Patents by Inventor Georges Metzger

Georges Metzger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20040063706
    Abstract: A process for the preparation of a 4,4′-bistriazinylamino-stilbene-2,2′-disulphonic acid compound of formula (I) in which, independently, each R1 represents —NH2, —NH(C1-c10alkyl), —N(C1-C10alkyl)2, —NH(C2-C4hydroxyalkyl), —NH(C2-C4hydroxyalkyl)2, —N(C1-C10alkyl)(C2-C4hydroxyalalkyl), —NH(C1-C4alkoxy-C2-C4hydroxyalkyl), —N(C1-C4alkoxy-C2-C6hydroxyalkyl)2, —N(C1-C4alkoxy-C2-C4hydroxyalkyl)(C1-C10alkyl), —N(C1-C4alkoxy-C2C4hydroxyalkyl)(C2-C4hydroxyalkyl), —NH(C1-C4alkoxy-C1-C4alkoxy-C1-C4-alkyl), —N(C1-C4alkoxy-C1-C4alkoxy-C1-C4-alkyl)2, —N(C1-C4alkoxy-C1-C4alkoxy-C1-C4alkyl)(C1-C6alkyl), —N(C1-C6alkoxy-C1-C4alkoxy-C2-C4alkyl)(C2-C4hydroxyalkyl)-NH(C5-C7cycloalkyl), —N(C5-C7cycloalkyl)2, —NH(C6-C10aryl), NH(C7-C13aralkyl) or a morpholino, piperidino or pyrrolidino residue; M represents H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di-, tri- or tetrasubstituted by C1C4alkyl, C2-C4hydroxyalkyl
    Type: Application
    Filed: July 7, 2003
    Publication date: April 1, 2004
    Inventors: Georges Metzger, Dieter Reinehr, Hanspeter Sauter, Helena Dbaly
  • Publication number: 20030192137
    Abstract: A method for the fluorescent whitening of cotton in a discontinuous process comprising contacting the cotton, I an aqueous bath having a pH value of 6 or less, with one or more compounds of the Formula (I) wherein R1 represents an —SO2R3, —SOR3, CO2M, —CO2R3, —CONR3R4, —CN or —NO2 substituent, R2 is —NH2, —NH(C1-C4alkyl), —N(C1-C4alkyl)2, —NH(C2-C4hydroxyalkyl), —N(C2-C4hydroxyalkyl)2, —NH(C1-C4alkoxy)(C1-C4alkyl), —N[(C1-C4alkoxy)(C1-C4alkyl)]2, NHC2—C4alkylsulphonic acid, morpholineo, piperidino pyrrolidino, an amino acid or amino acid amide residue from which a hydrogen atom on the amino group has been removed, —OC1-C4alkyl or —OC1-C4hydroxyalkyl, R3 and R4 each, independently, represent hydrogen, C1-C4alkyl, C2-C4hydroxyalkyl or C1-C4alkoxyC1-C4alkyl and M, is H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di-, tri- or tetrasubsituted by C1-C4alkyl, C2-C4hydroxyalkyl or a mixture thereof,
    Type: Application
    Filed: April 14, 2003
    Publication date: October 16, 2003
    Inventors: Fabienne Cuesta, Dieter Reinehr, Hans Kramer, GEORGE METZGER, BERND WOCKENFUSS
  • Publication number: 20030148231
    Abstract: A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of the formula (I) 1
    Type: Application
    Filed: November 20, 2002
    Publication date: August 7, 2003
    Inventors: Christophe Bulliard, Georges Metzger, Sonia Megert
  • Publication number: 20030103924
    Abstract: The use of a polymeric carrier material treated with a fluorescent whitening agent, for lightening human skin and for protecting human skin against UV radiation, is described.
