Abstract: The effluent stream from the treatment of glass with vapor-phase coating materials contains tin residues. By washing that effluent stream, in an apparatus having a scrubber bed and flow-control and -recycling means, with an acidic solution having a limited concentration of the tin residue, recovery efficiency of the post-coating treatment is improved, and process emissions are reduced.

Abstract: A hood for coating glass articles has side walls and a top part, forming a tunnel through which hot glass articles pass; blowing and suction channels in the active part of the hood are formed to present substantial line contacts facing the ware being coated. By introducing relatively large radiating surfaces, the buildup of reaction-product crust on the interior of the apparatus is minimized.

Abstract: A coating applicator is provided for depositing a film on a surface of glass or other substrates by chemical-vapor deposition. The applicator includes a pair of opposing coating nozzles for applying a vaporized coating-chemical reactant in a carrier gas to the surface at such a concentration and velocity that coating of the surface is achieved under substantially reaction-rate-controlled conditions. Each coating nozzle is positioned adjacent the surface with a small clearance therebetween, the clearance being open to the outside atmospehre. The opposing coating nozzles are directed toward each other at a selected angle with respect to the surface of the substrate. The angle and the clearance provide a condition where there is substantially no intermixing of coating vapors with the outside atmosphere.

Abstract: A coating applicator is provided for depositing a film on a surface of glass and other substrates by chemical vapor deposition. The applicator includes a pair of opposing coating nozzles for applying a vaporized coating chemical reactant in a carrier gas to the surface at such a concentration and velocity that coating of the surface is achieved under substantially reaction rate controlled conditions. Each coating nozzle is positioned adjacent the surface with a small clearance therebetween which is open to the outside atmosphere. The opposing coating nozzles are directed toward each other at a selected angle with respect to a normal to the surface of the substrate. The angle and the clearance provides a condition where there is substantially no intermixing of coating vapors with the outside atmosphere.

Abstract: A submersible positive displacement piston pump includes a cylinder for insertion within a body of liquid, the cylinder including a working end and an opposite end, an inlet port, an outlet port and a working chamber bounded by the outlet port and the working end; a piston rotatably and reciprocably movable in the cylinder between a retracted positon and an extended position for pumping liquid from the inlet port to the outlet port, the piston including a free end having a recessed section alternately in fluid communication with the inlet port and the outlet port; a pivoting assembly pivotally connected to a drive motor which rotatably and reciprocably drives the piston in the cylinder; and an extension assembly for connecting the pivoting assembly to the piston and for ensuring that the pivoting assembly and the drive motor are positioned out of the body of liquid when the piston and cylinder are positioned in the body of liquid, the extension assembly including a shaft extension for connecting the pivoting

Abstract: Haze-free tin oxide coatings are made from an organotin compound which ordinarily gives only hazy coatings. The improvement comprises first forming an undercoat of a haze-free tin oxide film on a substrate, preferably by decomposition of monophenyltin trichloride. Thereafter the tin oxide overcoating assumes the haze-free characteristics of the undercoat film.

Abstract: Improved nebulizable coating compositions for making high quality, fluorine-doped tin oxide coatings having a low sheet resistance and high visible light transmission includes a mixture of less than 95 wt. % of monobutyltin trichloride, less than 50 wt. % of an inorganic fluorine dopant, which is ammonium fluoride, ammonium bifluoride or dibutyltin difluoride, and the rest is a mixture of solvents.

Abstract: A tin oxide coated article characterized by including a transparent, haze-free tin oxide coating on a substrate, such as glass. The tin oxide coating is formed by deposition from a liquid coating composition including an organotin compound, such as an alkyltin trichloride, and a haze-reducing additive, such as a fluorocarboxylic acid or acid anhydride.

Abstract: Transparent, non-iridescent, infrared-reflecting glass window structures which are haze-free are provided herein. These structures comprise a glass sheet, an infrared-reflecting tin oxide coating on one major surface of the sheet, and an iridescence-reducing tin oxide coating on the opposed major surface of the sheet. The iridescence-reducing tin oxide coating is particularly characterized by being haze-free by virtue of its being made by contacting said sheet with monophenyltin trichloride in an oxygen-containing atmosphere.

Abstract: An improved liquid coating composition for producing high quality, high performance fluorine-doped tin oxide coatings by chemical vapor deposition includes the reaction product of a reactive fluorine dopant compound and an organotin compound, preferably 1-30 wt. % of the fluorine dopant and 70-99 wt. % of the organotin compound. The preferred liquid coating composition includes the reaction product of trifluoroacetic acid and monobutyltin trichloride.

Abstract: This invention relates to organotin compounds containing fluorine which are particularly useful for forming fluorine-doped tin oxide coatings by the chemical vapor deposition method. In the preferred embodiment, the compound is monobutyldichlorotin trifluoroacetate, which is prepared by reaction of monobutyltin trichloride and trifluoroacetic acid.

