Abstract: A method for synthesising polyepichlorohydrin including: a) reacting epichlorohydrin with boron trifluoroetherate in the presence of a polymerisation initiator; b) adding a good solvent for epichlorohydrin to the reaction product obtained in step a); c) adding epichlorohydrin to the reaction product obtained in step b).

Abstract: A method for synthesising polyepichlorohydrin includes: a) reacting epichlorohydrin with boron trifluoroetherate in the presence of a solvent; b) adding epichlorohydrin to the reaction product obtained in step a); c) hydrolysing the product obtained in step b).

Abstract: The present invention relates to a sequential one-pot synthesis of TKX-50, suitable for larger-scale production, during which an acetyl halide is used during the cyclization of diazidoglyoxime so as to obtain 1,1?-diacetyl-5,5?-bistetrazole, which is then hydrolyzed to 5,5?-bistetrazole-1,1?-diolate, to which compound a hydroxylammonium salt is subsequently added.

Abstract: A subject-matter of the present invention is a novel process for the synthesis of hexanitrohexaazaisowurtzitane (HNIW), a compound of use as energetic filler in powders, propellants and explosives. This process comprises a first stage of reaction of an ?,?-dicarbonyl derivative with a primary amine which makes it possible to form a hexasubstituted hexaazaisowurtzitane derivative. The HNIW is subsequently obtained directly, in a single reaction stage, by nitration of the hexasubstituted hexaazaisowurtzitane derivative. This process, in only 2 stages starting from a primary amine, is particularly simple and inexpensive.