Patents by Inventor Germain Martino

Germain Martino has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4277369
    Abstract: A catalyst for the steam dealkylation of aromatic hydrocarbons, comprising a carrier and 3 metals, is regenerated in the reaction zone containing the catalyst bed, after disconnection of said zone from the producing unit, by proceeding to the successive steps of: scavenging said zone with hydrogen and then with an inert gas, progressively replacing said inert gas by a gas containing molecular oxygen, burning the catalyst at a temperature lower than 650.degree. C. so as to calcine the carbon deposits of the catalyst, passing through the catalyst bed an air stream containing halogen to increase the halogen content of the catalyst, calcining by means of an air stream at a temperature of 300.degree.-600.degree. C. and purging with an inert gas before reconnecting said reaction zone to the producing unit.
    Type: Grant
    Filed: November 29, 1979
    Date of Patent: July 7, 1981
    Assignee: Institut Francais du Petrole
    Inventors: Philippe Courty, Jean Miquel, Germain Martino, Alain Convers
  • Patent number: 4250056
    Abstract: Process for reforming hydrocarbons or producing aromatic hydrocarbons under severe operating conditions, in the presence of a catalyst comprising an alumina carrier and, expressed by weight with respect to alumina:(a) from 0.05 to 0.6% of platinum(b) from 0.01 to 2% of rhenium(c) from 0.05 to 3% of thallium or indium, and(d) from 0.1 to 10% of a halogen.
    Type: Grant
    Filed: January 15, 1980
    Date of Patent: February 10, 1981
    Assignee: Societe Francaise des Produits pour Catalyse
    Inventors: Jean-Francois Le Page, Germain Martino, Jean Miquel
  • Patent number: 4243516
    Abstract: Catalytic hydroreforming process, particularly for the production of gasoline of high clear octane number, comprising hydrogenating a hydrocarbon charge in the presence of a catalyst containing an alumina carrier, a first metal selected from ruthenium, iridium and rhodium, a second metal, different from the first metal, and selected from ruthenium, palladium and osmium, a third metal consisting of indium, and a halogen.
    Type: Grant
    Filed: December 6, 1977
    Date of Patent: January 6, 1981
    Assignee: Societe Francaise des Produits pour Catalyse
    Inventors: Germain Martino, Jean Miquel
  • Patent number: 4239652
    Abstract: Catalyst for a process of hydroreforming or aromatic hydrocarbon production, comprising an alumina carrier, at least one noble metal of the platinum family, antimony, a metal selected from gallium, indium and thallium and halogen, said catalyst being used in a series of successive reaction zones as a moving bed, transferred from one reaction zone to the next, from the last reaction zone to a regeneration zone and from the latter to the first reaction zone, said process being preferably conducted at a temperature from 510.degree. to 600.degree. C. and under a pressure from 1 to 18 kg/cm.sup.2.
    Type: Grant
    Filed: June 29, 1979
    Date of Patent: December 16, 1980
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Francois Le Page, Germain Martino, Jean Miquel
  • Patent number: 4217205
    Abstract: Catalyst, particularly useful in catalytic reforming and for producing highly pure aromatic hydrocarbons, comprising an alumina carrier and containing, expressed in proportion of the weight of the alumina carrier:0.005 to 1% of platinum0.01 to 4% of gallium, indium or thallium0.01 to 2% of tungsten, and0.1 to 10% of halogen.
    Type: Grant
    Filed: August 25, 1978
    Date of Patent: August 12, 1980
    Assignee: Societe Francaise des Products pour Catalyse
    Inventors: Christian Marcilly, Jean-Francois Le Page, Germain Martino, Jean Miquel
  • Patent number: 4214980
    Abstract: Process for reforming hydrocarbons or producing aromatic hydrocarbons under severe operating conditions, in the presence of a catalyst comprising an alumina carrier and, expressed by weight with respect to alumina:(a) from 0.05 to 0.6% of platinum(b) from 0.01 to 2% of rhenium(c) from 0.05 to 3% of thallium or indium, and(d) from 0.1 to 10% of a halogen.
    Type: Grant
    Filed: December 9, 1977
    Date of Patent: July 29, 1980
    Assignee: Societe Francaise des Produits pour Catalyse
    Inventors: Jean-Francois Le Page, Germain Martino, Jean Miquel
  • Patent number: 4207169
    Abstract: Catalytic process for steam dealkylation of a charge containing at least one alkyl aromatic hydrocarbon, such as a charge issued from effluents of units for catalytic reforming or for producing aromatic hydrocarbons, wherein the catalyst contains an alumina carrier, from 0.1 to 1% of rhodium, from 0.05 to 1% of TiO.sub.2 and optionally from 0.1 to 1% of ruthenium, palladium, iridium, platinum or osmium and/or from 0.01 to 5% of lithium, sodium, potassium, rubidium or cesium.
