Abstract: A nanostructured metal oxide composition comprising hydroxides or oxygen vacancies or both hydroxides and oxygen vacancies on its surface is described. A process for preparing the nanostructured metal oxide composition comprising hydroxides or oxygen vacancies or both hydroxides and oxygen vacancies on its surface, which hydroxides and oxygen vacancies can participate in chemical reactions, which composition is prepared by a method selected from the group of methods comprising: i) controlled thermally induced dehydroxylation of nanostructured metal hydroxide precursors; ii) thermochemical reaction of said nanostructured metal oxide with hydrogen gas; iii) vacuum thermal treatment of said nanostructured metal oxide; and iv) aliovalent doping with a lower oxidation state metal.

Abstract: A nanostructured metal oxide composition comprising hydroxides or oxygen vacancies or both hydroxides and oxygen vacancies on its surface is described. A process for preparing the nanostructured metal oxide composition comprising hydroxides or oxygen vacancies or both hydroxides and oxygen vacancies on its surface, which hydroxides and oxygen vacancies can participate in chemical reactions, which composition is prepared by a method selected from the group of methods comprising: i) controlled thermally induced dehydroxylation of nanostructured metal hydroxide precursors; ii) thermochemical reaction of said nanostructured metal oxide with hydrogen gas; iii) vacuum thermal treatment of said nanostructured metal oxide; and iv) aliovalent doping with a lower oxidation state metal.

Abstract: The present disclosure provides methods, systems and devices for a photonic crystal combinatorial sensor. The photonic crystal sensor may include an array of photonic crystal materials, wherein each photonic crystal material has a reflected wavelength in a respective initial wavelength range. At least one a first one of the photonic crystal materials may be configured to have a response to an external stimulus different from at least a second one of the photonic crystal materials, the different response resulting in a change in the reflected wavelength of the first photonic crystal material that is an optically detectable difference from the second photonic crystal material. The optically detectable difference may provide an optically detectable response pattern of reflected wavelengths in the array. The sensor may be reversible and reusable.

Abstract: A nanostructured metal oxide composition comprising hydroxides or oxygen vacancies or both hydroxides and oxygen vacancies on its surface is described. A process for preparing the nanostructured metal oxide composition comprising hydroxides or oxygen vacancies or both hydroxides and oxygen vacancies on its surface, which hydroxides and oxygen vacancies can participate in chemical reactions, which composition is prepared by a method selected from the group of methods comprising: i) controlled thermally induced dehydroxylation of nanostructured metal hydroxide precursors; ii) thermochemical reaction of said nanostructured metal oxide with hydrogen gas; iii) vacuum thermal treatment of said nanostructured metal oxide; and iv) aliovalent doping with a lower oxidation state metal.

Abstract: A photoactive material including nanoparticles of photoactive first and second constituents. The first and second constituents have respective conduction band energies, valence band energies and electronic band gap energies to enable photon-driven generation and separation of charge carriers in each of the first and second constituents by absorption of light in the solar spectrum. The first and second constituents are provided in an alternating layered arrangement of respective first and second layers or are mixed together in a single layer. The nanoparticles have diameters smaller than wavelengths of light in the solar spectrum, to provide optical transparency for absorption of light. The charge carriers, upon photoactivation, are able to participate in redox reactions occurring in the photoactive material. The photoactive material may enable redox reactions of carbon dioxide with at least one of hydrogen and water to produce a fuel.

Abstract: The present disclosure provides methods, systems and devices for a photonic crystal combinatorial sensor. The photonic crystal sensor may include an array of photonic crystal materials, wherein each photonic crystal material has a reflected wavelength in a respective initial wavelength range. At least one a first one of the photonic crystal materials may be configured to have a response to an external stimulus different from at least a second one of the photonic crystal materials, the different response resulting in a change in the reflected wavelength of the first photonic crystal material that is an optically detectable difference from the second photonic crystal material. The optically detectable difference may provide an optically detectable response pattern of reflected wavelengths in the array. The sensor may be reversible and reusable.

Abstract: A photonic crystal incandescent light source comprising: a photonic crystal having a structure configured to reflect wavelengths from at least a portion of an infrared spectrum; and an incandescent central filament in the photonic crystal, causing the photonic crystal to transmit wavelengths from at least a portion of a visible spectrum; wherein the light source emits at least a portion of visible wavelengths and suppresses emission of at least a portion of infrared wavelengths.

