Patents by Inventor Gerhard Jozef Bleys

Gerhard Jozef Bleys has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9926479
    Abstract: The present invention is concerned with a material comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) exhibits a phase change as measured by differential scanning calorimetry (DSC) in the temperature range ?10° C. to +60° C. with an enthalpy ?Hm of at least 87 kJ/kg, 3) is interpenetrating said matrix A, and 4) has an average molecular weight of more than 700 and comprises at least 50% by weight of oxyalkylene groups, based on the weight of this material, wherein at least 85% of the oxyalkylene groups are oxyethylene groups (hereinafter called polymeric material B); and wherein the relative amount of said matrix A and of said polymeric material B, on a weight basis, ranges from 15:85 to 75:25. Process for preparing such material.
    Type: Grant
    Filed: May 10, 2010
    Date of Patent: March 27, 2018
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Patent number: 8822595
    Abstract: Isocyanurate-reactive mixture obtained by reacting an anhydride and a polyol; process for making it; polyisocyanate composition comprising this mixture; binder composition comprising such a polyisocyanate composition; the use of such a polyisocyanate composition and/or binder composition for making a polyisocyanurate and such polyisocyanurates.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: September 2, 2014
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Johan Robert Derluyn, Eric Huygens, Hans Verbeke, Luthgarde Alberta Marcella Geeraerts, Mathias Johan Richard Devos, Kristin Guillemine Irène Devos
  • Patent number: 8785570
    Abstract: A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerization catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4?-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25° C.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: July 22, 2014
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Stijn Roekaerts, Marc Vandervesse, Hans Godelieve Guido Verbeke
  • Patent number: 8519062
    Abstract: Elastomeric material having a density of more than 100 kg/m3 and comprising a matrix material comprising a plurality of urethane, urea and/or isocyanurate groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is the reaction product of a polyisocyanate and a polymer having an average molecular weight of more than 500 and one isocyanate-reactive group at an isocyanate index of 100-250 (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 90:10 and process for making such materials.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: August 27, 2013
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Patent number: 8349908
    Abstract: Foamed material having a density of less than 100 kg/m3 and comprising a matrix material comprising a plurality of urea groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is a polymer having an average molecular weight of more than 500 which polymer comprises at least 50% by weight of oxyethylene groups based on the weight of this polymer (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 70:30 and process for making such materials.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: January 8, 2013
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Publication number: 20130004770
    Abstract: The present invention is concerned with particulate material having a number average particle diameter of 1 ?m-1 cm, exhibiting a solid-solid phase change, as measured by differential scanning calorimetry (DSC), in the temperature range ?10° C. to +100° C. and comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material. Process for making this material and the use of it as.
    Type: Application
    Filed: January 14, 2011
    Publication date: January 3, 2013
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Patent number: 8283421
    Abstract: Composition obtained by reacting a polyisocyanate which is a diphenylmethane diisocyanate, optionally comprising a homologue comprising 3 or more isocyanate groups, and/or a variant of such diisocyanate with a monoalkylether of a polyoxyalkylene monoamine having an average molecular weight of 550-3000 and an oxyethylene content of more than 50% by weight, calculated on the weight of the monoamine, and the alkyl group having 1-4 carbon atoms at index of 100-250. It is used as plasticizer, particularly in polyurethane and/or polyurea materials.
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: October 9, 2012
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Publication number: 20120077942
    Abstract: The present invention is concerned with a material comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) exhibits a phase change as measured by differential scanning calorimetry (DSC) in the temperature range ?10° C. to +60° C. with an enthalpy ?Hm of at least 87 kJ/kg, 3) is interpenetrating said matrix A, and 4) has an average molecular weight of more than 700 and comprises at least 50% by weight of oxyalkylene groups, based on the weight of this material, wherein at least 85% of the oxyalkylene groups are oxyethylene groups (hereinafter called polymeric material B); and wherein the relative amount of said matrix A and of said polymeric material B, on a weight basis, ranges from 15:85 to 75:25. Process for preparing such material.
    Type: Application
    Filed: May 10, 2010
    Publication date: March 29, 2012
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Patent number: 8143364
    Abstract: Process for preparing a composition by reacting a polyisocyanate, a monoalkoxy polyoxyalkylene monoamine and water. The composition and its use in making cellular products are claimed as well.
    Type: Grant
    Filed: February 12, 2007
    Date of Patent: March 27, 2012
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Publication number: 20110237741
    Abstract: Isocyanurate-reactive mixture obtained by reacting an anhydride and a polyol; process for making it; polyisocyanate composition comprising this mixture; binder composition comprising such a polyisocyanate composition; the use of such a polyisocyanate composition and/or binder composition for making a polyisocyanurate and such polyisocyanurates.
