Patents by Inventor Genki Yoshikawa

Genki Yoshikawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11879863
    Abstract: The present invention provides a method for analyzing a liquid sample that solves a problem of a kinetically slow equilibrium at a liquid-solid interface, the problem occurring when liquid sample analysis is performed with a chemical sensor. In the method for analyzing a liquid sample according to an embodiment of the present invention, a component to be analyzed in a liquid sample is adsorbed on a receptor layer of a chemical sensor, one or more kinds of gases are then supplied to the chemical sensor, and a response thereof is measured. As a result, since a slow equilibrium at a liquid-solid interface is not used, a high-sensitivity measurement can be performed in a short time, and existing findings regarding analysis of gas samples on which much progress in research has been achieved can be used.
    Type: Grant
    Filed: November 13, 2019
    Date of Patent: January 23, 2024
    Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kosuke Minami, Genki Yoshikawa
  • Patent number: 11796408
    Abstract: A method for cleaning a receptor layer of a surface stress sensor according to an embodiment of the present invention includes, in a surface stress sensor that detects a change in surface stress of a thin film, the change being caused by a receptor layer disposed on a surface of the thin film, causing at least a part of a surface region of the thin film to generate heat or supplying heat to the receptor layer from the outside of the surface stress sensor. This makes it possible to easily perform efficient cleaning of a surface stress sensor such as a sensor that performs detection using a piezoresistor while avoiding structural complications as much as possible.
    Type: Grant
    Filed: August 28, 2019
    Date of Patent: October 24, 2023
    Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Genki Yoshikawa, Takahiro Nemoto, Makito Nakatsu, Naoto Takeda, Kota Shiba, Kosuke Minami
  • Patent number: 11774346
    Abstract: In an analysis of a fluid component using a nanomechanical sensor covered with a receptor, the same receptor is caused to express different response characteristics. In a measuring system of analyzing a response when a sample gas and a purge gas are supplied to a nanomechanical sensor while switching the sample gas and the purge gas, a gas (external gas) different from both gases is mixed into a gas channel and supplied to the sensor for measurement. Since a response characteristic of a receptor is modulated by mixing of the external gas, the object described above is achieved.
    Type: Grant
    Filed: June 4, 2019
    Date of Patent: October 3, 2023
    Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kosuke Minami, Gaku Imamura, Kota Shiba, Genki Yoshikawa
  • Publication number: 20230273183
    Abstract: An object of the present invention is to make it possible to easily determine a presence or absence of ketosis and/or the possibility of ketosis in an animal on site or the like. Another object of the present invention is to provide an apparatus for performing the determination. A method for determining ketosis according to one embodiment of the present invention includes providing gas detection means with a gas generated from a body fluid collected from an animal (except for humans), and determining ketosis of the animal based on a composition of the gas generated from the body fluid using a response of the gas detection means to the gas generated from the body fluid.
    Type: Application
    Filed: July 12, 2021
    Publication date: August 31, 2023
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Ryoh NAKAKUBO, Mitsuyoshi ISHIDA, Genki YOSHIKAWA, Kosuke MINAMI, Gaku IMAMURA, Hideki MATSUZAKA, Takahiro NEMOTO
  • Publication number: 20230147626
    Abstract: An object of the present invention is to make it possible to easily evaluate silage fermentation quality on site or the like. In one embodiment of the present invention, a gas generated from silage is applied to a surface stress sensor, and the amount of either one of organic acids and nitrogen-containing compounds contained in the silage is determined. The surface stress sensor can detect trace components in a gas by a simple device configuration and in simple procedures. Therefore, by utilizing the fact that relationship between the content of these components and the fermentation quality is known, the evaluation of fermentation quality can be easily realized by the above measurement.