Abstract: The invention relates to a process for producing photonic crystals by first providing an inorganic photoresist which, on illumination with energy greater than the electronic band gap of the photoresist, exhibits a phase alteration. Illumination of the photoresist with a laser beam whose energy is lower than the electronic band gap of the photoresist but whose intensity at the focal point is so high that nonlinear effects occur there nevertheless results in a phase alteration in the photoresist. Thereafter, the illuminated photoresist is exposed to an etching solution which preferentially dissolves one phase of the photoresist, and the developed photoresist is finally removed therefrom as a photonic crystal. Inorganic photonic crystals produced by the process according to the invention are suitable for completely optical systems, circuits and components for optical telecommunication or computer systems.

Abstract: The present invention provides a method to control the degree of connectivity of the colloidal particles making up a colloidal crystal and, consequently, the pore size, filling fraction, mechanical stability and optical properties of the colloidal lattice, without disrupting its long range order and without the deleterious effects of lattice contraction induced cracking observed in conventional necking methods based on thermal sintering. The colloidal particles are connected to adjacent colloidal particles in the lattice by a homogeneous layer of uniform and controllable thickness of a metal oxide. This metal oxide layer is grown in a layer-by-layer process and is chemically bonded to the colloidal particle surface and serves to enhance the mechanical stability of the colloidal crystal in addition to acting to control the pore size or void volume between the colloidal particles in the lattice.

Abstract: Method of synthesis of photonic band gap (PBG) materials. The synthesis and characterization of high quality, very large scale, face centered cubic photonic band gap (PBG) materials consisting of pure silicon, exhibiting a complete three dimensional PBG centered on a wavelength of 1.5 ?m. This is obtained by chemical vapor deposition and anchoring of disilane into a self-assembling silica opal template, wetting of a thick silicon layer on the interior surfaces of the template, and subsequent removal of the template. This achievement realizes a long standing goal in photonic materials and opens a new door for complete control of radiative emission from atoms and molecules, light localization and the integration of micron scale photonic devices into a three-dimensional all-optical micro-chip.

Abstract: The invention relates to a process for producing photonic crystals by first providing an inorganic photoresist which, on illumination with energy greater than the electronic band gap of the photoresist, exhibits a phase alteration. Illumination of the photoresist with a laser beam whose energy is lower than the electronic band gap of the photoresist but whose intensity at the focal point is so high that nonlinear effects occur there nevertheless results in a phase alteration in the photoresist. Thereafter, the illuminated photoresist is exposed to an etching solution which preferentially dissolves one phase of the photoresist, and the developed photoresist is finally removed therefrom as a photonic crystal. Inorganic photonic crystals produced by the process according to the invention are suitable for completely optical systems, circuits and components for optical telecommunication or computer systems.

Abstract: The invention relates to a process for producing a three-dimensional photonic crystal which consists of a material with high refractive index. To this end, a photonic crystal which consists of a polymer is first provided, through whose surface there are empty interstitial sites. As a result of introduction of a filler into the interstitial sites, a network forms there from the filler. After the removal of the polymer, cavities form in the network formed from the filler, into which the material with high refractive index is introduced, so that a structure of the material with high refractive index forms therein. After the removal of the filler, the structure of the material with high refractive index remains, which can be removed as the photonic crystal which consists of a material with high refractive index. Photonic crystals produced by the process according to the invention have complete band gaps in the region of telecommunications wavelengths.

Abstract: The present invention provides a template-directed self-assembly strategy to integrate the class of materials called dendrimers with periodic mesoporous and macroporous silica materials to create two totally new classes of organic/inorganic nanocomposite materials, which we call periodic mesoporous dendrisilicas (PMeDs) and periodic macroporous dendrisilicas (PMaDs). The unusual combination of inorganic silica and organic dendrimer chemical structures with these scales of porosity and surfaces suggests a myriad of uses for PMeDs and PMaDs, such as the controlled release and uptake of chemicals, chiral separations and catalysis, electronic printing and microelectronic packaging, biomaterial platforms, chromatography stationary phase, and photonic crystal applications. These applications target the synergistic relationship between the dendrimer and the meso- or macroporous structure within a single hierarchical nanostructured organic/inorganic hybrid material.

