Patents by Inventor Gerd Heilen

Gerd Heilen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6043338
    Abstract: In a process for the preparation of copolymers of tetrahydrofuran and but-2-yne-1,4-diol by catalytic polymerization of tetrahydrofuran, the polymerization is carried out over a heterogeneous acidic catalyst which has acid centers of acidity pK.sub.a <+2 in a concentration of at least 0.005 mmol/g of catalyst, in the presence of but-2-yne-1,4-diol. In particular, for the preparation of polyoxytetramethylene glycol, the copolymers are reacted in the presence of hydrogen over a hydrogenation catalyst.
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: March 28, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Christoph Sigwart, Rolf Fischer, Karsten Eller, Rainer Becker, Klaus-Dieter Plitzko, Gerd Heilen
  • Patent number: 5939590
    Abstract: Tetrahydrofuran/but-2-yne-1,4-diol copolymers containing C--C triple bonds and having an average molecular weight M.sub.n of from 500 to 3500 Dalton and a content of from 0.5 to 3 mol of triple bonds/mol of copolymer and blends of these copolymers with polytetrahydrofuran having an average molecular weight M.sub.n of from 500 to 3500 Dalton, processes for their preparation and their use.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: August 17, 1999
    Assignee: Basf Aktiengesellschaft
    Inventors: Christoph Sigwart, Rolf Fischer, Rainer Becker, Klaus-Dieter Plitzko, Gerd Heilen, Christof Palm, Peter Groll
  • Patent number: 5773648
    Abstract: A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C.sub.1 -C.sub.10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C.sub.1 -C.sub.10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500.degree. to 1000.degree. C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: June 30, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Becker, Christoph Sigwart, Michael Hesse, Rolf Fischer, Karsten Eller, Gerd Heilen, Klaus-Dieter Plitzko
  • Patent number: 4806670
    Abstract: .beta.-Dicarbonyl and .beta.-cyanocarbonyl compounds ##STR1## where R.sup.1 is alkyl of 1-20 carbons, X is --COR.sup.2, Y is --COOR.sup.3, --COR.sup.3 or --CN, and R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.10 -alkyl, are prepared from R.sup.1 --CHO (II) and X--CH.sub.2 --Y (III) by reaction in the presence of a condensation catalyst, hydrogen and a hydrogenation catalyst, using an oxide or phosphate of Mg, Al, Ti, Zn or a rare earth metal as the condensation catalyst.
    Type: Grant
    Filed: May 4, 1987
    Date of Patent: February 21, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Gramlich, Klaus Halbritter, Gerd Heilen
  • Patent number: 4739051
    Abstract: Morpholine and other cyclic imines are obtained by reacting diethylene glycol and other appropriate diols with ammonia under hydrogenating conditions in the gas phase in the presence of a catalyst which contains copper, a smaller amount of nickel and alumina.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: April 19, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Schroeder, Wolfgang Lengsfeld, Gerd Heilen, Otto Hertel, Guenter Boettger
  • Patent number: 4684392
    Abstract: New substituted .beta.-triazolyl oximes, processes for their manufacture, agents for regulating plant growth containing these compounds, and a process for regulating plant growth with these compounds.
    Type: Grant
    Filed: January 9, 1985
    Date of Patent: August 4, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Costin Rentzea, Hubert Sauter, Bernd Zeeh, Gerd Heilen, Johann Jung
  • Patent number: 4684743
    Abstract: .beta.-Dicarbonyl, .beta.-cyanocarbonyl and .beta.-dicyano compounds I ##STR1## where R.sup.1 is an organic radical, X and Y are COOR.sup.2, --CO--R.sup.2 or --CN and R.sup.2 is an organic radical, are prepared from R.sup.1 --CHO (II) and X--CH.sub.2 --Y (III) by reaction in the presence of a condensation catalyst, hydrogen and a hydrogenation catalyst, using an oxide or phosphate of Mg, Al, Ti, Zn or a rare earth metal as the condensation catalyst.
    Type: Grant
    Filed: October 1, 1985
    Date of Patent: August 4, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Gramlich, Klaus Halbritter, Gerd Heilen
  • Patent number: 4532234
    Abstract: .alpha.-Neopentyl-phenethyltriazoles of the formula I ##STR1## where R.sup.1, m and A have the meanings given in the description, processes for their preparation, and their use for controlling fungi.
    Type: Grant
    Filed: September 7, 1983
    Date of Patent: July 30, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Ernst Buschmann, Guenter Schulz, Gerd Heilen, Ernst-Heinrich Pommer, Eberhard Ammermann
  • Patent number: 4532337
    Abstract: 3-Formyl-5,6-dihydro-2H-pyran is prepared by conversion of acrolein in the presence of water, acids and halohydrocarbons of 1 to 6 carbon atoms and 1 to 6 halogen atoms as solvents at from 60.degree. to 150.degree. C. The 3-formyl-5,6-dihydro-2H-pyran obtained by the novel process is a valuable starting material for the preparation of dyes and crop protection agents.
