Patents by Inventor Georg Krolla

Georg Krolla has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7072562
    Abstract: The stepped optical fiber has a core glass member and a surrounding cladding glass member. It has a high numerical aperture (NA)?0.50. The core glass member preferably has a zinc-containing composition including, in % by weight, SiO2, 42 to 53; ZnO, 16 to 38; PbO, 1 to 20; Na2O, <14; K2O, <12; with a sum of ZnO and PbO?30 and a sum of Na2O and K2O is ?2. The cladding glass composition, which is compatible with this core glass, includes, in percent by weight, SiO2, 60 to 72; B2O3, <20; Al2O3, <10; Na2O, <18; and K2O, <15. The resulting optical fiber has low attenuation, very neutral color transmission and low manufacturing costs. Other cladding glass compositions resulted in considerably poorer properties with too much crystallization at the core glass boundary layer. Environmentally-friendly, lead-free embodiments of the core glass were also prepared having even lower aperture values of ?0.48.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: July 4, 2006
    Assignee: Schott Glas
    Inventors: Ralf Domres, Norbert Wolfram Gehenn, Uwe Kolberg, Georg Krolla, Frank Thomas Lentes
  • Publication number: 20050100305
    Abstract: The stepped optical fiber has a core glass member and a surrounding cladding glass member. It has a high numerical aperture (NA)?0.50. The core glass member preferably has a zinc-containing composition including, in % by weight, SiO2, 42 to 53; ZnO, 16 to 38; PbO, 1 to 20; Na2O, <14; K2O, <12; with a sum of ZnO and PbO?30 and a sum of Na2O and K2O is ?2. The cladding glass composition, which is compatible with this core glass, includes, in percent by weight, SiO2, 60 to 72; B2O3, <20; Al2O3, <10; Na2O, <18; and K2O, <15. The resulting optical fiber has low attenuation, very neutral color transmission and low manufacturing costs. Other cladding glass compositions resulted in considerably poorer properties with too much crystallization at the core glass boundary layer. Environmentally-friendly, lead-free embodiments of the core glass were also prepared having even lower aperture values of ?0.48.
    Type: Application
    Filed: September 30, 2003
    Publication date: May 12, 2005
    Inventors: Ralf Domres, Norbert Gehenn, Uwe Kolberg, Georg Krolla, Frank Lentes
  • Patent number: 6393868
    Abstract: The present invention relates to a novel process for the production of sequences of interference layers composed of layers i of prescribed thicknesses d(i) and refractive indices n(i). In this process a stack of at least two layers i of glasses having refractive indices n(i) and thicknesses d0(i), which are each larger than the predetermined thicknesses d(i) by the same multiplying factor, is provided. The stack is heated to a temperature above the transformation temperature of the glasses and during or after heating, the stack is drawn in such a manner that the individual layers obtain the prescribed thicknesses d(i). After this the drawn stack is cooled.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: May 28, 2002
    Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
    Inventors: Manfred Krauss, Hans-Georg Krolla, Eckart Hussmann, Bernhard R. Durschang, Gerd Muller
  • Patent number: 5446008