    Type: Application
    Filed: March 19, 2021
    Publication date: May 11, 2023
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Ryo NAKAKUBO, Mitsuyoshi ISHIDA, Masanori TOHNO, Hisami KOBAYASHI, Genki YOSHIKAWA, Kosuke MINAMI, Gaku IMAMURA, Hideki MATSUZAKA, Takahiro NEMOTO
  • Publication number: 20230090065
    Abstract: The present invention makes it possible to represent or synthesize any odor by separating the odor into a combination of a relatively small number of odors, similarly to separating a color into three primary colors. Since the “primary odors” corresponding to the primary colors have not yet been ascertained, the present invention provides a feasible method and apparatus in which, instead of presetting such fixed primary odors, the separation, synthesis, and the like can be performed by selecting a subset of odors from among a set consisting of a plurality of odors which subset or odors enables approximation of other odors as much as possible by mixture.
    Type: Application
    Filed: March 5, 2021
    Publication date: March 23, 2023
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Ryo TAMURA, Hanxiao XU, Koki KITAI, Kosuke MINAMI, Makito NAKATSU, Genki YOSHIKAWA, Kota SHIBA, Koji TSUDA
  • Publication number: 20220291185
    Abstract: An object of the present invention is to detect ammonia with high sensitivity and high selectivity using a nanomechanical sensor with a structure that is as simple as possible. A method for detecting ammonia according to an embodiment of the present invention comprises supplying a sample gas possibly containing ammonia to a nanomechanical sensor that detects a stress or a displacement using poly(methyl vinyl ether-alt-maleic anhydride) as a material of a receptor layer, and detecting presence or absence of ammonia or a content of ammonia in the sample gas based on an output signal from the nanomechanical sensor, in which the sample gas is a humidified sample gas with controlled relative humidity.
    Type: Application
    Filed: May 8, 2020
    Publication date: September 15, 2022
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Gaku IMAMURA, Kosuke MINAMI, Kota SHIBA, Genki YOSHIKAWA
  • Patent number: 11442051
    Abstract: Provided is a novel analysis method which, when a chemical sensor is used to perform a measurement, makes it possible to identify a sample without controlling or monitoring a change in the time the sample is introduced. According to the present invention, a sample can be identified without knowing a change in the time the sample is introduced, by using a chemical sensor having a plurality of channels each having different characteristics to perform a measurement, and performing an analysis on the basis of responses obtained from each channel.
    Type: Grant
    Filed: February 16, 2018
    Date of Patent: September 13, 2022
    Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Gaku Imamura, Genki Yoshikawa, Takashi Washio
  • Publication number: 20220260540
    Abstract: The present invention suppresses an adverse effect caused when an additional gas such as water vapor is mixed in a sample gas or the like that is subjected to gas measurement. In an embodiment of the present invention, in gas measurement for analyzing sensor output signals obtained by alternately supplying a sample gas and a reference gas to a sensor element while alternately switching between the sample gas and the reference gas, the sample gas and the reference gas pass through a humidity equilibration device partitioned by a water vapor permeable membrane, and then are supplied to the sensor element. As a result, since both gases have substantially the same value of humidity at the time of being supplied to the sensor element, influences of water vapor are substantially cancelled out in signals output from the sensor element by the alternate supply of the sample gas and the reference gas.
    Type: Application
    Filed: June 17, 2020
    Publication date: August 18, 2022
    Inventors: Genki YOSHIKAWA, Takahiro NEMOTO, Masaaki MATOBA, Kosuke MINAMI
  • Publication number: 20220228971
    Abstract: The present invention provides a nanomechanical sensor unsusceptible to water vapor, due to very low sensitivity to water vapor, that may interfere with measurement. In an embodiment of the present invention, as a sensitive film material of a nanomechanical sensor such as a surface stress sensor, poly(2,6-diphenyl-p-phenylene oxide) is utilized that is used for adsorption/concentration of a substance present in a trace amount in water or air, and represented by Formula (1) wherein n represents an integer of 1 or more. As can be seen from graphs showing changes over time of response signals in a case where a gas to be measured containing acetone, ethanol, and the like and nitrogen are alternately supplied to the surface stress sensor cyclically, it was confirmed that in the sensitive film of the present invention, adsorption/desorption of the components in the gas to be measured significantly occurs in response to the cyclic change, but the sensitivity to water is very low.
