Patents by Inventor Gerhard Heinz
Gerhard Heinz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4925910Abstract: Copolycondensate molding materials are obtainable by polycondensation offrom 2 to 98 mol % of 2,2-di-(4'-hydroxyphenyl)-propane (A),from 2 to 98 mol % of 4,4'-dihydroxydiphenyl sulfone (B) andfrom 0 to 96 mol % of (C) ##STR1## where R.sup.1 and R.sup.2 are each H, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy, X is a chemical bond, --S--, --O--, --CO--, CR.sup.3 R.sup.4 (where R.sup.3 and R.sup.4 are different when n and p are each 0), or SO.sub.2 -- only when n or p is 0), R.sup.3 and R.sup.4 are each H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl or halogen-substituted alkyl of 1 to 4 carbon atoms, m is 0 or 1, and n and p are each 0, 1, 2, 3, or 4,with from 1 to 100 mol % of (D) ##STR2## where R.sup.5 and R.sup.6 have the same meaning as R.sup.1 and R.sup.2, and v and w are each 0, 1, 2, 3 or 4, and from 0 to 99 mol % of (E) ##STR3## where R.sup.7 -R.sup.10 are each Cl or F or have the same meanings as R.sup.1 and R.sup.2, q is 0 or 1, r, s, t and n are each 0, 1, 2, 3 or 4, Z.sub.Type: GrantFiled: April 9, 1987Date of Patent: May 15, 1990Assignee: BASF AktiengesellschaftInventor: Gerhard Heinz
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Patent number: 4904754Abstract: Copolycondensate molding materials are obtainable by polycondensation offrom 2 to 98 mol % of 2,2-di-(4'-hydroxyphenyl)-propane (A),from 2 to 98 mol % of 4,4'-dihydroxydiphenyl sulfone (B) andfrom 0 to 96 mol % of (C) ##STR1## where R.sup.1 and R.sup.2 are each H, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy, X is a chemical bond, --S--, --O--, --CO--, CR.sup.3 R.sup.4 (where R.sup.3 and R.sup.4 are different when n and p are each 0), or SO.sub.2 -- (only when n or p is not 0), R.sup.3 and R.sup.4 are each H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl or halogen-substituted alkyl of 1 to 4 carbon atoms, m is 0 or 1, and n and p are each 0, 1, 2, 3 or 4, withfrom 1 to 100 mol % of (D) ##STR2## where R.sup.5 and R.sup.6 have the same meanings as R.sup.1 and R.sup.2, and v and w are each 0, 1, 2, 3 or 4, and from 0 to 99 mol % of (E) ##STR3## where R.sup.7 -R.sup.10 are each Cl or F or have the same meanings as R.sup.1 and R.sup.2, q is 0 or 1, r, s, t and n are each 0, 1, 2, 3 or 4, Z.sub.Type: GrantFiled: September 9, 1988Date of Patent: February 27, 1990Assignee: BASF AktiengesellschaftInventor: Gerhard Heinz
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Patent number: 4880876Abstract: Thermoplastic polyester molding materials having low-temperature impact strength essentially consist of(A) from 20 to 79 parts by weight of one or more aliphatic polyesters of an aromatic dicarboxylic acid having a relative viscosity of from 1.2 to 1.8,(B) from 20 to 79 parts by weight of one or more aromatic polycarbonates having a relative viscosity of from 1.2 to 1.5,(C) from 1 to 40 parts by weight of an elastomer blend consisting of1. from 5 to 95% by weight of an ethylene copolymer composed of(a) from 40 to 99% by weight of ethylene and(b) from 1 to 60% by weight of one or more comonomers containing carboxyl groups and/or derivatives of carboxyl groups, and2. from 5 to 95% by weight of an elastomeric graft polymer which is prepared by emulsion polymerization and composed of(a) from 70 to 95% by weight of a substantially crosslinked grafting base having a glass transition temperature T.sub.g below -20.degree. C.Type: GrantFiled: May 2, 1988Date of Patent: November 14, 1989Assignee: BASF AktiengesellschaftInventors: Hans-Henning Hub, Georg N. Simon, Gerhard Heinz, Walter Ziegler, Juergen Sadlowski
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Patent number: 4867912Abstract: Highly heat-resistant polyaryl ether ketones are composed of(A) from 50 to 100 mol % of repeat units of the general formula I ##STR1## or a ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivative thereof and(B) from 0 to 50 mol % of repeat units, different from I, of the general formulae II and/or III ##STR2## or a ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivative thereof, where Q, Q', Y, Y', T, T', Z and Z' are each --O--, --CO-- or a chemical bond, one or more of these substituents is a --CO-- group, and s, t and u are each 0 or 1.Type: GrantFiled: January 11, 1988Date of Patent: September 19, 1989Assignee: BASF AktiengesellschaftInventors: Gerhard Heinz, Juergen Koch, Manfred Eggersdorfer, Jochem Henkelmann, Helmut Muenstedt, Peter Ittemann
