12 to about 19 percent chromium, from about 0 to about 6 percent molybdenum, from about 20 to about 35 percent cobalt, from about 0 to about 5 percent aluminum, from about 0 to about 5 percent titanium, from about 0 to about 6 percent tantalum, from about 0 to about 6 percent tungsten, from about 0 to about 2.5 percent vanadium, from about 0 to about 0.06 percent zirconium, and the balance nickel plus incidental impurities, the alloys having a phasial stability number N.sub.v3B less than about 2.60. Furthermore, the alloys have at least one element selected from the group consisting of aluminum, titanium, columbium, tantalum and vanadium. Also, the alloys have at least one element selected from the group consisting of tantalum and tungsten.

Abstract: This invention relates to a nickel-based superalloy comprising the following elements in percent by weight: from about 5.0 to about 7.0 percent rhenium, from about 1.8 to about 4.0 percent chromium, from about 1.5 to about 9.0 percent cobalt, from about 7.0 to about 10.0 percent tantalum, from about 3.5 to about 7.5 percent tungsten, from about 5.0 to about 7.0 percent aluminum, from about 0.1 to about 1.2 percent titanium, from about 0 to about 0.5 percent columbium, from about 0.25 to about 2.0 percent molybdenum, from about 0 to about 0.15 percent hafnium, and the balance nickel+incidental impurities, the superalloy having a phasial stability number N.sub.v3B less than about 2.10.

Abstract: A nickel base superalloy for columnar grain, directional solidification which contains Re for strength and creep resistance, and substantially eliminates the use of Zr and minimizes Si to prevent DS grain boundary cracking. The creep- and stress-rupture properties, which approach nickel base superalloy single crystal performance, are achieved without the use of high temperature gamma prime solution treatment.

Abstract: A single crystal nickel alloy is provided having many of the foundry and performance characteristics of the higher density, single crystal, nickel base super alloys from which the vanes and blades are cast for high performance turbine aircraft engines. The lower density of this alloy permits its use for rebuilding and upgrading the performance of older turbine aircraft engines of designs which cannot withstand the centrifugal forces generated by the new state of the art higher density single crystal super alloys. The alloy for the first time provides a lower density single crystal alloy capable of heat treatment to stabilize its microstructure for high temperature, high stress use. It also provides for the first time a lower density alloy having acceptable resistance to the effects of high temperature sulfidation, salt corrosion and also to have good coating life.

Abstract: Single crystal nickel-base superalloy having very fine gamma prime after heat treatment in a temperature range permitting total gamma prime solutioning without incipient melting. Component of the heat treated alloy has exceptional resistance to creep under high temperature and stress, particularly in that part of the creep curve representing one percent or less elongation. The alloy exhibits exceptionally low steady-state creep rate.

Abstract: The alloy is a nickel base, superalloy specifically intended for the making of castings which consist of a single crystal. The castings are intended for use under extreme conditions of high temperature and stress. The alloy, for the first time, achieves the desired characteristics of phase stability, high stress-rupture strength and resistance to oxidation while maintaining a sufficient temperature differential between gamma prime solvus and incipient melting temperatures, that it is practical to solution heat treat without unacceptable percentages of rejects due to failure either to completely solution the primary coarse gamma prime or to initiation of incipient melting. In a modified form the coated oxidation/corrosion resistance of the alloy is increased by the addition of a trace quantity of hafnium.