    Type: Grant
    Filed: January 8, 1979
    Date of Patent: June 10, 1980
    Assignee: Institut Francais du Petrole
    Inventors: Philippe Courty, Germain Martino, Jean-Francois Le Page
  • Patent number: 4140621
    Abstract: A saturated hydrocarbon charge containing both butane and isobutane is subjected to selective hydrogenolysis in the presence of a catalyst comprising a specific carrier and 0.1 - 10 % b.w. of rhodium. Butane is thus selectively converted to ethane and propane, while isobutane is preserved or formed and can be recovered from the reaction product.
    Type: Grant
    Filed: September 20, 1977
    Date of Patent: February 20, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Pierre Franck, Jean-Francois Le Page, Germain Martino, Jean Miquel
  • Patent number: 4125566
    Abstract: This process applies to effluents from syntheses of the Fischer-Tropsch type; it comprises several treatments applied to the three cuts obtained from these effluents, i.e. a "light fraction", a "light oil" and a "decanted oil". These treatments comprise such steps as distillation, polymerization, alkylation, hydrotreatment, cracking-decarboxylation, isomerization and hydro reforming. The products are mainly gasoline, kerosene and gasoil.
    Type: Grant
    Filed: August 17, 1977
    Date of Patent: November 14, 1978
    Assignee: Institut Francais du Petrole
    Inventors: Chan Trin Dinh, Jean-Francois Le Page, Jean Cosyns, Germain Martino, Jean Miquel
  • Patent number: 4000058
    Abstract: New catalyst containing a carrier, platinum, iridium, manganese and optionally halogen. This catalyst is useful for reforming and dehydrogenation of hydrocarbons.
    Type: Grant
    Filed: February 4, 1976
    Date of Patent: December 28, 1976
    Assignee: Institut Francais du Petrole, des Carburants et Lubrifiants et Entreprise de Recherches et d'Activities Petrolieres Elf
    Inventors: Pierre Duhaut, Germain Martino, Jean Miquel
  • Patent number: 3980727
    Abstract: Toluene and poly-methyl benzene hydrocarbons are reacted in the presence of an improved catalyst containing a group VIII noble metal. The catalyst is obtained by admixing a catalyst carrier with a Group VIII noble metal or compound thereof and with a hydrocarbyl aluminum halide. Sulfur may be present. The yield and selectivity are substantially improved as compared to conventional catalysts.
    Type: Grant
    Filed: March 19, 1975
    Date of Patent: September 14, 1976
    Assignee: Institut Francais du Petrole, des Carburants et Lubrifiants et Entreprise de Recherches et d'Activities Petrolieres Elf
    Inventors: Christian Marcilly, Germain Martino, Jean-Pierre Franck
  • Patent number: 3957686
    Abstract: New catalyst containing a carrier, platinum, iridium, manganese and optionally halogen. This catalyst is useful for reforming and dehydrogenation of hydrocarbons.
    Type: Grant
    Filed: December 13, 1973
    Date of Patent: May 18, 1976
    Assignee: Societe Francaise des produits pour Catalyse
    Inventors: Pierre Duhaut, Germain Martino, Jean Miquel
  • Patent number: 3954601
    Abstract: Aromatic hydrocarbons are hydrogenated in the presence of a catalyst obtained by admixing an aluminous carrier with a group VIII noble metal compound and a reducing agent of the formula Al X.sub.y R.sub.3-y where y is 1, 3/2 or 2, X is halogen and R is a monovalent hydrocarbon radical.
    Type: Grant
    Filed: August 7, 1974
    Date of Patent: May 4, 1976
    Assignee: Institut Francais du Petrole
    Inventors: Jean Cosyns, Germain Martino, Jean-Francois Le Page
  • Patent number: 3943067
    Abstract: Process for manufacturing a catalyst suitable for the hydrogenation and reforming reactions, comprising impregnating, at a temperature of a least 160.degree. C, a solid carrier, with a homogeneous catalyst solution obtained by admixing in a solvent, at a temperature above 100.degree.C, a salt of a metal whose atomic number is in the range of from 22 to 29, 40 to 47, 72 to 79 and 90 to 92, with a metallic or organo-metallic reducing agent, the metal component being selected from groups Ia, IIa, IIb and IIIb.
    Type: Grant
    Filed: April 17, 1974
    Date of Patent: March 9, 1976
    Assignee: Institut Francais du Petrole
    Inventors: Trinh Dinh Chan, Germain Martino, Lucien Sajus, Claude Roux-Guerraz