Patents by Inventor Georges Kvasnikoff

Georges Kvasnikoff has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5607657
    Abstract: A process is disclosed for the removal of sulphur compounds from a residual gas so as to obtain a purified gas stream substantially free of sulphur compounds, which process comprises subjecting the residual gas to a combined hydrogenation and hydrolysis, cooling the gas to a temperature whereby water vapor in the gas is not condensed, mixing the gaseous effluent with a gas containing free oxygen, contacting the cooled gaseous effluent and the gas containing free oxygen with a catalyst for selective oxidation of H.sub.2 S to sulphur, and depositing substantially all of the sulphur formed on the catalyst.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: March 4, 1997
    Assignee: Elf Aquitaine Production
    Inventors: Andre Philippe, Jean Nougayrede, Georges Kvasnikoff
  • Patent number: 5508013
    Abstract: A process is provided for the production of sulphur from at least one sour gas containing H.sub.2 S and a gaseous or liquid fuel effluent, of the type comprising a thermal reaction step, wherein the thermal reaction step is conducted by performing the combustion of the gaseous or liquid fuel effluent in a first zone of the thermal reaction stage with a quantity of a gas containing free oxygen in excess in relation to the theoretical quantity needed for a complete combustion of the fuel effluent, the excess being smaller than the theoretical proportion of gas containing free oxygen needed to oxidize to SO.sub.2 approximately one third of the H.sub.
    Type: Grant
    Filed: August 22, 1994
    Date of Patent: April 16, 1996
    Assignee: Elf Aquitaine Production
    Inventors: Georges Kvasnikoff, Jean Nougayrede, Andre Philippe
  • Patent number: 5494650
    Abstract: A process is provided for the improvement of the sulphur yield of an assembly which produces sulphur from H.sub.2 S and which consists of a sulphur plant (1), an oxidation and hydrolysis unit (2) and a purification unit (3). The sulphur plant in producing sulphur provides a residual gas which incorporates H.sub.2 O, COS and/or CS.sub.2 and H.sub.2 S and SO.sub.2 in a mol ratio of H.sub.2 S:SO.sub.2 >2:1. The residual gas passes into the hydrolysis unit on a H.sub.2 S oxidation and COS and CS.sub.2 hydrolysis catalyst which functions between 180.degree. C. and 700.degree. C., in the presence of air, thus producing a residual gas free of COS and CS and incorporating H.sub.2 S and SO.sub.2 in a mol ratio which is kept equal to 2:1 by regulating the air flow. The residual gas is introduced into the purification unit in which H.sub.2 S and SO.sub.2 are made to react in order to produce sulphur and to obtain a purified residual gas.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: February 27, 1996
    Assignee: Societe Nationale Elf Aquitaine (Production)
    Inventors: Georges Kvasnikoff, Jean Nougayrede, Andre Philippe
  • Patent number: 5202107
    Abstract: A process is provided for improving the sulphur yield of a sulphur production unit using an acid gas containing H.sub.2 S and wherein said unit is comprised of a sulphur plant with a downstream purification unit. The H.sub.2 S resulting from hydrolysis of COS and CS.sub.2 is almost entirely recovered in the form of sulphur in the purification unit resulting in an improved sulphur output of the overall installation.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: April 13, 1993
    Assignee: Societe National Elf Aquitaine (Prod.)
    Inventors: Georges Kvasnikoff, Andre Philippe, Robert Voirin
  • Patent number: 5185140
    Abstract: Process for removing sulphur-containing compounds from a residual gas with recovery of said compounds in the form of sulphur, wherein the residual gas is subjected to a treatment comprising a hydrogenation and a hydrolysis phase to provide the sulphur-containing compounds in the unique form of H.sub.2 S, a cooling step with water condensation, a catalytic oxidation of H.sub.2 S in CLAUS stoechiometry and a catalytic CLAUS reaction phase with deposition of sulphur on the CLAUS catalyst and periodic regeneration of the sulphur-laden catalyst and cooling of the regenerated catalyst. The gas used for the regeneration and for the cooling is tapped from the gas effluent supplied to the catalytic oxidation and the gas issued from the regeneration is reintroduced at least in part into said gas effluent after separation of the sulphur containing therein. Application to the purification of residual gases issued from CLAUS sulphur units.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: February 9, 1993
    Assignee: Elf Aquitaine Production
    Inventors: Georges Kvasnikoff, Jean Nougayrede, Andre Philippe
  • Patent number: 5132098
    Abstract: Process for removing sulfur compounds contained in a residual gas with recovery of said compounds in the form of sulfur, wherein a gas obtained from a residual gas containing H.sub.s S and SO.sub.2 and having a temperature lower than 160.degree. C. is subjected to a catalytic CLAUS reaction phase with deposition of sulfur on the catalyst and periodic regeneration of the sulfur-laden catalyst and cooling of the regenerated catalyst. The gas brought in contact with the CLAUS catalyst is produced by subjecting the residual gas to a hydrogenation and hydrolysis treatment to provide the sulfur compounds in the unique form of H.sub.2 S and to cooling with water separation by condensation and then to catalytic oxidation of H.sub.2 S in CLAUS stoichiometry with cooling of the gas stream obtained from the oxidation step under 160.degree. C. in order to separate the sulfur by condensation. Application to the purification of the residual gases emitted by CLAUS sulfur plants.
