Patents by Inventor Gerhard Jozef Bleys
Gerhard Jozef Bleys has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9926479Abstract: The present invention is concerned with a material comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) exhibits a phase change as measured by differential scanning calorimetry (DSC) in the temperature range ?10° C. to +60° C. with an enthalpy ?Hm of at least 87 kJ/kg, 3) is interpenetrating said matrix A, and 4) has an average molecular weight of more than 700 and comprises at least 50% by weight of oxyalkylene groups, based on the weight of this material, wherein at least 85% of the oxyalkylene groups are oxyethylene groups (hereinafter called polymeric material B); and wherein the relative amount of said matrix A and of said polymeric material B, on a weight basis, ranges from 15:85 to 75:25. Process for preparing such material.Type: GrantFiled: May 10, 2010Date of Patent: March 27, 2018Assignee: HUNTSMAN INTERNATIONAL LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Patent number: 8822595Abstract: Isocyanurate-reactive mixture obtained by reacting an anhydride and a polyol; process for making it; polyisocyanate composition comprising this mixture; binder composition comprising such a polyisocyanate composition; the use of such a polyisocyanate composition and/or binder composition for making a polyisocyanurate and such polyisocyanurates.Type: GrantFiled: July 30, 2009Date of Patent: September 2, 2014Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Johan Robert Derluyn, Eric Huygens, Hans Verbeke, Luthgarde Alberta Marcella Geeraerts, Mathias Johan Richard Devos, Kristin Guillemine Irène Devos
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Patent number: 8785570Abstract: A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerization catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4?-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25° C.Type: GrantFiled: September 29, 2006Date of Patent: July 22, 2014Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Eric Huygens, Stijn Roekaerts, Marc Vandervesse, Hans Godelieve Guido Verbeke
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Patent number: 8519062Abstract: Elastomeric material having a density of more than 100 kg/m3 and comprising a matrix material comprising a plurality of urethane, urea and/or isocyanurate groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is the reaction product of a polyisocyanate and a polymer having an average molecular weight of more than 500 and one isocyanate-reactive group at an isocyanate index of 100-250 (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 90:10 and process for making such materials.Type: GrantFiled: February 5, 2009Date of Patent: August 27, 2013Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Patent number: 8349908Abstract: Foamed material having a density of less than 100 kg/m3 and comprising a matrix material comprising a plurality of urea groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is a polymer having an average molecular weight of more than 500 which polymer comprises at least 50% by weight of oxyethylene groups based on the weight of this polymer (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 70:30 and process for making such materials.Type: GrantFiled: March 4, 2009Date of Patent: January 8, 2013Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Publication number: 20130004770Abstract: The present invention is concerned with particulate material having a number average particle diameter of 1 ?m-1 cm, exhibiting a solid-solid phase change, as measured by differential scanning calorimetry (DSC), in the temperature range ?10° C. to +100° C. and comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material. Process for making this material and the use of it as.Type: ApplicationFiled: January 14, 2011Publication date: January 3, 2013Applicant: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Patent number: 8283421Abstract: Composition obtained by reacting a polyisocyanate which is a diphenylmethane diisocyanate, optionally comprising a homologue comprising 3 or more isocyanate groups, and/or a variant of such diisocyanate with a monoalkylether of a polyoxyalkylene monoamine having an average molecular weight of 550-3000 and an oxyethylene content of more than 50% by weight, calculated on the weight of the monoamine, and the alkyl group having 1-4 carbon atoms at index of 100-250. It is used as plasticizer, particularly in polyurethane and/or polyurea materials.Type: GrantFiled: December 5, 2008Date of Patent: October 9, 2012Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Publication number: 20120077942Abstract: The present invention is concerned with a material comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) exhibits a phase change as measured by differential scanning calorimetry (DSC) in the temperature range ?10° C. to +60° C. with an enthalpy ?Hm of at least 87 kJ/kg, 3) is interpenetrating said matrix A, and 4) has an average molecular weight of more than 700 and comprises at least 50% by weight of oxyalkylene groups, based on the weight of this material, wherein at least 85% of the oxyalkylene groups are oxyethylene groups (hereinafter called polymeric material B); and wherein the relative amount of said matrix A and of said polymeric material B, on a weight basis, ranges from 15:85 to 75:25. Process for preparing such material.Type: ApplicationFiled: May 10, 2010Publication date: March 29, 2012Applicant: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Patent number: 8143364Abstract: Process for preparing a composition by reacting a polyisocyanate, a monoalkoxy polyoxyalkylene monoamine and water. The composition and its use in making cellular products are claimed as well.Type: GrantFiled: February 12, 2007Date of Patent: March 27, 2012Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Publication number: 20110237741Abstract: Isocyanurate-reactive mixture obtained by reacting an anhydride and a polyol; process for making it; polyisocyanate composition comprising this mixture; binder composition comprising such a polyisocyanate composition; the use of such a polyisocyanate composition and/or binder composition for making a polyisocyanurate and such polyisocyanurates.Type: ApplicationFiled: July 30, 2009Publication date: September 29, 2011Applicant: Huntsman International LLCInventors: Gerhard Jozef Bleys, Johan Robert Derluyn, Julien Devos, Eric Huygens, Hans Verbeke