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Patent number: 4837296Abstract: Polyaryl ether ketones are prepared by reacting aromatic dihydroxy compounds with aromatic dihalogen compounds in polar aprotic solvents in the presence of alkali metal carbonates, in particular by reacting aromatic dihydroxy compounds I ##STR1## or ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivatives thereof, n and m each being 0 or 1, with aromatic dihalogen compounds ##STR2## or ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivatives thereof, r and s each being 0 or 1, A being oxygen or a chemical bond and X being chlorine or fluorine.Type: GrantFiled: January 11, 1988Date of Patent: June 6, 1989Assignee: BASF AktiengesellschaftInventors: Gerhard Heinz, Juergen Koch, Manfred Eggersdorfer, Jochem Henkelmann
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Patent number: 4835242Abstract: Aryl ether ketones of the general formula I ##STR1## where n is from 0 to 5,X is ##STR2## and Y is tert-butyl, acetyl, benzyl, benzoyl, tert-butoxycarbonyl or, in the case of n=0, H,and the ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivatives thereof are useful for preparing highly heat-resistant polyaryl ether ketones.Type: GrantFiled: January 11, 1988Date of Patent: May 30, 1989Assignee: BASF AktiengesellschaftInventors: Manfred Eggersdorfer, Jochem Henkelmann, Gerhard Heinz, Juergen Koch
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Patent number: 4798855Abstract: Thermoplastic molding materials contain, as essential components,(A) from 2 to 97.9% by weight of a nylon,(B) from 2 to 97.9% by weight of a polyaryl ether sulfone(C) from 0.1 to 30% by weight of a polymeric component having hydroxyl groupsand in addition(D) from 0 to 50% by weight of a rubber impact modifier and(E) from 0 to 60% by weight of reinforcing fillers.Type: GrantFiled: May 13, 1987Date of Patent: January 17, 1989Assignee: BASF AktiengesellschaftInventors: Dietrich Lausberg, Gerd Blinne, Peter Ittemann, Gerhard Heinz, Erhard Seiler, Manfred Knoll
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Patent number: 4764397Abstract: Fiber-reinforced materials are produced by a process in which a heat-stable thermoplastic aromatic polyether A containing reactive groups, preferably nitrile groups and/or sulfur bridges and/or arylthio or alkylthio groups, if required together with a heat-stable thermoplastic polymer B which does not contain any reactive groups, is applied onto reinforcing fibers, the resulting semi-finished product is shaped, and the plastic matrix in the molding obtained is crosslinked so that there is virturally no increase in its glass transition temperature although the amount of soluble material is decreased to less than 60%, determined by extraction in boiling dichloromethane for one hour.Type: GrantFiled: December 30, 1985Date of Patent: August 16, 1988Assignee: BASF AktiengesellschaftInventors: Juergen Fischer, Hartmut Zeiner, Dietmar Nissen, Gerhard Heinz
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Patent number: 4762869Abstract: High temperature resistant molding materials containing(A) 5-95 mol % of blocks having the structural unit I ##STR1## (B) 5-95 mol % of blocks having the structural unit II ##STR2## (C) 0-80 mol % of blocks having the structural unit III ##STR3## the molecular weight of the blocks being within the range 2000-20,000, where X is --O--, --S--, ##STR4## (only if a or b.noteq.0), ##STR5## (R.sup.7 =R.sup.8 =CH.sub.3 only if a or b.noteq.O) or a chemical bond, R.sup.7 and R.sup.8 are each alkoxy or alkyl of 1-6 carbon atoms, aryl or hydrogen, Q and W are each ##STR6## Z is --O-- or a chemical bond and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each alkyl or alkoxy of 1-6 carbon atoms, aryl, Cl or F and p, q and r are each 0 or 1 and a, b, c, d and e are each 0, 1, 2, 3 or 4.Type: GrantFiled: April 16, 1987Date of Patent: August 9, 1988Assignee: BASF AktiengesellschaftInventors: Gerhard Heinz, Hermann Buchert, Juergen Koch, Georg N. Simon, Peter Ittemann, Hartmut Zeiner
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Patent number: 4751274Abstract: In the preparation of block copolyethers which contain sulfonyl and keto groups by polycondensation of aromatic dihalogen compounds and bisphenols in the presence of an alkali metal carbonate in N-methylpyrrolidin-2-one as a solvent, an amorphous polyether sulfone block having a molecular weight Mn of from 1,500 to 30,000 is prepared in a first stage, and, in a second stage, a polyetherketone block is polymerized onto the living chain ends, the molar ratio of sulfonyl to keto groups being from 90:10 to 40:60.Type: GrantFiled: January 12, 1987Date of Patent: June 14, 1988Assignee: BASF AktiengesellschaftInventors: Peter Ittemann, Gerhard Heinz
