Patents by Inventor Gerhard Brindopke
Gerhard Brindopke has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20090221465Abstract: An aqueous mixture AB comprising, in its solids, a mass fraction of from 5 % to 40 % of a polyvinyl butyral B, and a mass fraction of from 60 % to 95 % of a Mannich base A which is made by a two-step reaction wherein an epoxy amine adduct A1 prepared in the first step from an epoxy resin A11 with a mixture A12 of a primary linear or branched aliphatic amine A121 having from 2 to 30 carbon atoms and a further aliphatic linear, branched or cyclic amine A122 having from 4 to 16 carbon atoms and having one primary and at least one tertiary amino group, which epoxy amine adduct A1 is reacted in die second step with formaldehyde and a phenolic compound A2 to form a Mannich base, and a method of use thereof as a binder in wash primers.Type: ApplicationFiled: March 1, 2007Publication date: September 3, 2009Inventors: Willibald Paar, Manfred Krassnitzer, Gerhard Brindöpke
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Patent number: 7262261Abstract: Condensation products of dihydroxyaromatics A, alone or in mixture with mono- or polyhydroxyaromatics C, with diepoxides or polyepoxides B which have been alkylolated by reaction with aldehydes D and whose alkylol groups may have been etherified with alcohols, a process for preparing them, and a method of use thereof in particular as compositions for coating the inside of foodstuff and beverage packaging forms made from metals.Type: GrantFiled: November 6, 2003Date of Patent: August 28, 2007Assignee: Surface Specialities Germany GmbH & Co. KGInventors: Gerhard Brindöpke, Oliver Etz, Paul Oberressl, Bodo Wixmerten
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Publication number: 20040092674Abstract: Condensation products of dihydroxyaromatics A, alone or in mixture with mono- or polyhydroxyaromatics C, with diepoxides or polyepoxides B which have been alkylolated by reaction with aldehydes D and whose alkylol groups may have been etherified with alcohols, a process for preparing them, and a method of use thereof in particular as compositions for coating the inside of foodstuff and beverage packaging forms made from metals.Type: ApplicationFiled: November 6, 2003Publication date: May 13, 2004Applicant: Surface Specialties Germany GmbH & Co. KGInventors: Gerhard Brindopke, Oliver Etz, Paul Oberressl, Bodo Wixmerten
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Patent number: 5169979Abstract: The invention relates to a curing component (A) containing active CH groups, which contains at least two groups of the formula (I) ##STR1## or structural units of the formula (I') or (I") ##STR2## in which: A denotes ##STR3## X and Y are identical or different and denote ##STR4## CO.sub.2 R.sup.1, CN, NO.sub.2, CONH.sub.2, CONR.sup.1 H or CONR.sup.1 R.sup.1, where the R.sup.1 radicals may be identical or different and represent a hydrocarbon radical, preferably an alkyl radical having 1 to 12 carbon atoms, which may also be interrupted by oxygen or an N-alkyl radical, with the proviso that only one of the two radicals X and Y may represent the NO.sub.2 group;A' denotes ##STR5## X' and Y' are identical or different and denote ##STR6## Curable mixtures of (A) and a Michael acceptor (B) and, if appropriate diluents and customary additivies cure rapidly even at low temperatures and are suitable, in particular for surface-coating preparations.Type: GrantFiled: November 30, 1990Date of Patent: December 8, 1992Assignee: Hoechst AGInventors: Uwe Kubillus, Gerhard Brindopke, Helmut Plum
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Patent number: 5159024Abstract: Curing product based onA) compounds having at least two R.sup.1 R.sup.2 C.dbd.CR.sup.3 --X groups (I) andB) compounds having methanetricarboxamide units of the formula ##STR1## these compounds B) containing at least two groups having active H atoms of the type ##STR2## In order to prepare this curing product, the compounds A) and B) of an oligomeric and/or polymeric reaction product are reacted in the presence of at least one catalyst. The mixtures of A) and B) can be used as two-component lacquers on their own or together with customary additives.Type: GrantFiled: November 19, 1986Date of Patent: October 27, 1992Assignee: Hoechst AGInventors: Gerhard Brindopke, Gerd Walz