    Type: Application
    Filed: April 14, 2020
    Publication date: July 21, 2022
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Genki YOSHIKAWA, Kota SHIBA
  • Patent number: 11391687
    Abstract: The invention provides: a gas sensor device that is capable of removing a component adsorbed on a gas sensor by relatively simple means and easily restoring a signal baseline of the gas sensor to a constant state; and a method for removing a gas component. The gas sensor device according to an embodiment of the invention includes a gas sensor and cleaning means that contains a liquid for cleaning the gas sensor. The gas sensor includes a sensor main body that is capable of detecting a characteristic parameter of a component present in a gas phase or a liquid phase, and a sensitive membrane that is coated on a surface of the sensor main body and is durable against the liquid.
    Type: Grant
    Filed: October 24, 2017
    Date of Patent: July 19, 2022
    Assignees: NATIONAL INSTITUTE FOR MATERIALS SCIENCE, KYOCERA CORPORATION
    Inventors: Genki Yoshikawa, Kota Shiba, Gaku Imamura, Takanori Yasuda, Kyohei Kobayashi, Hisashi Sakai
  • Patent number: 11353437
    Abstract: Provided is a novel analysis method that enables identification of a sample even when any sample is introduced during measurement carried out by using a chemical sensor. An input in which the amount of an unknown sample changes over time is provided to the chemical sensor, a response which is from the chemical sensor and which changes over time is measured, a sensor function (transmission function) of the chemical sensor with respect to the unknown sample is calculated on the basis of the input and the response, and the unknown sample is identified on the basis of the sensor function of the chemical sensor with respect to the unknown sample.
    Type: Grant
    Filed: November 22, 2017
    Date of Patent: June 7, 2022
    Assignee: National Institute for Materials Science
    Inventors: Gaku Imamura, Genki Yoshikawa, Takashi Washio
  • Publication number: 20220057372
    Abstract: The present invention provides a hydrogen sensor having a high sensitivity and low hysteresis characteristics while having a simple configuration and low cost. The present invention shows that a membrane-type surface stress sensor having an amorphous palladium-copper-silicon alloy as a sensitive film has low hysteresis and can detect a nitrogen gas to which hydrogen at a very low concentration of 0.25 ppm is added and a pure nitrogen gas with a sufficiently high S/N ratio.
    Type: Application
    Filed: February 14, 2020
    Publication date: February 24, 2022
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Taro YAKABE, Gaku IMAMURA, Genki YOSHIKAWA, Akiko NAKAMURA
  • Patent number: 11215585
    Abstract: The present invention provides a nanomechanical sensor in which a negative influence of water in a sample on measurement is suppressed. In an embodiment of the present invention, as a receptor material of the nanomechanical sensor, a low-hygroscopic material such as polysulfone, polycaprolactone, poly(vinylidene fluoride), or poly(4-methylstyrene) is used. According to this embodiment, a negative influence, such as saturation of a receptor layer by water in the sample, or masking of an output signal based on trace components by an output signal based on water contained in the sample in a large amount, can be suppressed.
    Type: Grant
    Filed: May 21, 2018
    Date of Patent: January 4, 2022
    Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kota Shiba, Kosuke Minami, Genki Yoshikawa
  • Publication number: 20210396699
    Abstract: The present invention provides a method for analyzing a liquid sample that solves a problem of a kinetically slow equilibrium at a liquid-solid interface, the problem occurring when liquid sample analysis is performed with a chemical sensor. In the method for analyzing a liquid sample according to an embodiment of the present invention, a component to be analyzed in a liquid sample is adsorbed on a receptor layer of a chemical sensor, one or more kinds of gases are then supplied to the chemical sensor, and a response thereof is measured. As a result, since a slow equilibrium at a liquid-solid interface is not used, a high-sensitivity measurement can be performed in a short time, and existing findings regarding analysis of gas samples on which much progress in research has been achieved can be used.