    Abstract: A transparent or translucent inorganic material, especially a glass-ceramic and/or composite material, is provided with a low average thermal longitudinal expansion coefficient, .alpha., of from -1.times.10.sup.-6 K.sup.-1 to +2.times.10.sup.-6 K.sup.-1 in the temperature range of -50.degree.-700.degree. C., with the following composition (in weight percent):Li.sub.2 O, 2.5-6.0; Na.sub.2 O, 0-4.0; K.sub.2 O, 0-4.0; Na.sub.2 O+K.sub.2 O, 0.2-4.0; MgO, 0-3.0; ZnO, 0-3.0; BaO, 0-3.5; CaO, 0-1.0; SrO, 0-1.0; Al.sub.2 O.sub.3, 18-28; SiO.sub.2, 50-70; TiO.sub.2, 1.0-7.0; ZrO.sub.2, 0-3.5; TiO.sub.2 +ZrO.sub.2, 1.0-7.0; and P.sub.2 O.sub.5, 0-8.0,optionally with coloring components (in weight percent):V.sub.2 O.sub.5, 0-2.0; Cr.sub.2 O.sub.3, 0-2.0; MnO, 0-2.0; Fe.sub.2 O.sub.3, 0-2.0; CoO, 0-2.0; and NiO, 0-2.0,optionally, conventional refining agents, such as As.sub.2 O.sub.3, Sb.sub.2 O.sub.3, NaCl, and Ce.sub.2 O.sub.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: August 29, 1995
    Assignee: Schott Glaswerke
    Inventors: Georg Krolla, Paul Kissl, Peter Nass, Kurt Schaupert
  • Patent number: 4719186
    Abstract: An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability of chemical hardening, comprises (in % by weight):______________________________________ SiO.sub.2 50-63 B.sub.2 O.sub.3 4-8 Al.sub.2 O.sub.3 1-2 Li.sub.2 O 4-8 Na.sub.2 O 4-8 K.sub.2 O 3-7 sum of M.sub.2 O 11-20 (M = Li, Na, K) MgO 0.5-2 CaO 2-5 sum of MO 0-3 (M = Mg, Ca) TiO.sub.2 8-12.5 ZrO.sub.2 1-3 F.sup.- 0-1 As.sub.2 O.sub.3 0.05-0.15 (optional refining agent) Sb.sub.2 O.sub.3 0.0-0.
    Type: Grant
    Filed: April 16, 1986
    Date of Patent: January 12, 1988
    Assignee: Schott Glaswerke
    Inventors: Karl Mennemann, Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
  • Patent number: 4704371
    Abstract: Infrared-transparent bi- or multicomponent chalcogenide glasses based on germanium and selenium are improved by doping with 0.05 to 1.0 atom % of at least one of the alkaline earth metals calcium or strontium and/or one of their compounds. Optical fibers and optical elements can be made from these glasses.
    Type: Grant
    Filed: September 26, 1986
    Date of Patent: November 3, 1987
    Assignee: Schott Glaswerke
    Inventors: Hans-Georg Krolla, Magdalena Winkler-Trudewig, Werner Schumann
  • Patent number: 4566987
    Abstract: A colorless, cerium-and phosphorous-containing barium silicate glass, with a density of >3.3 g/cm.sup.2, a radiation length <43.5 mm, with strong fluorescence at 415-430 nm and with good scintillation properties, consisting essentially of (in percent by weight):______________________________________ SiO.sub.2 20-60 B.sub.2 O.sub.3 0-18 21-60 P.sub.2 O.sub.5 1-10 Li.sub.2 O 0-10 Na.sub.2 O 0-10 K.sub.2 O 0-15 MgO 0-10 SrO 0-12 BaO 30-60 30-60 La.sub.2 O.sub.3 0-10 Ce.sub.2 O.sub.3 0.5-8 Other oxides 0-20 Al.sub.2 O.sub.
    Type: Grant
    Filed: June 16, 1983
    Date of Patent: January 28, 1986
    Assignee: Schott-Glaswerke
    Inventors: Georg Gliemeroth, Burkhard Speit, Hans-Georg Krolla
  • Patent number: 4562161
    Abstract: An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability for chemical hardening, comprises (in % by weight):SiO.sub.2 --47 to 75B.sub.2 O.sub.3 --1 to 20Al.sub.2 O.sub.3 --0 to 10P.sub.2 O.sub.5 --0 to 5Li.sub.2 O--0 to 15Na.sub.2 O--0 to 10K.sub.2 O--0 to 10CaO--0 to 20MgO--0 to 15SrO--0 to 4BaO--0 to 4ZnO--0 to 5TiO.sub.2 --1 to 15ZrO.sub.2 --0 to 8Nb.sub.2 O.sub.5 --0 to 5 andF----0 to 5.