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Patent number: 4672086Abstract: Self-extinguishing thermoplastic polyester molding materials containing linear aromatic polyesters, polyphenylene ethers and additives containA. from 20 to 50% by weight of polyethylene terephthalate and/or polybutylene terephthalate, as much as 20 mol % of which may be modified with other dicarboxylic acids and/or diols,B. from 10 to 40% by weight of one or more polyphenylene ethers,C. from 5 to 15% by weight of one or more alkali metal or alkaline earth metal phosphates, high-boiling phosphoric acid esters, phosphorous acid esters, phosphinic acid esters or phosphonous acid esters or organic phosphine oxides,D. from 5 to 30% by weight of framework-forming fillers,E. from 0 to 30% by weight of one or more aromatic polycarbonates,F. from 0 to 30% by weight of glass fibers,G. from 0 to 20% by weight of one or more elastomeric polymers,H. from 0 to 20% by weight of one or more styrene polymers, the percentages of components A to H summing to 100, andI. if required, additives in effective amounts.Type: GrantFiled: December 2, 1985Date of Patent: June 9, 1987Assignee: BASF AktiengesellschaftInventors: Erhard Seiler, Juergen Hambrecht, Gerhard Heinz
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Patent number: 4666973Abstract: Impact-resistant thermoplastic polyester molding materials are prepared by thoroughly mixingA. from 52 to 99 parts by weight of a melt of one or more polyalkylene terephthalates withB. from 1 to 48 parts by weight of one or more elastomeric graft polymers prepared by emulsion polymerization and composed of1. from 70 to 90% by weight of a grafting base consisting of elastomeric polymers having a gel content of not less than 80% and a glass transition temperature Tg of less than -20.degree. C. and2. from 10 to 30% by weight of a grafted shell consisting of one or more polymers having a glass transition temperature Tg greater than 40.degree. C.,in the form of an aqueous dispersion in which not less than 80% of the particles of graft polymer B have a size of from 0.05 to 0.15 .mu.m, with simultaneous removal of the water which vaporizes.Type: GrantFiled: December 2, 1985Date of Patent: May 19, 1987Assignee: BASF AktiengesellschaftInventors: Gerhard Heinz, Graham E. McKee, Georg N. Simon, Friedrich Kleber, Manfred Knoll
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Patent number: 4665150Abstract: A curable epoxy resin mixture containing an adduct of an epoxy resin with a bifunctional phenol or a bifunctional aromatic carboxylic acid of the formula ##STR1## where A=SO.sub.2 or CO, Ar is ##STR2## and X is OH or COOH, and an aromatic amine as a curing agent.Type: GrantFiled: April 16, 1986Date of Patent: May 12, 1987Assignee: BASF AktiengesellschaftInventors: Helmut Tesch, Michael Portugall, Herbert Stutz, Gerhard Heinz
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Patent number: 4649080Abstract: Fiber-reinforced materials are produced by a process in which a heat-stable thermoplastic aromatic polyether A which contains reactive groups, preferably nitrile groups and/or sulfur bridges and/or arylthio or alkylthio groups, if necessary together with a heat-stable thermoplastic polymer B which does not contain any reactive groups, is applied onto reinforcing fibers, the resulting semi-finished product is molded and, in the molding obtained, the plastic matrix is crosslinked so that the glass transition temperature increases and it becomes virtually insoluble.Type: GrantFiled: May 8, 1985Date of Patent: March 10, 1987Assignee: BASF AktiengesellschaftInventors: Juergen Fischer, Hartmut Zeiner, Dietmar Nissen, Gerhard Heinz, Peter Neumann
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Patent number: 4645785Abstract: Thermoplastic polyoxymethylene molding materials having high abrasion resistance contain(A) from 4 to 94.7 parts by weight of polyoxymethylene,(B) from 5 to 50 parts by weight of wollastonite,(C) from 0.2 to 5 parts by weight of N-hydroxymethylmelamines in which some or all of the hydroxymethyl groups are etherified with alkanols,(D) from 0.1 to 5 parts by weight of a silicone oil having a degree of polycondensation n of from 10 to 5,000 and/or(E) from 0.1 to 10 parts by weight of polyethylene and/or copolymers of ethylene and .alpha.-olefins having a molecular weight of from 100,000 to 1,000,000,the number of parts by weight of components A, B, C, D and E summing to 100, with or without(F) effective amounts of additives.Type: GrantFiled: November 5, 1985Date of Patent: February 24, 1987Assignee: BASF AktiengesellschaftInventors: Gerhard Heinz, Wilhelm Schuette, Georg N. Simon