    Type: Grant
    Filed: August 16, 1990
    Date of Patent: July 21, 1992
    Assignee: Societe Nationale Elf Aquitaine (Production)
    Inventors: Georges Kvasnikoff, Jean Nougayrede, Andre Philippe
  • Patent number: 5077031
    Abstract: Catalytic process for producing sulphur from H.sub.2 S-containing acid gas wherein the acid gas is subjected to a catalytic oxidation in CLAUS stoichiometry and to a catalytic CLAUS reaction phase with deposition of sulphur on the catalyst with periodic regeneration of the sulphur-laden catalyst and cooling of the regenerated catalyst. The gas used for the regeneration and for the cooling is tapped from the acid gas supplied to the catalytic oxidation and the gas issued from the regeneration is reintroduced into said acid gas after separation of the sulphur contained therein. The process is particularly applicable to the treatment.
    Type: Grant
    Filed: January 12, 1990
    Date of Patent: December 31, 1991
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Georges Kvasnikoff, Jean Nougayrede, Andre Philippe
  • Patent number: 4980146
    Abstract: Process for removing sulfur compounds contained in a residual gas with recovery of said compounds in the form of sulfur, wherein a gas obtained from a residual gas containing H.sub.2 S and SO.sub.2 and having a temperature lower than 160.degree. C. is subjected to a catalytic CLAUS reaction phase with deposition of sulfur on the catalyst and periodic regeneration of the sulfur-laden catalyst and cooling of the regenerated catalyst. The gas brought in contact with the CLAUS catalyst is produced by subjecting the residual gas to a hydrogenation and hydrolysis treatment to provide the sulfur compounds in the unique form of H.sub.2 S and to cooling with water separation by condensation and then to catalytic oxidation of H.sub.2 S in CLAUS stoichiometry with cooling of the gas stream obtained from the oxidation step under 160.degree. C. in order to separate the sulfur by condensation. Application to the purification of the residual gases emitted by CLAUS sulfur plants.
    Type: Grant
    Filed: June 25, 1987
    Date of Patent: December 25, 1990
    Assignee: Societe Nationale Elf Aquitaine (Production)
    Inventors: Georges Kvasnikoff, Jean Nougayrede, Andre Philippe
  • Patent number: 4894216
    Abstract: Catalytic process for producing sulphur from H.sub.2 S-containing acid gas wherein the acid gas is subjected to a catalytic oxidation of CLAUS stoichiometry and to a catalytic CLAUS reaction phase with deposition of sulphur on the catalyst with periodic regeneration of the sulphur-laden catalyst and cooling of the regenerated catalyst. The gas used for the regeneration and for the cooling is tapped from the acid gas supplied to the catalytic oxidation and the gas issued from the regeneration is reintroduced into said acid gas after separation of the sulphur contained therein. The process is particularly applicable to the treatment of acid gases having a low H.sub.2 S content.
    Type: Grant
    Filed: June 25, 1987
    Date of Patent: January 16, 1990
    Assignee: Societe Nationale Elf Aquitaine (Production)
    Inventors: Georges Kvasnikoff, Jean Nougayrede, Andre Philippe
  • Patent number: 4596699
    Abstract: A process to produce sulphur from two acid gases both containing hydrogen sulphide and one of which contains ammonia, using a modified Claus technique.The acid gas containing ammonia is burnt in the presence of air under substoichiometric conditions in a first heat-reaction chamber, while the ammonia-free acid gas is burnt in a second heat-reaction chamber, forming a series with the first chamber, with the right quantity of air to provide a molar ratio of H.sub.2 S to SO.sub.2 of approximately 2/1 at the catalytic reaction stage inlet. The mixed effluents from both heat-reaction chambers may pass through a high-temperature residence chamber before being conveyed to the heat-recovery stage.Gas effluents from the heat-reaction stage contain H.sub.2 S and SO.sub.2 in the right ratio for the catalytic reaction stage, and no hydrocarbons or harmful quantities of NH.sub.3 and NO.
    Type: Grant
    Filed: October 23, 1980
    Date of Patent: June 24, 1986
    Assignee: Societe Nationale Elf Aquitaine (Production)
    Inventors: Guy Desgrandchamps, Georges Kvasnikoff, Claude Blanc
  • Patent number: 4436716
    Abstract: Improved process for the production of sulphur from a gas containing H.sub.2 S, SO.sub.2, H.sub.2 and/or CO, in which the gas is caused to pass through a CLAUS catalyst in a primary catalytic stage operating at between 200.degree. and 460.degree. C. in order to form sulphur, and thereafter the sulphur contained in the reaction mixture issuing from this stage is condensed through indirect heat exchange with water to produce steam.The improved process consists in constituting at least the final eighth of the catalyst volume in this stage by a composite mass formed from a refractory oxide on which is fixed a transition metal compound, for example Co and/or Mo, and in entering into contact the gas with this composite mass at between 300.degree. and 460.degree. C. in order to oxidize H.sub.2 and CO.The energy resulting from this oxidation is recovered in the form of a supplementary quantity of steam during the sulphur condensation.
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: March 13, 1984
    Assignee: Societe Nationale Elf Aquitaine (Production)
    Inventors: Georges Kvasnikoff, Robert Voirin
  • Patent number: 4395390
    Abstract: A process to produce sulphur from two acid gases both containing hydrogen sulphide and one of which contains ammonia, using a modified Claus technique.The acid gas containing ammonia is burnt in the presence of air under substoichiometric conditions in a first heat-reaction chamber, while the ammonia-free acid gas is burnt in a second heat-reaction chamber, forming a series with the first chamber, with the right quantity of air to provide a molar ratio of H.sub.2 S to SO.sub.2 of approximately 2/1 at the catalytic reaction stage inlet. The mixed effluents from both heat-reaction chambers may pass through a high-temperature residence chamber before being conveyed to the heat-recovery stage.Gas effluents from the heat-reaction stage contain H.sub.2 S and SO.sub.2 in the right ratio for the catalytic reaction stage, and no hydrocarbons or harmful quantities of NH.sub.3 and NO.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: July 26, 1983
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Guy Desgrandchamps, Georges Kvasnikoff, Claude Blanc