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Patent number: 5126424Abstract: Products of the reaction of (a) a polyisocyanate, (b) a CH-active alkyl ester, (c) a polyoxyalkyleneamine and (d) if appropriate a further NH- and/or OH-reactive compound as the curing component for binders (B) which contain groups which are capable of amide and/or ester formation.Mixtures of (A) and (B), and where appropriate diluents (C) and additives (D), have a long shelf life, even in aqueous systems, and are particularly suitable for aqueous paint formulations.Type: GrantFiled: January 26, 1990Date of Patent: June 30, 1992Assignee: Hoechst AGInventors: Gerhard Brindopke, Helmut Plum
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Patent number: 5084536Abstract: A 3-component lacquer composed of A) compounds containing at least two R.sup.1 R.sup.2 C.dbd.CR.sup.3 --X groups (I) wherein R.sup.1 denotes hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms, R.sup.2 and R.sup.3 are individually hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, an ester group containing the radical R.sup.4 of a monohydric alcohol having up to 12 carbon atoms, --CN, --NO.sub.2 or a --CO--NHR.sup.1 or --CO--R.sup.1 group, X is --CO-- which is attached to a further R.sup.1 R.sup.2 C.dbd.CR.sup.Type: GrantFiled: June 26, 1989Date of Patent: January 28, 1992Assignee: Hoechst AGInventors: Gerhard Brindopke, Gerd Walz, Karl Waldmann, Manfred Schon, Hans-Jerg Kleiner
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Patent number: 5039720Abstract: An aqueous electrophoretic coating material, which can be deposited at the cathode and contains(A) 90 to 50% by weight, based on the total portion of synthetic resin vehicle, of one or several polycondensation, polymerization and/or poly-addition resins, the resin or, in the event that several resins are present, their mixture(a) having a number average molecular weight (Mn) of 700 to 10,000(b) having 1.2.times.10.sup.23 to 21.7.times.10.sup.23 lateral or terminal double bonds per 1,000 g, corresponding to a hydrogenation iodine number of 5 to 90,(c) optionally containing primary and/or secondary hydroxyl groups, corresponding to a hydroxyl number of 0 to 450 mg KOH/g of resin, and(d) tertiary amino groups corresponding to an amine number of 30 to 450 mg KOH/g of resin.Type: GrantFiled: September 30, 1988Date of Patent: August 13, 1991Assignee: Hoechst AktiengesellschaftInventors: Dietrich Saatweber, Georg Hendriux, Gerhard Brindopke, Helmut Plum
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Patent number: 4892954Abstract: Process for the preparation of 2-oxo-1,3-dioxolanes by reaction of epoxides with carbon dioxide in the presence of a catalyst, wherein at least one epoxy compound is mixed with at least one catalyst in the presence or absence of an inert solvent and is reacted at temperatures from 40.degree. to 180.degree. C. while introducing carbon dioxide at normal pressure or slightly increased pressure to form the corresponding organic carbonates. The 2-oxo-1,3-dioxolanes obtained are used to prepare synthetic resins containing urethane groups in the form of coatings and molded bodies.Type: GrantFiled: October 21, 1987Date of Patent: January 9, 1990Assignee: Hoechst AGInventors: Gerhard Brindopke, Manfred Marten
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Patent number: 4882391Abstract: Non-crosslinked reaction products of compounds (A) which contain structural units carrying 1,3-dioxolan-2-one groups in random distribution and compounds (B) which contain at least one primary aliphatic or cycloaliphatic amino group and additionally at least one further basic amino group.These reaction products are suitable, if appropriate together with conventional curing agents, especially as binders for coatings, above all electrodip coatings.Type: GrantFiled: December 22, 1987Date of Patent: November 21, 1989Assignee: Hoechst AGInventors: Gerhard Brindopke, Michael Honel
