Patents by Inventor George E. Vogtlin

George E. Vogtlin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20040045285
    Abstract: A high-surface-area (greater than 600 m2/g), large-pore (pore size greater than 6.5 angstroms), basic zeolite having a structure such as an alkali metal cation-exchanged Y-zeolite is employed to convert NOx contained in an oxygen-rich exhaust to N2 and ON2. Preferably, the invention relates to a two-stage method and apparatus for NOx reduction in an oxygen-rich engine exhaust that includes a plasma oxidative stage and a selective reduction stage. The first stage employs a non-thermal plasma treatment of NOx gases in an oxygen-rich exhaust and is intended to convert NO to NO2 in the presence of O2 and added hydrocarbons. The second stage employs a lean-NOx catalyst including the basic zeolite at relatively low temperatures to convert such NO2 to environmentally benign gases that include N2, CO2, and H2O.
    Type: Application
    Filed: September 10, 2003
    Publication date: March 11, 2004
    Applicant: The Regents of the University of California
    Inventors: Bernardino M. Penetrante, Raymond M. Brusasco, Bernard T. Merritt, George E. Vogtlin
  • Patent number: 6685897
    Abstract: A high-surface-area (greater than 600 m2/g), large-pore (pore size diameter greater than 6.5 angstroms), basic zeolite having a structure such as an alkali metal cation-exchanged Y-zeolite is employed to convert NOx contained in an oxygen-rich engine exhaust to N2 and O2. Preferably, the invention relates to a two-stage method and apparatus for NOx reduction in an oxygen-rich engine exhaust such as diesel engine exhaust that includes a plasma oxidative stage and a selective reduction stage. The first stage employs a non-thermal plasma treatment of NOx gases in an oxygen-rich exhaust and is intended to convert NO to NO2 in the presence of O2 and added hydrocarbons. The second stage employs a lean-NOx catalyst including the basic zeolite at relatively low temperatures to convert such NO2 to environmentally benign gases that include N2, CO2, and H2O.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: February 3, 2004
    Assignee: The Regents of the University of California
    Inventors: Bernardino M. Penetrante, Raymond M. Brusasco, Bernard T. Merritt, George E. Vogtlin
  • Patent number: 6374595
    Abstract: A two-stage method for NOx reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NOx gases in an oxygen-rich exhaust and is intended to convert NO to NO2 in the presence of O2 and hydrocarbons. The second stage employs a lean NOx trap to convert such NO2 to environmentally benign gases that include N2, CO2, and H2O. By preconverting NO to NO2 in the first stage with a plasma, the efficiency of the second stage for NOx reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO2 in the presence of O2 and hydrocarbons, such as propene. A flow of such hydrocarbons (CxHy) is input from usually a second pipe into at least a portion of the first chamber.
    Type: Grant
    Filed: January 25, 2000
    Date of Patent: April 23, 2002
    Assignee: The Regents of the University of California
    Inventors: Bernardino M. Penetrante, George E. Vogtlin, Bernard T. Merritt, Raymond M. Brusasco
  • Patent number: 6202407
    Abstract: Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NOx to N2 in the presence of a catalyst. Exhaust NOx reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NOx species removed.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: March 20, 2001
    Assignee: The Regents of the University of California
    Inventors: Raymond M. Brusasco, Bernardino M. Penetrante, George E. Vogtlin, Bernard T. Merritt
  • Patent number: 6119451
    Abstract: Hydrocarbons, such as diesel fuel, are added to internal combustion engine exhaust to reduce exhaust NO.sub.x in the presence of a amphoteric catalyst support material. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbons.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: September 19, 2000
    Assignee: Regents of the University of California
    Inventors: George E. Vogtlin, David A. Goerz, Mark Hsiao, Bernard T. Merritt, Bernie M. Penetrante, John G. Reynolds, Ray Brusasco
  • Patent number: 6038854
    Abstract: A non-catalytic two-stage process for removal of NO.sub.x and particulates from engine exhaust comprises a first stage that plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, and a second stage, which preferably occurs simultaneously with the first stage, that converts NO.sub.2 and carbon soot particles to respective environmentally benign gases that include N.sub.2 and CO.sub.2. By preconverting NO to NO.sub.2 in the first stage, the efficiency of the second stage for NO.sub.x reduction is enhanced while carbon soot from trapped particulates is simultaneously converted to CO.sub.2 when reacting with the NO.sub.2 (that converts to N.sub.2). For example, an internal combustion engine exhaust is connected by a pipe to a chamber where carbon-containing particulates are electrostatically trapped or filtered and a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. Volatile hydrocarbons (C.sub.x H.sub.
