Patents by Inventor George R. Chapman, Jr.

George R. Chapman, Jr. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5547761
    Abstract: Copolymers of tetrafluoroethylene (TFE) and hexafluoropropylene (HFP) having high HFP content and end-of-melting temperature, T.sub.m (end), as low as 200.degree. C. are disclosed. Exceptional performance as a processing aid in polyolefins results from having T.sub.m (end) of the TFE/HFP copolymer close to the processing temperature of the polyolefin. These TFE/HFP copolymers are soluble in fluorinated cyclic solvents. Copolymer/solvent systems copolymer at significant concentrations in selected solvents are fluid and stable at room temperature.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: August 20, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Richard A. Morgan, Charles W. Stewart, William H. Tuminello, John G. Van Alsten, Randall A. Vogel, Mark E. Wagman
  • Patent number: 5464904
    Abstract: Copolymers of tetrafluoroethylene (TFE) and hexafluoropropylene (HFP) having high HFP content and end-of-melting temperature, T.sub.m (end), as low as 200.degree. C. are disclosed. Exceptional performance as a processing aid in polyolefins results from having T.sub.m (end) of the TFE/HFP copolymer close to the processing temperature of the polyolefin. These TFE/HFP copolymers are soluble in fluorinated cyclic solvents. Copolymer/solvent systems copolymer at significant concentrations in selected solvents are fluid and stable at room temperature.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: November 7, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Lewis E. Crenshaw, Rita S. McMinn, Richard A. Morgan, Donnan E. Priester, Charles W. Stewart, Robert E. Tarney
  • Patent number: 5266639
    Abstract: Copolymers of tetrafluoroethylene (TFE) and hexafluoropropylene (HFP) having high HFP content and end-of-melting temperature, T.sub.m (end), as low as 200.degree. C. are disclosed. Exceptional performance as a processing aid in polyolefins results from having T.sub.m (end) of the TFE/HFP copolymer close to the processing temperature of the polyolefin. These TFE/HFP copolymers are soluble in fluorinated cyclic solvents. Copolymer/solvent systems copolymer at significant concentrations in selected solvents are fluid and stable at room temperature.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: November 30, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Lewis E. Crenshaw, Rita S. McMinn, Richard A. Morgan, Donnan E. Priester, Charles W. Stewart, William H. Tuminello, Robert E. Tarney, John G. Van Alsten, Mark E. Wagman
  • Patent number: 5132368
    Abstract: The subject invention provides a composition having excellent extrusion characteristics comprising a difficulty-melt-processible polymer and 0.002-0.5 wt. % of one or more fluoropolymer process aids wherein the fluoropolymer has a fluorine to carbon ratio of at least 1:2, is capable of forming a die-coating film under the prevailing conditions of extrusion temperature and pressure, and contains an effective amount of polar functional polymer chain end groups, --W, wherein --W is selected from --COF, --SO.sub.2 F, --SO.sub.3 M, --OSO.sub.3 M, --COOR, and --COOM, wherein R is C.sub.1-3 alkyl and M is hydrogen, a metal cation, preferably an alkali or alkaline earth metal cation, or a quaternary ammonium cation.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: July 21, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Donnan E. Priester, Charles W. Stewart, Robert E. Tarney
  • Patent number: 5106911
    Abstract: An extrusion process for difficultly melt processible resins, for example, a difficultly-melt-processible hydrocarbon polymer, having improved processibility and having incorporated therein an elastomeric fluorocarbon copolymer, for example, an amorphous vinylidene fluoride copolymer, and a crystalline vinylidene fluoride polymer.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: April 21, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Donnan E. Priester
  • Patent number: 5089200
    Abstract: Process of melt extruding through an extrusion die whose surface is coated with one or more metal oxides, M.sub.x O.sub.y, wherein M is a metal selected from the group consisting of Ti, Zr, Cr, Fe, Ni, Pd, Pt, Cu, Ag, Au, Al and Si, and x and y are selected to satisfy the valencies of M, a difficultly-melt-processible polymer containing 0.002-2 parts by weight, based on the weight of the polymer, of at least one melt-processible fluorocarbon polymer processing aid having a fluorine to carbon ratio of at least 1:2 and having metal oxide-reactive sites capable of reacting with or physically associating with the metal oxide of the die surface.