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Patent number: 4871822Abstract: A reaction product of (A) compounds containing at least two R.sup.1 R.sup.2; C.dbd.CR.sup.3 --X groups (I) with (B) compounds which contain(a) at least two active H atoms or(b) at least two groups containing active H atoms of the type --AH-- (II) or(c) at least one active H atom and at least one group of the type (III),or which form the corresponding amount of this group (II), in which, the formula (I),X denotes --CO-- which is attached to a further R.sup.1 R.sup.2 C.dbd.CR.sup.3 group either directly or via the radical of a polyhydric alcohol or of an amine,R.sup.1 denotes hydrogen or a hydrocarbon radical having 1 to 10, preferably 1 to 4, carbon atoms, such as alkyl, phenyl, benzyl or naphthyl,R.sup.2 denotes hydrogen, a hydrocarbon radical having 1 to 10, preferably 1 to 4, carbon atoms, such as alkyl, phenyl, benzyl or naphthyl, an ester group containing the radical R.sup.4 of a monohydric alcohol having up to 12 carbon atoms, --CN, --NO.sub.2 or a CO--NHR.sup.1 or CO--R.sup.1 group, andR.sup.Type: GrantFiled: June 16, 1986Date of Patent: October 3, 1989Assignee: Hoechst AGInventors: Gerhard Brindopke, Gerd Walz, Karl Waldmann, Manfred Schon, Hans-Jerg Kleiner
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Patent number: 4859788Abstract: Amino group containing curing component (A) for compounds (B) which contain epoxy or 1,3-dioxolan-2-one groups, comprising a reaction product of (a.sub.1) active CH alkyl esters of isocyanate adducts thereof with (a.sub.2) polyamines.Mixtures of (A) and (B) with or without diluents and additives give rapid curing even at low temperatures and high atmospheric humidity and are suitable in particular for paint formulations.Type: GrantFiled: April 7, 1988Date of Patent: August 22, 1989Assignee: Hoechst AGInventors: Gerhard Brindopke, Claus Godau, Walter Weber
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Patent number: 4837271Abstract: Curable mixtures based on(A) compounds containing hydroxyl groups,(B) curable compounds,(C) catalysts and(D) if appropriate a diluent and if appropriate further additives,in which compounds which are used as the curing compounds(B) are those which contain at least two enol ether groups of the formula (I) ##STR1## The mixtures according to the invention already cure rapidly at low temperatures and are particularly suitable for the production of shaped articles or coatings or as a constituent in lacquers.Type: GrantFiled: June 23, 1988Date of Patent: June 6, 1989Assignee: Hoechst AGInventor: Gerhard Brindopke
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Patent number: 4835289Abstract: A process for the preparation of 2-oxo-1,3-dioxolanes by reaction of epoxides with carbon dioxide in the presence of alkali iodides wherein at least one epoxy compound is reacted in the presence or absence of inert solvent either with a combination of A) at least one alkali iodide and B) at least one compound of the group a) polyol and b) an ether or polyether or, if the epoxy compound already has the structural features of the compounds Ba) and Bb), with the alkali iodide A) alone, at temperatures from 40.degree. to 180.degree. C. while introducing carbon dioxide at normal pressure or at slightly increased pressure, to form the corresponding organic carbonates. The 2-oxo-1,3-dioxolanes obtained are used for the preparation of synthetic resins, containing urethane groups, in the form of coatings of molded bodies.Type: GrantFiled: January 8, 1987Date of Patent: May 30, 1989Assignee: Hoechst AGInventor: Gerhard Brindopke
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Patent number: 4806611Abstract: Aminourethanes, a process for their preparation and their useThe invention relates to aminourethanes composed essentially of structural units derived from(A) polyamines of the general formula (I) an/or (II ##STR1## (B) if appropriate, further polyamines, (C) compounds containing, on average, at least one terminal 2-oxo-1,3-dioxolane group per molecule and(D) if appropriate, compounds having a monofunctional reaction, as chain stoppers.The invention also relates to a process for the preparation of these aminourethanes and to their use, in particular in paint formulations and especially in electrodeposition paints.Type: GrantFiled: December 22, 1987Date of Patent: February 21, 1989Assignee: Hoechst AktiengesellschaftInventors: Michael Honel, Peter Ziegler, Gerd Walz, Rudiger Lenz, Hartmut Foedde, Gerhard Brindopke