    Type: Grant
    Filed: February 18, 1983
    Date of Patent: December 31, 1985
    Assignee: Schott Glaswerke
    Inventors: Karl Mennemann, Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
  • Patent number: 4508834
    Abstract: A spectacle glass which is colorless in the visible spectrum range, not transmissive in the ultraviolet spectrum range below 350 nm, has a refractive index n.sub.d higher than 1.56 and an Abbe number of more than 45, and which has an extremely low density, has the following composition (in % by weight):______________________________________ 12-40 P.sub.2 O.sub.5 13-34 Al.sub.2 O.sub.3 8-30 SiO.sub.2 0-16 B.sub.2 O.sub.3 4-12 TiO.sub.2 0-4 ZrO.sub.2 2-18 CaO 0-4 MgO 0-15 Na.sub.2 O 0-11 K.sub.2 O 0-6 Li.sub.2 O 0-12 Nb.sub.2 O.sub.5 0-8 ZnO.
    Type: Grant
    Filed: February 10, 1983
    Date of Patent: April 2, 1985
    Assignee: Schott Glaswerke
    Inventors: Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
  • Patent number: 4485178
    Abstract: A new phototropic glass in which the phototropic properties arise from precipitations of silver halide and which in the unirradiated condition is slightly tinted or completely colorless while showing a brown color in the light-exposed condition, comprises, in known phototropic glass compositions, an additional content of at least 0.001 wt % of TeO.sub.2 and/or Yb.sub.2 O.sub.3.
    Type: Grant
    Filed: May 31, 1983
    Date of Patent: November 27, 1984
    Assignee: Schott-Glaswerke
    Inventors: Georg Gliemeroth, Uwe Eichhorn, Eva Holzel, Ludwig Ross, Hans-Georg Krolla, Burkhard Speit, Volkmar Geiler, Hans-Jurgen Hoffmann
  • Patent number: 4225459
    Abstract: Glass composition ranges are described which permit the introduction of laser activators into fluorphosphate glass with exceptionally high fluorine content while forming glasses of high crystallization stability and permitting the realization of large melt volumes. The high fluorine content imparts to the glasses an exceptionally low nonlinear refractive index n.sub.2 down to O,4 .times.10.sup.-13 esu.
    Type: Grant
    Filed: April 18, 1978
    Date of Patent: September 30, 1980
    Assignee: JENAer Glaswerk Schott & Gen.
    Inventors: Marga Faulstich, Walter Jahn, Georg Krolla, Norbert Neuroth
  • Patent number: 4099834
    Abstract: A glass when in the form of an optical fiber having an optical loss of not more than 150 dB/km, high transparency, a high numerical aperture, and a high flexural strength, said glass being especially suitable for optical fibers and consisting essentially of:SiO.sub.2 : 65 - 75 mol-%; (38 - 46% by weight);R.sub.2 o: 4 - 17 mol-%; (4 - 13% by weight);PbO: 16 - 25 mol-%; (42 - 55% by weight); wherein R.sub.2 O is Na.sub.2 O, K.sub.2 O or Cs.sub.2 O or mixtures thereof, preferably not more than 3.0 mol % Na.sub.2 O, and with the provision that the molar ratio of SiO.sub.2 : PbO is 2.5 - 4.0.
    Type: Grant
    Filed: November 25, 1974
    Date of Patent: July 11, 1978
    Assignee: Jenaer Glaswerk Schott & Gen.
    Inventors: Marga Faulstich, Norbert Neuroth, Franz Reitmayer, Georg Krolla
  • Patent number: 3960578
    Abstract: Arsenic pentoxide glasses characterized by containing 8 - 60 wt.% arsenic pentoxide and correspondingly 92 - 40 wt.% polyvalent metal fluorides exhibit improved processing characteristics while maintaining outstanding optical properties when prepared from a formula containing at least 0.5% of at least one member selected from the group consisting of bromides, chlorides, sulfates and metal oxides.
    Type: Grant
    Filed: January 19, 1973
    Date of Patent: June 1, 1976
    Assignee: Jenaer Glaswerk Schott & Gen.
    Inventor: Georg Krolla