    Type: Application
    Filed: June 11, 2002
    Publication date: June 5, 2003
    Inventors: Dieter Reinehr, Helmut Luther, Georges Metzger
  • Publication number: 20030045444
    Abstract: Biphenyl-substituted triazines of the formulae 1
    Type: Application
    Filed: July 31, 2002
    Publication date: March 6, 2003
    Inventors: Ian John Fletcher, Jurgen Kaschig, Georges Metzger, Dieter Reinehr, Pascal Hayoz
  • Patent number: 6528469
    Abstract: A fabric bleaching composition comprising a peroxy compound and a specified manganese compound is disclosed, as well as a process for bleaching and/or cleaning a fabric by contacting it with said fabric bleaching composition.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: March 4, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Georges Metzger
  • Patent number: 6506545
    Abstract: A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of formula (I) wherein X is O or NH; n is 1 or 2, p is 0, 1 or 2, M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an amimoacid residue from which a hydrogen atom on the amino group has been removed; each R2, independendy, is hydrogen, C1-C8alkyl, C1-C8alkoxy, halogen, cyano, COOR, wherein R is hydrogen or C1-C3alky1, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, or SO3M, wherein M has its previous significance, or, if n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl, in that photographic material.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: January 14, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Christophe Bulliard, Georges Metzger, Sonia Megert
  • Patent number: 6482241
    Abstract: The present invention provides, as a first aspect, an asymmetric compound having the formula: in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; Xa and Xb are the same or different and each is NH2; NH(C1-C4alkyl); NH(C2-C4alkoxyalkyl); N(C1-C4alkyl)2; N(CH2CH2OH)2; a group NH—Z—NR1R2 in which Z is C2-C14alkylene or optionally substituted arylene, and R1 and R2 are the same or different and each is C1-C12alkyl or R1 and R2, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; an aminoacid residue; C1-C4alkoxy; hydroxy-substituted-C2-C4alkoxy; and Ya and Yb are the same or different and each is a substituted amino group having both UVA and UVB-absorbing properties having the formula: in which R3 is CN; SO2R5 in which R5 is, C1-C12alkyl, C1-C12alkoxy, NH2, NH(C1-C4alkyl), N(C1-C4alkyl)2, N(CH2CH2OH)2, C1-C4alkoxy or hydroxy-substituted-C2-C4alkoxy;
    Type: Grant
    Filed: September 8, 2000
    Date of Patent: November 19, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Georges Metzger, Dieter Reinehr, Claude Eckhardt, Fabienne Cuesta
  • Publication number: 20020165298
    Abstract: The present invention provides compounds having the formula: 1
    Type: Application
    Filed: December 11, 2001
    Publication date: November 7, 2002
    Inventors: Dieter Reinehr, Georges Metzger, Peter Michaelis, Helmut Luther
  • Patent number: 6468958
    Abstract: Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: October 22, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ian John Fletcher, Jürgen Kaschig, Georges Metzger, Dieter Reinehr, Pascal Hayoz
  • Patent number: 6464735
    Abstract: The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is gl
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: October 15, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Rohringer, Georges Metzger, Dieter Reinehr
  • Patent number: 6458169
    Abstract: The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is gl
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: October 1, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Rohringer, Georges Metzger, Dieter Reinehr
  • Patent number: 6365737
    Abstract: A process for the preparation of a 4,4′-bis-(triazinylamino)-stilbene-2,2′-disulphonic acid compound of formula (1) is disclosed, characterized in that (a) in a first reaction step cyanurchloride is reacted with the disodium salt of 4,4′-diaminostilbene-2,2′-disulfonic acid to give the intermediate of formula (2); (b) in a second reaction step the compound of formula (2) is reacted with a compound of formula R1—H and/or R2—H to give the compound of formula (3); (c) in a third step the compound of formula (3) is reacted with the compound of the formula R3H, and reaction step (a) and/or (c) are carried out in a medium consisting of a mixture of water and a polyglycol to give the compound of formula (1), wherein R1, R2 and R3, independently, are phenylamino; phenylamino substitued by C1-C3alkyl, halogen, cyano, COOR or COR; CONH—R; SO2NH—R; NH—COR; mono- or disulphonated phenylamino; morpholino; piperidino; pyrrolidino; —NH2; —NH
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: April 2, 2002
    Assignee: Ciba Specialty Chemical Corporation
    Inventors: Georges Metzger, Fabienne Cuesta, Peter Rohringer, Dieter Reinehr, René Schlatter
  • Publication number: 20020017001
    Abstract: The present invention provides new compounds having the formula: 1
    Type: Application
    Filed: January 22, 2001
    Publication date: February 14, 2002
    Inventors: Peter Rohringer, George Metzger, Dieter Reinehr
  • Publication number: 20010039341
    Abstract: Biphenyl-substituted triazines of the formulae 1
    Type: Application
    Filed: May 3, 2001
    Publication date: November 8, 2001
    Inventors: Ian John Fletcher, Jurgen Kaschig, Georges Metzger, Dieter Reinehr, Pascal Hayoz
  • Publication number: 20010014989
    Abstract: The present invention provides new compounds having the formula: 1
    Type: Application
    Filed: January 22, 2001
    Publication date: August 23, 2001
    Inventors: Peter Rohringer, Georges Metzger, Dieter Reinehr
  • Patent number: 6255483
    Abstract: Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: July 3, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ian John Fletcher, Jürgen Kaschig, Georges Metzger, Dieter Reinehr, Pascal Hayoz
  • Publication number: 20010003737
    Abstract: A fabric bleaching composition comprising a peroxy compound and a specified manganese compound is disclosed, as well as a process for bleaching and/or cleaning a fabric by contacting it with said fabric bleaching composition.
    Type: Application
    Filed: October 13, 1998
    Publication date: June 14, 2001
    Inventors: DIETER REINEHR, GEORGES METZGER
  • Patent number: 6228127
    Abstract: A bleaching or washing composition comprising a peroxy compound and a specified cobalt compound is disclosed, as well as a process for bleaching or washing a fabric or dishes by contacting them with said bleaching or washing composition.
    Type: Grant
    Filed: April 10, 1998
    Date of Patent: May 8, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Georges Metzger
  • Patent number: 6210449
    Abstract: The present invention provides new compounds having formula (1), in which X is 0 or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is glycine and R2 is H or C
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: April 3, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Rohringer, Georges Metzger, Dieter Reinehr