Abstract: Apparatus for coating an optical fiber with a metal oxide coating material in vapor form, includes a coating chamber through which the fiber moves, the coating chamber including an inlet supplied with the coating material in vapor form, a circumferential passage for supplying the coating material to the fiber, a flow restriction passage in fluid communication between the inlet and the circumferential passage for supplying the coating material from the inlet to the circumferential passage, the flow restriction passage including a tortuous circumferential path through a plurality of circumferentially arranged orifices and a through a narrow gap, and an oil jacket containing heated oil surrounding the walls of the coating chamber for heating the same; an evaporator for supplying the coating material in vapor form to the inlet; and a heating assembly for supplying heated air to the evaporator to entrain the coating material and for supplying heated oil to the evaporator for heating the coating material and to the

Abstract: A coating hood for applying protective coatings to glass containers, includes a pair of spaced side walls; a supply of vaporized or atomized coating chemical in a carrier gas; a conveyor for transporting the glass containers to be coated longitudinally through the coating hood; a hood ceiling with a plurality of openings positioned at the level of the container finishes for supplying coating free air across the finish of the containers; the openings on one side of the containers are offset in the longitudinal direction of the hood with respect to the openings on the other side of the containers; each opening supplying an envelope of the coating free air across the finish of the containers such that lateral boundaries of the envelope of each opening on one side of the containers are substantially coincident with lateral boundaries of the envelopes of the offset and laterally adjacent openings on the other side of the containers; and a blower for supplying the coating free air to the openings.

Abstract: A liquid coating composition for producing high quality, high performance fluorine-doped tin oxide coatings by chemical vapor deposition includes 1-30 wt. % of a reactive fluorine dopant compound and 70-99 wt. % of an organotin compound.

Abstract: Transparent, haze-free tin oxide coatings on glass are obtained by chemical vapor deposition of liquid monophenyltin trichloride. The method includes the steps of vaporizing liquid monophenyltin trichloride and contacting the vapor in an oxidizing atmosphere with a substrate at an elevated substrate temperature, preferably about 450.degree. to 600.degree. C. The tin oxide coating on glass produced by this method has a haze which is less than 1%, and is substantially equal to the haze value for uncoated glass.

Abstract: A positive displacement pump utilizes at least three driven displacer valves and a plurality of driving membranes and at least one pumping membrane to withdraw minute quantities of corrosive fluid from a drum and discharge same from a spray nozzle. The pump is submerged within the fluid to be pumped and is driven by a remotely positioned pneumatic pulse generator comprising pneumatic logic circuitry. The driven displacer valves operate in a particular sequence to draw fluid into the pump body, advance same from pumping chamber to pumping chamber within the pump body, and then discharge same at a constant rate of discrete pulses through an outlet port. The pulse generator and logic circuitry provide the control pulses for operating the displacer valves at the proper times in the operational cycle. The delivery characteristics of the instant pump far exceed the performance capabilities of conventional pumps utilized for similar purposes.

Abstract: The invention relates to a stabilized composition for coating glass containers, and to its method of use. The method involves the steps of heating the surface of a glass container to at least 800.degree. F., and spraying the surface of the glass with a glass coating formulation comprising monoalkyltin trihalide and about 0.5 to 10 parts by weight per hundred parts monoalkyltin trihalide of a solubilizing material.

Abstract: An air-operated diaphragm pump assembly for withdrawing small volumes of liquid from a receptacle until the receptacle is almost completely emptied. The pump assembly includes a diaphragm pump that is submerged within the liquid in one receptacle, an extension sleeve extending upwardly from the pump to a position above the receptacle, fluid logic circuitry to operate the pump, inlet conduit(s) passing through the sleeve to transmit control pulses to the pump, and outlet conduit(s) passing through the sleeve to discharge the liquid forced out of the pump in response to the control pulses. The fluid logic circuitry includes a pneumatic Schmitt-Trigger that is operatively associated with a pneumatic inverter. The diaphragm pump includes a pumping diaphragm and a driving diaphragm, the diaphragms being coupled together to drive a displacer within a pumping chamber in response to a pressure differential to thereby expel the liquid contained therein.

Abstract: A coating hood adapted to uniformly apply protective coatings to the exterior of hot glass containers is disclosed. The hood comprises a tunnel for allowing the containers to pass therethrough, and an adjustable top for accommodating containers of various sizes. At least two jet slots are located in each side wall, and at least two receiver slots in the opposite side wall are aligned therewith. The jet slots and the suction slots are interspersed opposite to each other in each side wall. The coating compound is introduced through at least one feedpoint, and blowers secured to the side walls furnish high velocity air containing the coating compound. Baffles are situated in the flow path of the high velocity air so that the jets issuing from the jet slots are well defined. Two or more closed recirculating loops are defined by the judicious selection of blowers, jet slots and receivers.

Abstract: A positive displacement piston pump includes a cylinder having a working end, an inlet port, an outlet port and a working chamber bounded by the outlet port and the working end; a piston rotatably and reciprocably movable in the cylinder between a retracted position and an extended position, the piston including a free end having a recessed section alternately in fluid communication with the inlet port and the outlet port; a drive motor rotatably and reciprocably driving the piston in the cylinder; a yoke and ball and socket joint pivotally connecting the piston to the drive motor; a base having an upper surface with an elongated slot below the pivot point of the piston and an arcuate slot adjacent the opposite end of the cylinder; and first and second pivot pins secured to a swivel plate which is, in turn, secured to the cylinder through a vertical column, whereby the recessed section is positioned entirely in the working chamber when the piston is at the end of its pressure stroke, regardless of the angle b