Abstract: The present invention provides a method of forming a metal coating having a microstructure as well as a structural member having a metal coating formed by the method. In particular, the invention provides an advantageous method of forming a metal coating in which minute carbides are uniformly dispersed. The method of forming the metal coating of the present invention includes the steps of cladding a surface of the substrate with metal powder by a laser cladding method and forming the metal coating having a microstructure by applying a friction stir processing to the cladded region.

Abstract: Provided are a method of modifying a cemented carbide and a cemented carbide modified by the method. Particularly provided is an advantageous method of modifying a cemented carbide layer formed by a thermal spraying method on a surface of a metal substrate. The method of modifying a cemented carbide includes applying a friction stir process to a cemented carbide, thereby allowing crystal grains in a binder phase included in the cemented carbide to become finer. It is possible to achieve modification effectively by applying the friction stir process particularly to a cemented carbide layer formed on a surface of a metal substrate by using the thermal spraying method.

Abstract: This invention relates to a method of producing a corrosion-, heat- and wear-resistant member which comprises packing an atomized powder of a high-carbon high-chromium steel into a capsule, heating the capsule packed with the powder, then extruding the capsule packed with the powder to obtain a stock not containing carbide grains greater than 3 .mu.m, working the stock, polishing a surface of the stock, and evaporating a film of TiC and/or TiN onto the polished surface, and further a corrosion-, heat- and wear-resistant member produced by the method. The corrosion-, heat- and wear-resistant member according to this invention is suitable for being members for tools used under extremely severe conditions, such as various tools for can manufacturing, molding tools for reinforced plastics, etc.