    Type: Grant
    Filed: February 28, 1984
    Date of Patent: July 30, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Eckhardt, Klaus Halbritter, Norbert Goetz, Gerd Heilen
  • Patent number: 4521602
    Abstract: A pyridine or a pyrrole is obtained in a one-stage process directly from an .alpha.,.omega.-dinitrile of appropriate carbon skeleton when the dinitrile is reacted in the gas phase with hydrogen, over a hydrogenation catalyst.
    Type: Grant
    Filed: June 9, 1983
    Date of Patent: June 4, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Rebafka, Gerd Heilen, Klaus Halbritter, Wolfgang Franzischka
  • Patent number: 4374274
    Abstract: A process for the preparation of .alpha.-methylsubstituted ketones by reacting the corresponding non-methylsubstituted ketones with formaldehyde under hydrogenating conditions. The reaction proceeds easily and with good yields if a catalyst containing metallic palladium deposited on a zirconium, hafnium, titanium or tin phosphate is used. The products are valuable intermediates for the preparation of dyes, crop protection agents or drugs.
    Type: Grant
    Filed: September 11, 1980
    Date of Patent: February 15, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Heilen, Klaus Halbritter, Walter Gramlich
  • Patent number: 4328028
    Abstract: Agents for regulating plant growth containing ketone derivatives bearing an azolyl radical in the .beta.-position to the keto group, and a process for regulating plant growth with these compounds.
    Type: Grant
    Filed: August 25, 1978
    Date of Patent: May 4, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Costin Rentzea, Johann Jung, Hubert Sauter, Gerd Heilen, Bernd Zeeh
  • Patent number: 4319055
    Abstract: A process for removing formaldehyde from aqueous solutions of but-2-yne-1,4-diol by treating the solutions with an alkaline agent at an elevated temperature in the presence of hydrogen peroxide.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: March 9, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Rebafka, Gerd Heilen, Werner Fliege
  • Patent number: 4278800
    Abstract: New .gamma.-azolyl compounds, especially ethers, esters and carbamates, processes for their manufacture, agents for influencing plant growth which contain these compounds as active ingredients, and processes for regulating plant growth with these compounds.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: July 14, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Costin Rentzea, Hubert Sauter, Eberhard Ammermann, Gerd Heilen, Johann Jung
  • Patent number: 4273945
    Abstract: Saturated aliphatic, cycloaliphatic and araliphatic aldehydes are prepared by selective hydrogenation of the corresponding olefinically unsaturated aldehydes with hydrogen in the liquid phase over a palladium-containing catalyst, using a catalyst system in which the active constituents are from 2 to 90% by weight of palladium and from 10 to 98% by weight of an oxide or a salt of a rare earth metal or of a mixture of different oxides and/or salts of this type.
    Type: Grant
    Filed: July 5, 1979
    Date of Patent: June 16, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Heilen, Axel Nissen, Wolfgang Koernig, Michael Horner, Werner Fliege, Guenter Boettger
  • Patent number: 4270006
    Abstract: Aliphatic carbonyl compounds are prepared by an aldol condensation of carbonyl compounds R.sup.1 --CH.sub.2 --CO--R.sup.2 (I; R.sup.1 and R.sup.2 =H or C.sub.1 -C.sub.8 -alkyl) in the presence of hydrogen and of a catalyst which has both condensing and hydrogenating properties, by using a catalyst system wherein the active components are from 1 to 90 percent by weight of a noble metal of group VIII of the periodic table and from 10 to 99 percent by weight of an oxide or salt of a rare earth metal, or of a mixture of different oxides and/or salts of rare earth metals.
    Type: Grant
    Filed: December 27, 1979
    Date of Patent: May 26, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Heilen, Axel Nissen, Otto Woerz
  • Patent number: 4212825
    Abstract: Aldehydes or ketones of not less than 4 or 5 carbon atoms, respectively, are manufactured in a one stage process in the liquid phase by subjecting aldehydes and/or ketones of not less than 2 or 3 carbon atoms, respectively, to an aldol condensation and hydrogenating the resulting olefinically unsaturated aldehyde, the catalyst used for the aldol condensation and hydrogenation containing a mixture of nickel and cobalt, zinc oxide and at least one of the elements iron, arsenic, antimony, bismuth, gallium, indium, thallium, germanium, tin, lead, cadmium and mercury or compounds of the said elements.
    Type: Grant
    Filed: November 16, 1977
    Date of Patent: July 15, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Axel Nissen, Gerd Heilen, Ekkehard Sapper, Werner Fliege, Arnold Wittwer
  • Patent number: 4146581
    Abstract: A process for the manufacture of higher ketones by reacting an aldehyde with a ketone in the presence of hydrogen over a catalyst system which contains, firstly, oxides or salts of the rare earth metals and, secondly, metals of group VIII of the periodic table of the elements. The process gives numerous higher ketones, required, for example, as solvents for surface coatings, or as scents, with high conversions and good selectivities, and therefore more simply and more economically than conventional methods.
    Type: Grant
    Filed: March 30, 1977
    Date of Patent: March 27, 1979
    Assignee: BASF Aktiengesellschaft
    Inventors: Axel Nissen, Otto Woerz, Gerd Heilen, Werner Fliege, Arnold Wittwer