    Type: Application
    Filed: July 30, 2009
    Publication date: September 29, 2011
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Johan Robert Derluyn, Julien Devos, Eric Huygens, Hans Verbeke
  • Publication number: 20110136991
    Abstract: Elastomeric material having a density of more than 100 kg/m3 and comprising a matrix material comprising a plurality of urethane, urea and/or isocyanurate groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is the reaction product of a polyisocyanate and a polymer having an average molecular weight of more than 500 and one isocyanate-reactive group at an isocyanate index of 100-250 (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 90:10 and process for making such materials.
    Type: Application
    Filed: February 5, 2009
    Publication date: June 9, 2011
    Applicant: Huntsman International LLC
    Inventor: Gerhard Jozef Bleys
  • Publication number: 20110015287
    Abstract: Foamed material having a density of less than 100 kg/m3 and comprising a matrix material comprising a plurality of urea groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is a polymer having an average molecular weight of more than 500 which polymer comprises at least 50% by weight of oxyethylene groups based on the weight of this polymer (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 70:30 and process for making such materials.
    Type: Application
    Filed: March 4, 2009
    Publication date: January 20, 2011
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Publication number: 20110003944
    Abstract: Composition obtained by reacting a polyisocyanate which is a diphenylmethane diisocyanate, optionally comprising a homologue comprising 3 or more isocyanate groups, and/or a variant of such diisocyanate with a monoalkylether of a polyoxyalkylene monoamine having an average molecular weight of 550-3000 and an oxyethylene content of more than 50% by weight, calculated on the weight of the monoamine, and the alkyl group having 1-4 carbon atoms at index of 100-250. It is used as plasticizer, particularly in polyurethane and/or polyurea materials.
    Type: Application
    Filed: December 5, 2008
    Publication date: January 6, 2011
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Patent number: 7687548
    Abstract: Process for preparing a moulded elastomeric polyurethane material having an overall density of 200-1000 kg/m3, preferably of 200-500 kg/m3, and a compression load at 40% deflection of at least 25 kPa by reacting in a closed mould an isocyanate terminated prepolymer, having an NCO-value of 5-15% by weight and which is the reaction product of a polyisocyanate and a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 500-5000 and an oxyethylene content of 50-90% by weight, and water. The elastomer obtained is claimed as well.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: March 30, 2010
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Johan Indesteege
  • Publication number: 20090069456
    Abstract: Process for preparing a composition by reacting a polyisocyanate, a monoalkoxy polyoxyalkylene monoamine and water. The composition and its use in making cellular products are claimed as well.
    Type: Application
    Filed: February 12, 2007
    Publication date: March 12, 2009
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Publication number: 20090005517
    Abstract: Process for making a polyisocyanurate composite which process comprises combining a polyisocyanate, a polyether polyol and a trimerization catalyst with a to-be-bonded material to form a reactive composite, and allowing in a next step this reactive composite to react at elevated temperature, wherein the amount of the reactive binder composition is 1-60% by weight and the amount of the to-be-bonded material is 40-99% by weight, both calculated on the amount of the reactive binder composition plus the amount of the to-be-bonded material, wherein the amount of the polyisocyanate and the polyol is such that the index is 150-10000, characterized in that the polyol is a polyol having an average equivalent weight of 100-2500 and an oxyethylene content of at least 50% by weight. The reactive composite is claimed as well together with composites obtained from this process and from these reactive composites.
    Type: Application
    Filed: January 17, 2007
    Publication date: January 1, 2009
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Stijn Roekaerts, Marc Vandervesse, Hans Godelieve Guido Verbeke
  • Publication number: 20080262168
    Abstract: A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerisation catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane di-isocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4?-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25° C.
    Type: Application
    Filed: September 29, 2006
    Publication date: October 23, 2008
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Stijn Roekaerts, Marc Vandervesse, Hans Godelieve Guido Verbeke
  • Patent number: 7307136
    Abstract: A polyisocyanate-based elastomer having a ratio of the storage modulus (E?) at 20° C. and the storage modulus (E?) at 120° C. of between 0.75 and 1.5, a tan ? at 100° C. of less than 0.1 and a maximum value of the tan ? of more than 0.8, the tan ? being the ratio of the loss modulus (E?) and the storage modulus (E?).
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: December 11, 2007
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Alan James Hamilton, Jan Willem Leenslag
  • Patent number: 7169824
    Abstract: Process for preparing flexible polyurethane foam by reacting an MDI-based polyisocyanate and a polyether polyol with a high oxyethylene content in a mold.
    Type: Grant
    Filed: July 24, 2002
    Date of Patent: January 30, 2007
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Jan-Willem Leenslag, Herman Eugene Germain Moureau
  • Patent number: 6914117
    Abstract: Process for preparing an elastomeric polyurethane material by reacting a polyisocyanate, a polyol and a monool.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: July 5, 2005
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Danny Anna Edward Geukens, Hans Godelieve Guido Verbeke