Abstract: A compound of formula Li4+xMnM1aM2bOc wherein: M1 is selected from the group consisting in Ni, Mn, Co, Fe and a mixture thereof; M2 is selected from the group consisting in Si, Ti, Mo, B, Al and a mixture thereof; with: ?1.2?x?3; 0<a?2.5; 0?b?1.5; 4.3?c?10; and c=4+a+n·b+x/2 wherein n=2 when M2 is selected from the group consisting in Si, Ti, Mo or a mixture thereof; and n=1.5 when M2 is selected from the group consisting in B, Al or a mixture thereof; and n=0 if b=0.

Abstract: The present invention relates to a precursor of a negative electrode compartment for rechargeable metal-air batteries, comprising a rigid casing (1), at least one solid electrolyte membrane (2), a protective covering (5), completely covering the inside face of the solid electrolyte membrane (2), a metallic current collector (3) applied against the inside face of the protective covering (5), preferably also a block (4) of elastic material applied against the current collector and essentially filling the entire internal space defined by the walls of the rigid casing and the solid electrolyte (2), and a flexible electronic conductor (6) passing in a sealed manner through one of the walls of the rigid casing. The present invention also relates to a negative electrode compartment having a rigid casing obtained from said precursor and to a battery containing such a negative electrode compartment.

Abstract: A compound of formula Lia+y(M1(1?t)Mot)2M2b(O1?xF2x)c wherein: M1 is selected from the group consisting in Ni, Mn, Co, Fe, V or a mixture thereof; M2 is selected from the group consisting in B, Al, Si, P, Ti, Mo; with 4?a?6; 0<b?1.8; 3.8?c?14; 0?x<1; ?0.5?y?0.5; 0?t?0.9; b/a<0.45; the coefficient c satisfying one of the following relationships: c=4+y/2+z+2t+1.5b if M2 is selected from B and Al; c=4+y/2+z+2t+2b if M2 is selected from Si, Ti and Mo; c=4+y/2+z+2t+2.5b if M2 is P; with z=0 if M1 is selected from Ni, Mn, Co, Fe and z=1 if M1 is V.

Abstract: A compound of formula Li4+xMnM1aM2bOc wherein: M1 is selected from the group consisting in Ni, Mn, Co, Fe and a mixture thereof; M2 is selected from the group consisting in Si, Ti, Mo, B, Al and a mixture thereof; with: ?1.2?x?3; 0<a?2.5; 0?b?1.5; 4.3?c?10; and c=4+a+n·b+x/2 wherein n=2 when M2 is selected from the group consisting in Si, Ti, Mo or a mixture thereof; and n=1.5 when M2 is selected from the group consisting in B, Al or a mixture thereof; and n=0 if b=0.

Abstract: An alloy comprising tin, silicon and carbon, and containing a crystalline M-Sn phase, M being an inert metal. An alloy comprising tin and silicon, comprising: a) a nanocrystalline phase containing at least 50 at. % of the element silicon Si°; b) a nanocrystalline phase containing a compound based on tin; c) a nanocrystalline phase constituted by the element tin Sn°. A manufacturing process for this alloy.

Abstract: A compound of formula Lia+y(M1(1?t)Mot)2M2b(O1?xF2x)c wherein: M1 is selected from the group consisting in Ni, Mn, Co, Fe, V or a mixture thereof; M2 is selected from the group consisting in B, Al, Si, P, Ti, Mo; with 4?a?6; 0<b?1.8; 3.8?c?14; 0?x<1; ?0.5?y?0.5; 0?t?0.9; b/a<0.45; the coefficient c satisfying one of the following relationships: c=4+y/2+z+2t+1.5b if M2 is selected from B and Al; c=4+y/2+z+2t+2b if M2 is selected from Si, Ti and Mo; c=4+y/2+z+2t+2.5b if M2 is P; with z=0 if M1 is selected from Ni, Mn, Co, Fe and z=1 if M1 is V.

Abstract: The present invention relates to a precursor of a negative electrode compartment for rechargeable metal-air batteries, comprising a rigid casing (1), at least one solid electrolyte membrane (2), a protective covering (5), completely covering the inside face of the solid electrolyte membrane (2), a metallic current collector (3) applied against the inside face of the protective covering (5), preferably also a block (4) of elastic material applied against the current collector and essentially filling the entire internal space defined by the walls of the rigid casing and the solid electrolyte (2), and a flexible electronic conductor (6) passing in a sealed manner through one of the walls of the rigid casing. The present invention also relates to a negative electrode compartment having a rigid casing obtained from said precursor and to a battery containing such a negative electrode compartment.

Abstract: An alloy comprising tin, silicon and carbon, and containing a crystalline M-Sn phase, M being an inert metal. An alloy comprising tin and silicon, comprising: a) a nanocrystalline phase containing at least 50 at. % of the element silicon Si°; b) a nanocrystalline phase containing a compound based on tin; c) a nanocrystalline phase constituted by the element tin Sn°. A manufacturing process for this alloy.

Abstract: The invention proposes an open alkaline accumulator of the nickel cadmium or nickel metal hydride type comprising at least one positive electrode, at least one negative electrode and at least one separator, said separator comprising a microporous membrane of polyolefin grafted with an ethylenically unsaturated monomer, and on either side of said membrane, at least one layer of polyolefin with a fibrous structure. Said accumulator has a lesser risk of thermal runaway upon charging at constant voltage, and a longer life time. The invention lies in the discovery that the use of a microporous membrane of polyolefin grafted with an ethylenically unsaturated monomer in an open alkaline accumulator of the nickel cadmium or nickel metal hydride type, provides a barrier to oxygen gas. The invention is extended to the method for charging at constant voltage said alkaline accumulator.

Abstract: An electrochemical cell (1) comprises firstly a negative electrode (9) and a positive electrode (10), each comprising a current collector (11, 15) having a first portion (12, 16) defining a connection terminal (13, 18) extending from a second portion (14, 19) provided with an active material (15, 20), the connection terminals (13, 18) being placed on either side of an electrically insulating layer (22) and co-operating therewith to define a single connection tab (3), the cell also having a case (4) housing in leakproof manner the second portions (14, 19) of the current collectors (11, 15) while leaving at least a portion of the single connection tab (3) projecting outwards.

Abstract: An electrode comprises a porous three-dimensional conductive support and at least one reinforcing metal band fixed along a longitudinal edge portion of the support and having a coefficient of elongation to rupture equal to at least 20% in a direction parallel to the edge portion of the support. Two longitudinal edge portions of the band are bent against the same face of the band, at least part of whose surface is pressed against the support.

Abstract: A process of preparing an electrode for an electrochemical cell comprising a foamlike porous metal support (1) loaded with active material, wherein, on each side of said support there is placed a separator layer (2, 3) made of polyolefin fibers, and wherein the assembly thus obtained is compressed so as to produce an adhesive bond between the layers of separator and the entire surface of said support.