Abstract: In a catalytic combustor for gas turbines, the dimensions of the preheater and premix duct, the location of the preheater and premix fuel nozzles, and the number and location of air orifices in the combustor can inner liner are configured to result in low NOx production during both preheating combustion and catalytic combustion. Placement of the air orifices helps reduce the potential for autoignition within the premix duct, while enhancing fuel-air mixture uniformity upstream of the catalyst. At the same time, the overall configuration is optimized to result in the relative compactness of the catalytic combustor, making it particularly suitable for applications such as automotive turbine engines and microturbines.

Abstract: This application relates to a catalyst and a process using this catalyst to convert or destroy organic compounds including organohalogen compounds. A preferred catalyst contains as catalytic components titania, vanadium oxide, tungsten oxide, tin oxide and at least one noble metal selected from the group consisting of platinum, palladium and rhodium, characterized in that the vanadium oxide, tungsten oxide and noble metals are uniformly dispersed on the titania. The process of this invention comprises contacting the gas stream, which contains organohalogen compounds and other organic compounds, at a temperature of about 200.degree. to about 500.degree. C. with the catalyst described above in the presence of an oxidizing agent and water. The oxidizing agent can be oxygen or air.

Abstract: This application relates to a catalyst and a process using this catalyst to convert or destroy organic compounds including organohalogen compounds. A preferred catalyst contains as catalytic components titania, vanadium oxide, tungsten oxide, tin oxide and at least one noble metal selected from the group consisting of platinum, palladium and rhodium, characterized in that the vanadium oxide, tungsten oxide and noble metals are uniformly dispersed on the titania. The process of this invention comprises contacting the gas stream, which contains organohalogen compounds and other organic compounds, at a temperature of about 200.degree. to about 500.degree. C. with the catalyst described above in the presence of an oxidizing agent and water. The oxidizing agent can be oxygen or air.

Abstract: This invention relates to a catalyst comprising a mixture of a primary refractory inorganic oxide having dispersed thereon at least one first active component selected from the group consisting of rare earth oxides and a secondary support consisting of zirconia, titania or cerium oxide having dispersed thereon at least one second active component which is a metal oxide, the metal selected from the group consisting of metals which form a stable sulfide said mixture having at least one main catalytic metal selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium deposited thereon. This invention also relates to a method of manufacturing said catalyst. Finally a method to minimize the formation of H.sub.2 S when automotive exhaust is contacted with a method is also claimed.

Abstract: This invention relates to a catalytic composite comprising a mixture of a primary refractory inorganic oxide having dispersed thereon at least one first active component selected from the group consisting of rare earth oxides and a secondary support consisting of zirconia, titania or cerium oxide having dispersed thereon at least one second active component selected from the group consisting of metals which form a stable sulfide said mixture having at least one main catalytic metal selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium deposited thereon. This invention also relates to a method of manufacturing said catalytic composite. Finally a method to minimize the formation of H.sub.2 S when automotive exhaust is contacted with a catalytic composite is also claimed.

Abstract: Silicon nitride powder may be prepared by subjecting a composite comprising at least a monolayer of a carbonaceous pyropolymer possessing recurring units containing at least carbon and hydrogen atoms on the surface of a silica support to the action of nitrogen-containing atmospheres at nitriding conditions to form silicon nitride.

Abstract: A catalyst composition and a process are presented for the reduction of nitrogen oxides in flue gases to nitrogen. The catalyst comprises titania, mordenite and a metal component. The preferred metal component comprises vanadium oxide and tungsten oxide. At least 15 wt. % mordenite is present, with high silica H-mordenite being preferred.

Abstract: Integral shaped replication composites which may be useful for supports for catalysts or as adsorbents comprise a carbonaceous pyropolymeric structure which has been prepared by treating an inorganic support with an organic pyropolymer precursor and pyrolyzing the precursor to form a carbonaceous pyropolymer possessing recurring units containing at least carbon and hydrogen atoms on the surface of the support. This carbonaceous pyropolymer will duplicate the physical shape and dimensions of the inorganic support as well as a substantial portion of the pore structure thereof. The integral shaped replication will possess an ABD which is about 25% to 100% of the ABD of the inorganic support, and have a crush strength of from about 0.5 to about 14 kilograms. The composite comprising the carbonaceous pyropolymer on the surface of the support may then be leached with an acid or base to remove the inorganic support, thus leaving a shaped replication of particle aggregates.

Abstract: A polyfunctional phenol is polymerized utilizing a carrier catalyst comprising a palladium carboxylic acid salt in a carboxylic acid medium.

Abstract: A method of impregnating a catalytic component on a carrier material. The carrier material is immersed in an impregnating solution containing a catalytic component and a polybasic carboxylic acid, with a sulfur-containing carboxylic acid being subsequently added to the solution whereby the catalytic component is dispersed in a subsurface layer on the carrier material and penetration beyond the desired subsurface layer is substantially obviated. Prior to calcining, the impregnated carrier material is further impregnated with an alkaline earth metal salt of an organic acid, and the solution evaporated to dryness in contact with the impregnated carrier material.

Abstract: A method of impregnating a catalytic component on the outer surface of a carrier material at conditions to improve the activity stability as well as the physical stability of the catalytic composite. A carrier material is immersed in an impregnating solution containing a catalytic component and a sulfur-containing carboxylic acid whereby the catalytic component is dispersed on the outer surface of the carrier material without any substantial penetration thereof. Prior to calcining, the impregnated carrier material is further impregnated with an alkaline earth metal salt of an organic acid and the solution evaporated to dryness in contact with the impregnated carrier material.

Abstract: A method of impregnating a catalytic component as a subsurface layer on a carrier material. The carrier material is immersed in an impregnating solution containing a catalytic component and a dibasic carboxylic acid, with a sulfur-containing carboxylic acid being subsequently added to the solution whereby the catalytic component is dispersed in a subsurface layer on the carrier material and penetration beyond the desired subsurface layer is substantially obviated.