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Patent number: 4772666Abstract: Curable mixtures based on(A) compounds containing 1,3-dioxolan-2-one groups, groups capable of reaction with isocyanate groups and, if appropriate, further groups,(B) polyisocyanates and/or aminoplast resins and(C) if appropriate, further curing compounds.The coatings obtainable from these mixtures are distinguished above all by rapid curing and by good solvent stability and good adhesive power.Type: GrantFiled: December 22, 1987Date of Patent: September 20, 1988Assignee: Hoechst AktiengesellschaftInventors: Christoph Just, Helmut Durr, Gerhard Brindopke
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Patent number: 4758615Abstract: Polymers which contain urethane groups and are capable of being crosslinked by extraneous crosslinking agents, solutions thereof and aqueous dispersions thereof, prepared without the use of isocyanates by reacting polyamino compounds with polycarbonates and, if appropriate, reacting the reaction product further with polycarboxylic acids to give products having an acid number between 0 and 100, and, if appropriate, neutralizing the resulting products partly or completely by adding basic compounds, preferably organic bases, and, if appropriate, mixing the partly or completely neutralized products vigorously with an amount of water such that aqueous polymer dispersions having a solids content of up to 75% by weight, relative to the dispersion, are obtained.Type: GrantFiled: May 22, 1987Date of Patent: July 19, 1988Assignee: Hoechst AGInventors: Dieter Engel, Christoph Just, Gerhard Brindopke, Gerd Walz
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Patent number: 4657962Abstract: Finely divided coating agents based on (A) oligomers and/or polymers containing OH groups and (B) blocked polyisocyanates and, if required, further conventional additives, in which the component (B) contains at least one acylurethane possessing groups of the formula --CO--NH--CO--XR.sup.1 (I), wherein X represents oxygen or nitrogen, and, when X is oxygen, R.sup.1 represents alkyl, alkoxyalkyl, hydroxyalkyl, aryl, aralkyl or cycloalkyl, and, when X is nitrogen, the radical XR.sup.1 represents the group ##STR1## wherein R.sup.2 is C.sub.1-11 -alkylene, C.sub.1-11 -alkenylene, or unsubstituted or alkyl-substituted phenylene having up to 8 carbon atoms in the alkyl radical, and Y and Z together form an oxygen atom, or are identical or different and each denote hydrogen or C.sub.1-5 -alkyl, the coating agent being present in powder form or in the form of a dispersion. The coating agent is used for coating articles exposed to weather, and as top coats and primers.Type: GrantFiled: June 6, 1985Date of Patent: April 14, 1987Assignee: Hoechst AKInventors: Gerhard Brindopke, Gerhard Johannes
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Patent number: 4608420Abstract: Process for the preparation of acylurethanes by reacting a urethane with compounds containing hydroxyl groups, which comprises reacting a hydroxy compound (A) with a urethane (B) in the form of an imide of the formula ##STR1## to give an acylurethane containing at least one grouping of the formula --CO--R--CO--NH--COOR.sup.1 (II). In these formulae,R denotes the hydrocarbon radical of an optionally .alpha.,.beta.-ethylenically unsaturated, aliphatic, cycloaliphatic or aromatic dicarboxylic acid or endomethylene derivatives thereof, andR.sup.1 denotes alkyl, alkoxy, alkoxyalkyl, cycloalkyl or benzyl.These acylurethanes are suitable for use as self-crosslinking curing agents or as curing agents for polyhydroxy compounds for the production of shaped articles and/or coatings.Type: GrantFiled: June 6, 1985Date of Patent: August 26, 1986Assignee: Hoechst AktiengesellschaftInventors: Gerhard Brindopke, Gerhard Johannes