    Type: Grant
    Filed: July 22, 1998
    Date of Patent: March 21, 2000
    Assignee: The Regents of the University of California
    Inventors: Bernardino M. Penetrante, George E. Vogtlin, Bernard T. Merritt, Raymond M. Brusasco
  • Patent number: 6038853
    Abstract: A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.
    Type: Grant
    Filed: July 15, 1998
    Date of Patent: March 21, 2000
    Assignee: The Regents of the University of California
    Inventors: Bernardino M. Penetrante, George E. Vogtlin, Bernard T. Merritt, Raymond M. Brusasco
  • Patent number: 5893267
    Abstract: Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO.sub.x reduction in oxygen-rich vehicle engine exhausts.
    Type: Grant
    Filed: August 5, 1997
    Date of Patent: April 13, 1999
    Assignee: The Regents of the University of California
    Inventors: George E. Vogtlin, Bernard T. Merritt, Mark C. Hsiao, P. Henrik Wallman, Bernardino M. Penetrante
  • Patent number: 5891409
    Abstract: A two-stage catalyst comprises an oxidative first stage and a reductive second stage. The first stage is intended to convert NO to NO.sub.2 in the presence of O.sub.2. The second stage serves to convert NO.sub.2 to environmentally benign gases that include N2, CO2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber. An oxidizing first catalyst converts NO to NO.sub.2 in the presence of O.sub.2 and includes platinum/alumina, e.g., Pt/Al.sub.2 O.sub.3 catalyst. A flow of hydrocarbons (C.sub.x H.sub.y) is input from a pipe into a second chamber. For example, propene can be used as a source of hydrocarbons. The NO.sub.2 from the first catalyst mixes with the hydrocarbons in the second chamber. The mixture proceeds to a second reduction catalyst that converts NO.sub.2 to N2, CO2, and H.sub.2 O, and includes a gamma-alumina .gamma.-Al.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: April 6, 1999
    Assignee: The Regents of the University of California
    Inventors: Mark C. Hsiao, Bernard T. Merritt, Bernardino M. Penetrante, George E. Vogtlin
  • Patent number: 5731538
    Abstract: A slapper detonator comprises a solid-state high-voltage capacitor, a low-jitter dielectric breakdown switch and trigger circuitry, a detonator transmission line, an exploding foil bridge, and a flier material. All these components are fabricated in a single solid-state device using thin film deposition techniques.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: March 24, 1998
    Assignee: The Regents of the University of California
    Inventors: Dennis W. O'Brien, Robert L. Druce, Gary W. Johnson, George E. Vogtlin, Troy W. Barbee, Jr., Ronald S. Lee
  • Patent number: 5715677
    Abstract: Reduction of NO.sub.x from diesel engine exhaust by use of plasma-regenerated absorbent beds. This involves a process for the reduction of NO.sub.x and particulates from diesel engines by first absorbing NO.sub.x onto a solid absorbent bed that simultaneously acts as a physical trap for the particulate matter, and second regenerating said solid absorbent by pulsed plasma decomposition of absorbed NO.sub.x followed by air oxidation of trapped particulate matter. The absorbent bed may utilize all metal oxides, but the capacity and the kinetics of absorption and desorption vary between different materials, and thus the composition of the absorbent bed is preferably a material which enables the combination of NO.sub.x absorption capability with catalytic activity for oxidation of hydrocarbons. Thus, naturally occurring or synthetically prepared materials may be utilized, particularly those having NO.sub.x absorption properties up to temperatures around 400.degree. C.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: February 10, 1998
    Assignee: The Regents Of The University Of California
    Inventors: P. Henrik Wallman, George E. Vogtlin
  • Patent number: 5711147
    Abstract: Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO.sub.x reduction in oxygen-rich vehicle engine exhausts.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: January 27, 1998
    Assignee: The Regents of the University of California
    Inventors: George E. Vogtlin, Bernard T. Merritt, Mark C. Hsiao, P. Henrik Wallman, Bernardino M. Penetrante