Abstract: Provided herein are manufacturing processes that include (1) subjecting precursor-containing solids to dissolution under acoustic perturbation to yield an initial slurry including dissolved precursors; (2) subjecting the initial slurry to hydrothermal synthesis to yield a subsequent slurry including siliceous solids formed from the dissolved precursors; and (3) subjecting the subsequent slurry to cementation to yield a cemented siliceous solid. Also provided herein are cemented siliceous solids formed by the manufacturing processes.

Abstract: A manufacturing method includes: (1) incorporating at least one soluble, calcium, magnesium, or other divalent cation-containing additive into a concrete mixture including aggregates prone to alkali-silica reaction; and (2) curing the concrete mixture to form a concrete product.

Abstract: A manufacturing process of a concrete product includes: (1) extracting calcium from solids as portlandite; (2) forming a cementitious slurry including the portlandite; (3) shaping the cementitious slurry into a structural component; and (4) exposing the structural component to carbon dioxide sourced from a flue gas stream, thereby forming the concrete product.

Abstract: Provided herein are methods of removing carbon dioxide from an aqueous stream or gaseous stream by: contacting the gaseous stream comprising carbon dioxide, when present, with an aqueous solution comprising ions capable of forming an insoluble carbonate salt; contacting the aqueous solution comprising carbon dioxide with an electroactive mesh that induces its alkalinization thereby forcing the precipitation of a carbonate solid from the solution and thereby the removal of dissolved inorganic carbon by electrolysis; and removing the precipitated carbonate solids from the solution, or the surface of the mesh where they may deposit. Also provided herein are flow-through electrolytic reactors comprising an intake device in fluid connection with a rotating cylinder comprising an electroactive mesh, and a scraping device and/or liquid-spray based device for separating a solid from the mesh surface.

Abstract: A manufacturing process of a cement product includes: (a) reacting at least one anhydrous or hydrated cement component with liquid or supercritical CO2 to form a cement composition; and (b) curing the cement composition to form a cement product.

Abstract: A method includes: (1) using a chelating agent, extracting divalent ions from a brine solution as complexes of the chelating agent and the divalent ions; (2) using a weak acid, regenerating the chelating agent and producing a divalent ion salt solution; and (3) introducing carbon dioxide to the divalent ion salt solution to induce precipitation of the divalent ions as a carbonate salt. Another method includes: (1) combining water with carbon dioxide to produce a carbon dioxide solution; (2) introducing an ion exchanger to the carbon dioxide solution to induce exchange of alkali metal cations included in the ion exchanger with protons included in the carbon dioxide solution and to produce a bicarbonate salt solution of the alkali metal cations; and (3) introducing a brine solution to the bicarbonate salt solution to induce precipitation of divalent ions from the brine solution as a carbonate salt.

Abstract: A method includes: (1) using a chelating agent, extracting divalent ions from a brine solution as complexes of the chelating agent and the divalent ions; (2) using a weak acid, regenerating the chelating agent and producing a divalent ion salt solution; and (3) introducing carbon dioxide to the divalent ion salt solution to induce precipitation of the divalent ions as a carbonate salt. Another method includes: (1) combining water with carbon dioxide to produce a carbon dioxide solution; (2) introducing an ion exchanger to the carbon dioxide solution to induce exchange of alkali metal cations included in the ion exchanger with protons included in the carbon dioxide solution and to produce a bicarbonate salt solution of the alkali metal cations; and (3) introducing a brine solution to the bicarbonate salt solution to induce precipitation of divalent ions from the brine solution as a carbonate salt.

Abstract: A manufacturing process of a cement product includes: (a) reacting at least one anhydrous or hydrated cement component with liquid or supercritical CO2 to form a cement composition; and (b) curing the cement composition to form a cement product.

Abstract: Provided herein are compositions and methods of carbonation processing for the fabrication of cementitious materials and concrete products. Embodiments include manufacturing processes of a low-carbon concrete product comprising: forming a cementitious slurry including portlandite; shaping the cementitious slurry into a structural component; and exposing the structural component to a CO2 waste stream, thereby enabling manufacture of the low-carbon concrete product.

Abstract: A method includes: (1) using a chelating agent, extracting divalent ions from a brine solution as complexes of the chelating agent and the divalent ions; (2) using a weak acid, regenerating the chelating agent and producing a divalent ion salt solution; and (3) introducing carbon dioxide to the divalent ion salt solution to induce precipitation of the divalent ions as a carbonate salt. Another method includes: (1) combining water with carbon dioxide to produce a carbon dioxide solution; (2) introducing an ion exchanger to the carbon dioxide solution to induce exchange of alkali metal cations included in the ion exchanger with protons included in the carbon dioxide solution and to produce a bicarbonate salt solution of the alkali metal cations; and (3) introducing a brine solution to the bicarbonate salt solution to induce precipitation of divalent ions from the brine solution as a carbonate salt.

Abstract: A manufacturing process of a concrete product includes: (1) extracting calcium from solids as portlandite; (2) forming a cementitious slurry including the portlandite; (3) shaping the cementitious slurry into a structural component; and (4) exposing the structural component to carbon dioxide sourced from a flue gas stream, thereby forming the concrete product.

Abstract: A manufacturing process of a cement product includes: (a) reacting at least one anhydrous or hydrated cement component with liquid or supercritical CO2 to form a cement composition; and (b) curing the cement composition to form a cement product.

Abstract: A manufacturing process of a cement product includes: (1) incorporating at least one additive into a high-alumina cement composition, wherein the at least one additive is selected from nitrate-containing salts, nitrite-containing salts, carbonate-containing salts, sulfate-containing salts, chloride-containing salts, and hydroxide-containing salts; and (2) curing the high-alumina cement composition to form the cement product.

Abstract: Provided herein is a cementitious composition comprising a photoactivator, wherein the photoactivator is capable of converting NOx to NO2— or NO3— when exposed to ultraviolet (U.V.) or visible light.

Abstract: A manufacturing process of a cement product includes: (1) incorporating at least one additive into a high-alumina cement composition, wherein the at least one additive is selected from nitrate-containing salts, nitrite-containing salts, carbonate-containing salts, sulfate-containing salts, chloride-containing salts, and hydroxide-containing salts; and (2) curing the high-alumina cement composition to form the cement product.

Abstract: A manufacturing process of a “low cement content” concrete includes: (1) forming a cementitious mixture by combining a cement, a carbonate source, and an aluminous source; and (2) curing the cementitious mixture to form the concrete. The carbonate source is included in an amount greater than 20% by weight of solids combined in the cementitious mixture.

Abstract: A mechanical property of a cementitious mixture is predicted by: (1) receiving user input characterizing a mixture of a cement and a mineral addition, the user input corresponding to at least one of: (a) a size characteristic of the cement; (b) a size characteristic of the mineral addition; and (c) a replacement level of the cement by the mineral addition in the mixture; (2) based on the user input, deriving a predicted cumulated heat released by the mixture through hydration for a reaction time period; and (3) based on the predicted cumulated heat released, deriving a predicted mechanical property of the mixture at an age corresponding to the reaction time period.

Abstract: Provided herein is a cementitious composition comprising a photoactivator, wherein the photoactivator is capable of converting NOx to NO2— or NO3— when exposed to ultraviolet (U.V.) or visible light.

Abstract: Provided herein are compositions comprising concrete and one or more phase change materials (PCMs) for prevention or reduction of thermal damage in a cementitious system, and uses thereof.