    Type: Grant
    Filed: September 20, 1990
    Date of Patent: February 18, 1992
    Assignee: E. I. DuPont de Nemours and Company
    Inventors: George R. Chapman, Jr., Rita S. McMinn, Donnan E. Priester, William L. Phillips
  • Patent number: 5057575
    Abstract: Polymer blend composition having improved processibility and comprising:(a) a major portion of a difficultly melt-procesible polymer, and(b) a minor portion of:1 at least an effective amount, to improve processibility, of a fluorocarbon copolymer which at the melt-processing temperature of (a) is either in a melted form if crystalline, or is above its glass transition temperature if amorphous, and(2) at least an effective amount, to improve processibility, of at least one tetrafluoroethylene homopolymer or copolymer of tetrafluoroethylene and at least one monomer copolymerizable therewith, wherein the mole ratio of fluorine to hydrogen is at least 1:1, and which is solid at the melt-processing temperature of (a);masterbatches comprised of the processing aid; and processes utilizing the processing aid.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: October 15, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Donnan E. Priester, Charles W. Stewart
  • Patent number: 5013792
    Abstract: Polymer blend composition having improved processibility and comprising:(a) a major portion of a difficultly melt-processible polymer, and(b) a minor portion of:(1) at least an effective amount, to improve processibility, of a fluorocarbon copolymer which at the melt-processing temperature of (a) is either in a melted form if crystalline, or is above its glass transition temperature if amorphous, and(2) at least an effective amount, to improve processibility, of at least one tetrafluoroethylene homopolymer or copolymer of tetrafluoroethylene and at least one monomer copolymerizable therewith, wherein the mole ratio of fluorine to hydrogen is at least 1:1, and which is solid at the melt-processing temperature of (a);masterbatches comprised of the processing aid; and processes utilizing the processing aid.
    Type: Grant
    Filed: August 29, 1990
    Date of Patent: May 7, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Donnan E. Priester, Charles W. Stewart
  • Patent number: 5010130
    Abstract: Improved polymer blend composition having improved processibility and comprising:(a) a major portion of a difficultly melt-processible polymer, and(b) a minor portion of:(1) at least an effective amount, to improve processibility, of a fluorocarbon copolymer which at the melt-processing temperature of (a) is either in a melted form if crystalline, or is above its glass transition temperature if amorphous, and(2) at least an effective amount, to improve processibility, of at least one tetrafluoroethylene homopolymer or copolymer of tetrafluoroethylene and at least one monomer copolymerizable therewith, wherein the mole ratio of fluorine to hydrogen is at least 1:1, and which is solid at the melt processing temperature of (a),said composition further characterized in that it contains an abrasive inorganic filler that retards the processibility of (a) in the presence of (b)(1) and (b)(2), the improvement consisting of minimizing the retarding effect of the inorganic filler by employing (b)(1) having an apparent
    Type: Grant
    Filed: May 15, 1990
    Date of Patent: April 23, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Lee A. Gorthey, Donnan E. Priester
  • Patent number: 4904735
    Abstract: Polymer blend composition having improved processibility and comprising:(a) a major portion of a difficultly melt-processible polymer, and(b) a minor portion of:(1) at least an effective amount, to improve processibility, of a fluorocarbon copolymer which at the melt-processing temperature of (a) is either in a melted form if crystalline, or is above its glass transition temperature if amorphous, and(2) at least an effective amount, to improve processibility, of at least one tetrafluoroethylene homopolymer or copolymer of tetrafluoroethylene and at least one monomer copolymerizable therewith, wherein the mole ratio of fluorine to hydrogen is at least 1:1, and which is solid at the melt-processing temperature of (a);masterbatches comprised of the processing aid; and processes utilizing the processing aid.
    Type: Grant
    Filed: July 8, 1988
    Date of Patent: February 27, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Donnan E. Priester