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Patent number: 4639488Abstract: Impact-resistant polyoxymethylene molding materials containing(A) from 30 to 95% by weight of one or more polyoxymethylenes and(B) from 5 to 70% by weight of one or more elastomeric graft polymers which are prepared by emulsion polymerization, are dispersed in component A, have a mean particle diameter of from 0.08 to 2 .mu.m and are composed of1. from 60 to 90% by weight of a grafting base of crosslinked polybutadiene in which not more than 30% by weight of the butadiene may be replaced with isoprene, 2,3-dimethylbutadiene, styrene, p-methylstyrene, .alpha.-methylstyrene and/or (meth)acrylonitrile, and2. from 10 to 40% by weight of one or more grafted shells consisting of polymers of styrene and/or methyl methacrylate, in which not more than 15% by weight of the said monomers 2 may be replaced with acrylonitrile or a C.sub.1 -C.sub.8 -alkyl acrylate,the percentages A and B and the percentages 1 and 2 summing to 100, with or without(C) effective amounts of assistants,and a process for their preparation.Type: GrantFiled: November 5, 1985Date of Patent: January 27, 1987Assignee: BASF AktiengesellschaftInventors: Wilhelm Schuette, Graham Edmund McKee, Albrecht Hilt, Gerhard Heinz, Heiner Goerrissen
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Patent number: 4616070Abstract: Thermoplastic molding materials containing a mixture ofA. a heat-stable polymer, e.g. a polyether sulfone or polysulfone, which does not contain any reactive groups, andB. a heat-stable polymer which contains reactive groups, preferably nitrile or thioaryl groups and/or sulfur bridges,can be processed to moldings, which can be crosslinked, for example by being heated at above 200.degree. C., so that the plastic matrix becomes virtually insoluble.Type: GrantFiled: May 8, 1985Date of Patent: October 7, 1986Assignee: BASF AktiengesellschaftInventors: Hartmut Zeiner, Gerhard Heinz, Peter Neumann, Juergen Fischer, Dietmar Nissen
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Patent number: 4590104Abstract: Fiber-reinforced materials are produced by impregnating continuous filaments with a melt of a polyarylene sulfide ketone, preferably one having a reduced viscosity .eta..sub.red of from 0.1 to 0.5 [dl.g.sup.-1 ], shaping the resulting semi-finished product to give a finished article and heating the latter for not less than 15 minutes at above the crystallite melting point of the polyarylene sulfide ketone, the latter undergoing crosslinking and its glass transition temperature Tg increasing by not less than 5.degree. C.Type: GrantFiled: February 14, 1985Date of Patent: May 20, 1986Assignee: BASF AktiengesellschaftInventors: Hartmut Zeiner, Jurgen Fischer, Gerhard Heinz, Peter Neumann, Dietmar Nissen, Gerhard Schaefer
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Patent number: 4430417Abstract: Photopolymerizable mixtures of (a) one or more block copolymers, (b) one or more photopolymerizable, ethylenically unsaturated, low molecular weight compounds and (c) a photopolymerization initiator, with or without (d) other additives, contain as component (a) block copolymers which are composed solely of elastomeric polymer blocks, and contain two or more elastomeric polymer blocks having a glass transition temperature of from -20.degree. C. to +15.degree. C., linked by one or more elastomeric polymer blocks having a glass transition temperature of below -20.degree. C.Type: GrantFiled: September 17, 1982Date of Patent: February 7, 1984Assignee: BASF AktiengesellschaftInventors: Gerhard Heinz, Peter Richter, Wolfgang F. Mueller
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Patent number: 4418180Abstract: A process for the preparation of branched block copolymers of from 60 to 95% by weight of a monovinyl-aromatic monomer and from 40 to 5% by weight of a conjugated diene by polymerizing the monomers in an inert solvent in the presence of a monolithium-hydrocarbon as the initiator, wherein, in a first process stage (a), from 50 to 80, or where necessary at most 90, % by weight of the total amount of monovinyl-aromatic compound are polymerized to virtually complete conversion in the presence of a relatively small amount of the monolithium-hydrocarbon. This stage is carried out by starting with from 30 to 70% by weight of the vinyl-aromatic monomer and adding from 70 to 30% by weight in the feed, during the polymerization, in such a way that the polymerization temperature, which at the start of the polymerization is from 30.degree. to 40.degree. C., is kept at from 45.degree. to 70.degree. C., with use of reflux cooling. After all the monomer feed has been added, the reaction temperature is lowered to 30.degree.Type: GrantFiled: August 27, 1981Date of Patent: November 29, 1983Assignee: BASF AktiengesellschaftInventors: Gerhard Heinz, Burghard Schmitt, Ingo H. Dorn, Hermann Gausepohl, Karl Gerberding, Rudolf H. Jung, Hans Mittnacht, Jurgen Pohrt, Paul Witimer