Patents by Inventor George J. Hirasaki

George J. Hirasaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11933932
    Abstract: This invention is useful for determining the permeability of a geological formation using 1H NMR diffusion measurements acquired in the laboratory and using downhole 1H NMR well logging. The current technology for obtaining formation permeability downhole using NMR is not adequate for low-permeability, unconventional source rock formations with high organic content. This new method uses laboratory 1H NMR diffusion measurements for creating continuous downhole well logs of the mobile-hydrocarbon permeability of the hydrocarbon-filled pore space of downhole geological formations.
    Type: Grant
    Filed: April 6, 2021
    Date of Patent: March 19, 2024
    Assignee: VINEGAR TECHNOLOGIES LLC
    Inventors: Harold J. Vinegar, Philip M. Singer, George J. Hirasaki, Zeliang Chen, Xinglin Wang, Eva Vinegar
  • Patent number: 11921069
    Abstract: The following invention is used for determining the relative permeability of a fluid in a rock for three different phases: water, oil, and gas, in both conventional and unconventional formations. The permeability of a phase describes how much it can flow in porous media given a pressure gradient and is useful in evaluating reservoir quality and productivity. The following invention is a method to determine the three-phase relative permeabilities in both conventional and unconventional formations using NMR restricted diffusion measurements on core with NMR-active nuclei, combined with centrifugation of the core. In addition, the tortuosity, pore size (surface-to-volume ratio), fluid-filled porosity, and permeability is determined for each of the three phases in a rock.
    Type: Grant
    Filed: April 6, 2021
    Date of Patent: March 5, 2024
    Assignee: Vinegar Technologies LLC
    Inventors: Eva Vinegar, Philip M. Singer, George J. Hirasaki, Zeliang Chen, Xinglin Wang, Harold J. Vinegar
  • Patent number: 11099292
    Abstract: New methods for determining the volumetric composition and saturation of methane and NGLs (natural gas liquids: ethane, propane, butane, and pentane) in a petroleum reservoir combining NMR (nuclear magnetic resonance) logging and NMR core analysis and for determining the mean pore-size and tortuosity of the light hydrocarbon-filled porosity in a petroleum reservoir using NMR core analysis.
    Type: Grant
    Filed: April 8, 2020
    Date of Patent: August 24, 2021
    Assignee: Vinegar Technologies LLC
    Inventors: Harold J. Vinegar, Philip M. Singer, George J. Hirasaki, Zeliang Chen, Xinglin Wang
  • Patent number: 9377449
    Abstract: Various embodiments of the present disclosure pertain to nanocomposites for detecting hydrocarbons in a geological structure. In some embodiments, the nanocomposites include: a core particle; a polymer associated with the core particle; a sulfur-based moiety associated with the polymer; and a releasable probe molecule associated with the core particle, where the releasable probe molecule is releasable from the core particle upon exposure to hydrocarbons. Additional embodiments of the present disclosure pertain to methods of detecting hydrocarbons in a geological structure by utilizing the nanocomposites of the present disclosure.
    Type: Grant
    Filed: March 25, 2013
    Date of Patent: June 28, 2016
    Assignee: WILLIAM MARSH RICE UNIVERSITY
    Inventors: James M. Tour, Chih-Chau Hwang, Wei Lu, Gedeng Ruan, Mason B. Tomson, Amy Kan, Lu Wang, Michael S. Wong, Gautam Kini, George J. Hirasaki, Clarence Miller
  • Publication number: 20150050741
    Abstract: Various embodiments of the present disclosure pertain to nanocomposites for detecting hydrocarbons in a geological structure. In some embodiments, the nanocomposites include: a core particle; a polymer associated with the core particle; a sulfur-based moiety associated with the polymer; and a releasable probe molecule associated with the core particle, where the releasable probe molecule is releasable from the core particle upon exposure to hydrocarbons. Additional embodiments of the present disclosure pertain to methods of detecting hydrocarbons in a geological structure by utilizing the nanocomposites of the present disclosure.
    Type: Application
    Filed: March 25, 2013
    Publication date: February 19, 2015
    Applicant: William Marsh Rice University
    Inventors: James M. Tour, Chih-Chau Hwang, Wei Lu, Gedeng Ruan, Mason B. Tomson, Amy Kan, Lu Wang, Michael S. Wong, Gautam Kini, George J. Hirasaki, Clarence Miller
  • Patent number: 8911615
    Abstract: A composition and method demulsify a produced emulsion from anionic surfactants and polymer (SP) and alkali, surfactants, and polymer (ASP). The produced emulsion is demulsified into oil and water. In one embodiment, the composition includes a surfactant. The surfactant comprises a cationic surfactant, an amphoteric surfactant, or any combinations thereof.
