Abstract: A silicate optical fiber comprises a graded index silicate core co-doped with aluminum oxide, phosphorus oxide, germanium oxide and fluorine in unique compositions that we have discovered allow multimode, multi-wavelength operation without significant intermodal dispersion. Illustratively, the core comprises a multiplicity of compositions whose refractive indices are graded from a maximum at or near the center of the core to a minimum at the interface with the cladding. Each core composition resides within a sub-volume of a 5 dimensional phase space in which an optimum core profile shape is essentially constant over the wavelength range of operation of the fiber. For operation in the wavelength range of about 0.78 ?m to 1.55 ?m, each composition preferably comprises no more than approximately 6 mole % Al2O3, 9 mole % P2O5, 6 mole % GeO2, 6 mole % F, and 90-100 mole % SiO2.

Abstract: The present invention provides a method of preparing preforms for optical fibers. The invention allows one to remove or significantly reduce undesirable refractive index variations in the central portion of the optical fibers. The method of preparing the preform having a central duct includes the steps of a first collapsing step, an etching step and a second collapsing step. The first collapsing step reduces the size of the central duct without closing the central duct by heating the preform at a first preform collapsing temperature. A portion of the last deposited layer of the core glass layers is etched by flowing an etchant gas through the central duct at a lower temperature than the preform collapsing temperature. The preform is finally collapsed at a second collapsing temperature to close the central duct of the preform and form a solid rod.