    Type: Application
    Filed: November 13, 2019
    Publication date: December 23, 2021
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kosuke MINAMI, Genki YOSHIKAWA
  • Publication number: 20210277546
    Abstract: A multilayer textile for a sandwich structure includes skins made of a fiber-reinforced resin and a core that is sandwiched by the skins. Skin portions are each configured by a warp and a weft both made of a reinforcement fiber. A core portion is configured by a warp and a weft both made of a fiber that is insoluble in a matrix resin of the skins and has a smaller specific gravity than the reinforcement fiber. The skin portions and the core portion are integrated by a binding yarn that is insoluble in the matrix resin of the skins.
    Type: Application
    Filed: June 29, 2017
    Publication date: September 9, 2021
    Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventor: Genki YOSHIKAWA
  • Publication number: 20210215556
    Abstract: A method for cleaning a receptor layer of a surface stress sensor according to an embodiment of the present invention includes, in a surface stress sensor that detects a change in surface stress of a thin film, the change being caused by a receptor layer disposed on a surface of the thin film, causing at least a part of a surface region of the thin film to generate heat or supplying heat to the receptor layer from the outside of the surface stress sensor. This makes it possible to easily perform efficient cleaning of a surface stress sensor such as a sensor that performs detection using a piezoresistor while avoiding structural complications as much as possible.
    Type: Application
    Filed: August 28, 2019
    Publication date: July 15, 2021
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Genki YOSHIKAWA, Takahiro NEMOTO, Makito NAKATSU, Naoto TAKEDA, Kota SHIBA, Kosuke MINAMI
  • Publication number: 20210199563
    Abstract: In an analysis of a fluid component using a nanomechanical sensor covered with a receptor, the same receptor is caused to express different response characteristics. In a measuring system of analyzing a response when a sample gas and a purge gas are supplied to a nanomechanical sensor while switching the sample gas and the purge gas, a gas (external gas) different from both gases is mixed into a gas channel and supplied to the sensor for measurement. Since a response characteristic of a receptor is modulated by mixing of the external gas, the object described above is achieved.
    Type: Application
    Filed: June 4, 2019
    Publication date: July 1, 2021
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kosuke MINAMI, Gaku IMAMURA, Kota SHIBA, Genki YOSHIKAWA
  • Publication number: 20210190655
    Abstract: Provided is a novel material analysis technique using a chemical sensor. By reversing the conventional approach, a material to be measured is provided as a receptor of the chemical sensor, and a response signal of the chemical sensor obtained by supplying a known gas or the like to the chemical sensor is obtained. From the response signal, it is possible to identify and distinguish the receptor material, and to obtain its composition and the like. By analyzing the response signal by means of a statistical or machine learning technique such as principal component analysis, linear discriminant analysis, or a support vector machine, the above-mentioned identification and the like can be performed with high accuracy.
    Type: Application
    Filed: June 4, 2019
    Publication date: June 24, 2021
    Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kosuke MINAMI, Genki YOSHIKAWA, Gaku IMAMURA, Kota SHIBA
  • Patent number: 10947647
    Abstract: A fabric laminate used as a reinforcing base material of a fiber-reinforced composite is constituted by laminating fabrics having warp yarns and weft yarns. Each warp yarn has a diameter-changing portion, in which the diameter of the yarn gradually changes in the yarn longitudinal direction in the vicinity of one end in the yarn longitudinal direction of the warp yarn.
    Type: Grant
    Filed: December 8, 2016
    Date of Patent: March 16, 2021
    Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Genki Yoshikawa, Ryuta Kamiya, Shun Kuno