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Publication number: 20110136991Abstract: Elastomeric material having a density of more than 100 kg/m3 and comprising a matrix material comprising a plurality of urethane, urea and/or isocyanurate groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is the reaction product of a polyisocyanate and a polymer having an average molecular weight of more than 500 and one isocyanate-reactive group at an isocyanate index of 100-250 (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 90:10 and process for making such materials.Type: ApplicationFiled: February 5, 2009Publication date: June 9, 2011Applicant: Huntsman International LLCInventor: Gerhard Jozef Bleys
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Publication number: 20110015287Abstract: Foamed material having a density of less than 100 kg/m3 and comprising a matrix material comprising a plurality of urea groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is a polymer having an average molecular weight of more than 500 which polymer comprises at least 50% by weight of oxyethylene groups based on the weight of this polymer (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 70:30 and process for making such materials.Type: ApplicationFiled: March 4, 2009Publication date: January 20, 2011Applicant: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Publication number: 20110003944Abstract: Composition obtained by reacting a polyisocyanate which is a diphenylmethane diisocyanate, optionally comprising a homologue comprising 3 or more isocyanate groups, and/or a variant of such diisocyanate with a monoalkylether of a polyoxyalkylene monoamine having an average molecular weight of 550-3000 and an oxyethylene content of more than 50% by weight, calculated on the weight of the monoamine, and the alkyl group having 1-4 carbon atoms at index of 100-250. It is used as plasticizer, particularly in polyurethane and/or polyurea materials.Type: ApplicationFiled: December 5, 2008Publication date: January 6, 2011Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Patent number: 7687548Abstract: Process for preparing a moulded elastomeric polyurethane material having an overall density of 200-1000 kg/m3, preferably of 200-500 kg/m3, and a compression load at 40% deflection of at least 25 kPa by reacting in a closed mould an isocyanate terminated prepolymer, having an NCO-value of 5-15% by weight and which is the reaction product of a polyisocyanate and a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 500-5000 and an oxyethylene content of 50-90% by weight, and water. The elastomer obtained is claimed as well.Type: GrantFiled: December 17, 2004Date of Patent: March 30, 2010Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Johan Indesteege
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Publication number: 20090069456Abstract: Process for preparing a composition by reacting a polyisocyanate, a monoalkoxy polyoxyalkylene monoamine and water. The composition and its use in making cellular products are claimed as well.Type: ApplicationFiled: February 12, 2007Publication date: March 12, 2009Applicant: Huntsman International LLCInventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
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Publication number: 20090005517Abstract: Process for making a polyisocyanurate composite which process comprises combining a polyisocyanate, a polyether polyol and a trimerization catalyst with a to-be-bonded material to form a reactive composite, and allowing in a next step this reactive composite to react at elevated temperature, wherein the amount of the reactive binder composition is 1-60% by weight and the amount of the to-be-bonded material is 40-99% by weight, both calculated on the amount of the reactive binder composition plus the amount of the to-be-bonded material, wherein the amount of the polyisocyanate and the polyol is such that the index is 150-10000, characterized in that the polyol is a polyol having an average equivalent weight of 100-2500 and an oxyethylene content of at least 50% by weight. The reactive composite is claimed as well together with composites obtained from this process and from these reactive composites.Type: ApplicationFiled: January 17, 2007Publication date: January 1, 2009Applicant: Huntsman International LLCInventors: Gerhard Jozef Bleys, Eric Huygens, Stijn Roekaerts, Marc Vandervesse, Hans Godelieve Guido Verbeke
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Publication number: 20080262168Abstract: A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerisation catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane di-isocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4?-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25° C.Type: ApplicationFiled: September 29, 2006Publication date: October 23, 2008Applicant: Huntsman International LLCInventors: Gerhard Jozef Bleys, Eric Huygens, Stijn Roekaerts, Marc Vandervesse, Hans Godelieve Guido Verbeke
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Patent number: 7307136Abstract: A polyisocyanate-based elastomer having a ratio of the storage modulus (E?) at 20° C. and the storage modulus (E?) at 120° C. of between 0.75 and 1.5, a tan ? at 100° C. of less than 0.1 and a maximum value of the tan ? of more than 0.8, the tan ? being the ratio of the loss modulus (E?) and the storage modulus (E?).Type: GrantFiled: February 4, 2002Date of Patent: December 11, 2007Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Alan James Hamilton, Jan Willem Leenslag
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Patent number: 7169824Abstract: Process for preparing flexible polyurethane foam by reacting an MDI-based polyisocyanate and a polyether polyol with a high oxyethylene content in a mold.Type: GrantFiled: July 24, 2002Date of Patent: January 30, 2007Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Eric Huygens, Jan-Willem Leenslag, Herman Eugene Germain Moureau
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Patent number: 6914117Abstract: Process for preparing an elastomeric polyurethane material by reacting a polyisocyanate, a polyol and a monool.Type: GrantFiled: November 18, 2003Date of Patent: July 5, 2005Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Danny Anna Edward Geukens, Hans Godelieve Guido Verbeke