Abstract: This invention describes methods of synthesis and applications of planarized photonic crystals. Provided are simple, quick, reproducible and inexpensive methods that combine self-assembly and lithography to achieve the first examples of vectorial control of thickness, structure, area, topology, orientation and registry of colloidal crystals that have been patterned in substrates for use in lab-on-chip and photonic chip technologies. 1-, 2 and 3-D colloidal crystals patterned either on or within substrates can be used for templating inverted colloidal crystal replica patterns made of materials like silicon as well as building micron scale structural defects in such colloidal crystals.

Abstract: The present invention discloses a method whereby laser microwriting is used to microanneal an amorphous silicon phase to a nanocrystalline silicon phase in silicon photonic crystals, films, fibers or surface patterns to enable the precise definition of a pre-determined refractive index contrast pattern in spatially designated regions of amorphous silicon photonic crystals, films, fibers or surface patterns in a rapid and straightforward fashion. At the micrometer length scale of the silicon photonic lattice the method can be used to create extrinsic defects in silicon photonic crystals, films, fibers or surface patterns, exemplified but not limited to points, lines and bends for localizing, guiding and bending light.

Abstract: The invention described herein is broadly directed to 3D photonic crystal fibers exemplified but not limited to novel 3D inverse colloidal crystal fibers made of silicon. In particular the invention relates to the general utilization of controlled size and controlled shape and controlled length microchannel surface relief patterns that have been lithographically defined in silicon substrates for the geometrically confined crystallization of silica microspheres to form highly ordered and oriented colloidal photonic crystal microchannel templates and the utilization of such templates for creating, through silicon infiltration synthetic strategies, colloidal silicon-silica photonic crystal composite materials thereof and the subsequent removal of the silica template and detachment of these colloidal silicon-silica photonic crystal composite materials from the silicon substrate by etching in a fluoride-based medium to create oriented free standing 3D inverse colloidal photonic crystal fibers.

Abstract: A new type of synthetic silicon colloidal photonic colloidal crystal is described presenting a different topology than previously synthesised high refractive index contrast colloidal photonic crystals. It has been built using a new synthesis process based upon micromolding in inverse silica opals (MISO), where the micromold has a structure of interconnected air cavities in a silica matrix. By chemical vapour deposition of disilane within this micromold, a continuous and uniform silicon layer of controlled thickness is formed, which coats the walls of the silica matrix. Later, by dissolution of the starting silica micromold it is possible to obtain a face centered cubic silicon colloidal photonic crystal with a topology never observed before and which presents a full photonic band gap, as indicated by theoretical photonic band structure calculations making them useful as optical components of envisioned all-optical microphotonic crystal devices, circuits, chips and computers.

Abstract: The present invention provides a straightforward and robust synthetic process for producing a chromatographic column with eluent-sensitive light diffracting properties based on an inherent photonic band structure and a chromatographic device using the chromatographic column. The present invention provides chromatographic devices employing a chromatographic column which in one embodiment is a photonic colloidal crystal which includes an assembly of colloidal microspheres assembled into a highly ordered array within a housing such as a tube with the highly ordered array being a photonic crystal along the length of the crystal, and a second embodiment which is an inverse construct of the first embodiment, where solid microspheres making up the photonic colloidal crystal chromatographic column are replaced with spherical voids or void spaces subsequent to infiltration of a material of selected refractive index.

Abstract: A functionalized porous crystalline material is disclosed exhibiting an X-ray diffraction pattern with at least one peak at a position greater than about 1.8 nm d-spacing with a relative intensity of 100. The crystalline material comprises a framework including metal atoms, oxygen atoms and at least one organic group bonded between at least two of said metal atoms so as to be integral with said framework, and wherein said organic group has at least one sulfonate moiety bonded thereto.

Abstract: A functionalized porous crystalline material is disclosed exhibiting an X-ray diffraction pattern with at least one peak at a position greater than about 1.8 nm d-spacing with a relative intensity of 100. The crystalline material comprises a framework including metal atoms, oxygen atoms and at least one organic group bonded between at least two of said metal atoms so as to be integral with said framework, and wherein said organic group has at least one sulfonate moiety bonded thereto.