Abstract: A process for the addition of pendant groups to polyarylenes comprises the steps of charging a reaction vessel with a solution of a polyarylene and a Friedel-Crafts catalysts; said polyarylene having the formula ##STR1## adding to the reaction vessel a pendant forming group G, wherein G is selected from the group consisting of sulfonyl halides, sulfonamide halides, alkylhalides, acylhalides and phosphorus acid halides; heating the contents of the reaction vessel to form a substituted polyarylene having the formula ##STR2## and thereafter recovering the substituted polyarylene. The substituted polyarylenes are novel and have utility as a semipermeable membrane and a process for the separation of gases therewith is also provided.

Abstract: The process for the separation of gases from a mixture is improved by using as the separation vehicle a single layer semipermeable membrane containing at least about 25 weight percent, based upon the total weight of the membrane, of at least one substituted poly(arylene oxide) polymer containing at least about 50 mole percent of structural units of the formula ##STR1## wherein each R is independently a C.sub.1 to C.sub.8 aliphatic; a C.sub.5 to C.sub.7 cycloaliphatic; a C.sub.1 to C.sub.8 alkoxy radical; a C.sub.6 to C.sub.12 aromatic radical or an inertly-substituted derivative of any one of them, each radical being free of a tertiary alpha-carbon atom, each X is independently hydrogen or a radical at least the size of a chloride radical, with the proviso that at least one X is not hydrogen.

Abstract: Novel permselective membrane compositions comprise a crosslinked polymer membrane. The polymer membrane has from about 25 to 100 parts by weight of a polyarylene having the formula ##STR1## and from about 0 to 75 parts by weight of a crosslinkable copolymer, the copolymer being present at least when the polyarylene component is devoid of crosslinkable cites. The foregoing polymer or polymer mixture is crosslinked by a silicon-containing amineterminated compound selected from the group consisting of the siloxanes having the formula ##STR2## and silanes having the formulaH.sub.2 N--R.sub.2 --[Si--O--R.sub.4 ].sub.3.A process is provided for the separation of gases from a mixture containing at least two gases and includes the step of passing the gas mixture over the permselective membrane composition of the present invention.

Abstract: Semipermeable membranes useful for the separation of gases from a mixture containing at least two fractions into enriched fractions of each, the membrane formed from at least one polymer containing a preponderance of arylene units of the formula ##STR1## where each R is independently a C.sub.1 -C.sub.8 aliphatic or a C.sub.5 -C.sub.7 cycloaliphatic hydrocarbon radical, an aryl radical, an aralkyl radical or an alkaryl radical, each radical being free of a tertiary alpha-carbon atom; each Q is a radical of the formula ##STR2## where R' is a C.sub.1 -C.sub.20 linear or branched hydrocarbon or a nonpolymeric aryl radical; X is a divalent oxygen or sulfur atom or a carbonate group; m is an integer of 0-2; and n is 0-1 with the proviso that n is 1 in at least 10 percent of the arylene units of the polymer. A process is also provided whereby a mixture of gases is separated with the foregoing semipermeable membrane.

Abstract: A protective coating which is resistant to attack by basic solutions is formed from interpolymers containing maleic anhydride (MAH). An article is coated with a solution of the dissolved ammonium or amine salts of the MAH interpolymer, or if the article itself contains MAH the salts may alternatively be formed on the surface of the article by applying a basic solution containing the ammonium or amine ions. The article is then dried and heated at a temperature sufficient to form the cyclic imide structure from the ammonium or amine salt of the MAH, typically about 160 to 200.degree. C.

Abstract: Semipermeable membranes prepared from at least one cellulosic polymer, such as cellulose triacetate, and containing at least one silicon compound, such as tetraethoxy silane, are useful for the separation of various gaseous mixtures into their constituent parts, such as separating natural gas into enriched fractions of carbon dioxide and methane.

Abstract: Semipermeable membranes useful for separating gaseous mixtures of carbon dioxide and methane into enriched fractions of each are prepared from at least one polymer containing a preponderance of arylene units, such as polyxylene oxide, the arylene units containing pendent sulfone groups substituted with an aromatic group, such as phenyl.

Abstract: Molded fiber-reinforced thermoplastic articles are prepared by a novel two-step process involving an in situ polymerization of monomers onto the fiber followed by compression molding of the product.

Abstract: Moldable polyolefin compositions exhibiting improved heat distortion and modulus characteristics, and a method of preparing such compositions are described. The method of preparing these polyolefin compositions comprises reacting(a) a graft-modified polyolefin obtained by reacting a polyolefin with an unsaturated polycarboxylic acid, ester or anhydride which is graft-polymerizable therewith, and(b) at least one organic hydroxy compound. These polyolefin compositions can be reinforced with fibers, minerals and fillers for particular applications.

Abstract: Polymeric compositions having high softening temperatures, good gas barrier properties and low creep properties are composed of an olefinically unsaturated nitrile, another monovinyl component and maleic anhydride and optionally a diene monomer.

Abstract: Polymeric compositions having high softening temperatures, good gas barrier properties and low creep properties are composed of an olefinically unsaturated nitrile, another monovinyl component and maleic anhydride and optionally a diene monomer.

Abstract: Certain physical properties, such as heat-distortion temperature and flexural modulus, of certain commercially available thermoplastic resins are improved by blending with polyindene or coumarone-indene resins.

Abstract: A dehydrogenation process for producing indene and substituted indenes from tetrahydroindene or substituted tetrahydroindene is described and comprises contacting said tetrahydroindene or substituted tetrahydroindene with a catalyst comprising cobalt oxide and molybdenum oxide at an elevated temperature for a period of from about 0.1 to 30 seconds. The tetrahydroindene and substituted tetrahydroindenes may be prepared from cyclopentadiene or dicyclopentadiene and a butadiene.

Abstract: A plasticized resin system is described, and the system comprises an intimate mixture of(a) an interpolymer derived from at least one vinyl monomer and an .alpha.,.beta.- unsaturated dicarboxylic acid, anhydride or the lower alkyl esters thereof, and(b) a plasticizing amount of a hydroxy substituted fatty acid containing at least about eight carbon atoms.The plasticized resin system also may contain at least one additional polar resin such as polycarbonates, polysulfones, polyesters, etc. The use of the hydroxy substituted fatty acid in this manner improves the processability of the interpolymers.

Abstract: Certain physical properties, such as heat-distortion temperature and flexural modulus, of certain commercially available thermoplastic resins are improved by blending with polyindene or coumarone-indene resins.

Abstract: Polymeric compositions having high softening temperatures, good gas barrier properties and low creep properties are composed of an olefinically unsaturated nitrile, another monovinyl component and maleic anhydride and optionally a diene monomer.

Abstract: Blends of high-acrylonitrile thermoplastic copolymers with acrylonitrile-indene copolymers have improved softening temperatures, improved gas barrier properties and other improved physical properties.

Abstract: High softening thermoplastic polymeric compositions having good impact resistance are composed of polymerized maleic anhydride, a cyclic olefin such as beta-pinene, styrene, and a preformed rubber such as a styrene-butadiene rubber.

Abstract: Certain physical properties, such as heat-distortion temperature and flexural modulus, of certain commercially available thermoplastic resins are improved by blending with polyindene or coumarone-indene resins.

Abstract: Blends of high-acrylonitrile thermoplastic copolymers with acrylonitrile-indene copolymers have improved softening temperatures, improved gas barrier properties and other improved physical properties.