    Type: Grant
    Filed: April 8, 2010
    Date of Patent: December 16, 2014
    Assignees: William Marsh Rice University, NALCO Company
    Inventors: Olina G. Raney, John Hera, Jr., Duy T. Nguyen, Michael K. Poindexter, George J. Hirasaki, Clarence A. Miller
  • Publication number: 20130196886
    Abstract: The invention relates to a hydrocarbon recovery composition comprising a combination of an internal olefin sulfonate and an alkoxy glycidyl sulfonate, more specifically a hydrocarbon recovery composition comprising surfactant and water, wherein the surfactant comprises a combination of an internal olefin sulfonate with a chain length of greater than C20 and an alkoxy glycidyl sulfonate selected from an ethoxylated glycidyl sulfonate and a propoxylated glycidyl sulfonate. Further, the invention relates to a method of treating a hydrocarbon containing formation, comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises a blend of an internal olefin sulfonate and an alkoxy glycidyl sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
    Type: Application
    Filed: February 10, 2011
    Publication date: August 1, 2013
    Inventors: Julian Richard Barnes, George J. Hirasaki, Clarence A. Miller, Maura Puerto
  • Publication number: 20110247966
    Abstract: A composition and method demulsify a produced emulsion from anionic surfactants and polymer (SP) and alkali, surfactants, and polymer (ASP). The produced emulsion is demulsified into oil and water. In one embodiment, the composition includes a surfactant. The surfactant comprises a cationic surfactant, an amphoteric surfactant, or any combinations thereof.
    Type: Application
    Filed: April 8, 2010
    Publication date: October 13, 2011
    Applicants: NALCO COMPANY, WILLIAM MARSH RICE UNIVERSITY
    Inventors: Olina G. Raney, John Hera, JR., Duy T. Nguyen, Michael K. Poindexter, George J. Hirasaki, Clarence A. Miller
  • Patent number: 6695055
    Abstract: Methods of reducing the water permeability of a water producing zone in a subterranean formation are provided. The methods basically comprise introducing a polymeric surfactant and an inert gas into the water producing zone to thereby form a water permeability reducing foam therein. The polymeric surfactant has the property of facilitating the formation of the foam and the additional property of stabilizing the foam in the presence of flowing formation water.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: February 24, 2004
    Assignee: Wm. Marsh Rice University
    Inventors: George J. Hirasaki, Clarence A. Miller
  • Publication number: 20030092578
    Abstract: Methods of reducing the water permeability of a water producing zone in a subterranean formation are provided. The methods basically comprise introducing a polymeric surfactant and an inert gas into the water producing zone to thereby form a water permeability reducing foam therein. The polymeric surfactant has the property of facilitating the formation of the foam and the additional property of stabilizing the foam in the presence of flowing formation water.
    Type: Application
    Filed: November 15, 2001
    Publication date: May 15, 2003
    Inventors: George J. Hirasaki, Clarence A. Miller
  • Publication number: 20020094684
    Abstract: A method and apparatus for cleaning semiconductor wafers during the fabrication process. In the method, a foam is passed over the wafer surfaces in order to remove particulate matter. Viscosity, electrical charge and recipe of the foam may be varied to enhance wafer cleaning. In a preferred embodiment of the present invention, a number of wafers are situated vertically in a cleaning chamber and allowed to rotate between a number of axially rotatable rollers, with at least one roller also being a drive roller, while foam is passed across the wafer surfaces.
    Type: Application
    Filed: November 27, 2001
    Publication date: July 18, 2002
    Inventors: George J. Hirasaki, Daniel Pham
  • Patent number: 4597442
    Abstract: In a process in which steam and steam-foaming surfactant are injected into a subterranean reservoir having significant cation-exchange capacity, the rate of transport of the steam-foaming surfactant is increased by a prior injection of an aqueous liquid solution of surfactant and monovalent cation salt.
    Type: Grant
    Filed: February 26, 1985
    Date of Patent: July 1, 1986
    Assignee: Shell Oil Company
    Inventors: Richard E. Dilgren, Hon C. Lau, George J. Hirasaki
  • Patent number: 4570711
    Abstract: In a process for injecting a steam-foam-forming mixture into a subterranean reservoir to displace oil, injecting a mixture containing only as much noncondensible gas as required for substantially reducing the mobility of an injected steam-foam-forming mixture containing a given kind and amount of surfactant and electrolyte, which amount of noncondensible gas to add is calculated from a specified equation interrelating the reservoir temperature and pore size.
    Type: Grant
    Filed: August 9, 1984
    Date of Patent: February 18, 1986
    Assignee: Shell Oil Company
    Inventors: Andrew H. Falls, Jimmie B. Lawson, George J. Hirasaki
  • Patent number: 4086964
    Abstract: In a viscous oil reservoir in which the stratification of the rock permeability is insufficient to confine steam within the most permeable strata, oil can be produced by forming and expanding a steam channel through which steam is flowed and oil is produced. Steam is injected and fluid is produced at rates causing a steam channel to be extended between locations that are horizontally separated. A foam-forming mixture of steam, noncondensable gas and surfactant is then injected into the steam channel to provide foam and a relatively high pressure gradient within the channel, without plugging the channel. A flow of steam-containing fluid through the steam channel is continued in a manner such that the magnitudes of the pressure gradient, the rate of oil production, and the rate of steam channel expansion exceed those which could be provided by steam alone.
    Type: Grant
    Filed: May 27, 1977
    Date of Patent: May 2, 1978
    Assignee: Shell Oil Company
    Inventors: Richard E. Dilgren, George J. Hirasaki, Harold J. Hill, Derrill G. Whitten