Patents by Inventor Gerold HÜBNER

Gerold HÜBNER has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 12170379
    Abstract: A manufacturing process includes: depositing a catalyst support on a gas diffusion layer to form a catalyst support-coated gas diffusion layer; depositing a catalyst on the catalyst support-coated gas diffusion layer to form a catalyst-coated gas diffusion layer; and depositing an ionomer on the catalyst-coated gas diffusion layer to form an ionomer-coated gas diffusion layer. A membrane electrode assembly for a fuel cell includes: a gas diffusion layer; a polymer electrolyte membrane; and a catalyst layer disposed between the gas diffusion layer and the polymer electrolyte membrane, wherein the catalyst layer includes an ionomer, and a concentration of the ionomer varies within the catalyst layer according to a concentration profile.
    Type: Grant
    Filed: November 25, 2019
    Date of Patent: December 17, 2024
    Assignees: The Board of Trustees of the Leland Stanford Junior University, Volkswagen Aktiengesellschaft
    Inventors: Shicheng Xu, Friedrich B. Prinz, Thomas Schladt, Tanja Graf, Jonathan Edward Mueller, Sebastian Kirsch, Gerold Huebner, Vedran Glavas
  • Patent number: 12132231
    Abstract: A layered structure for a fuel cell comprises a carbon-based catalyst-free gas diffusion layer substrate and a carbon-based microporous layer, which is joined to the gas diffusion layer substrate and comprises a plurality of carbon carriers or carbon fibers embedded into an ion-conducting polymer binder mixture. The polymer binder mixture comprises a sulfur-free binding polymer and a sulfonated polymer, and a fraction of the binding polymer at or near a surface of the microporous layer facing away from the gas diffusion layer substrate is less than or equal to a fraction of the sulfonated polymer. A method for producing a layered structure of this type is also provided.
    Type: Grant
    Filed: July 8, 2019
    Date of Patent: October 29, 2024
    Assignees: VOLKSWAGEN AG, AUDI AG
    Inventors: Gerold Hübner, Tanja Graf, Thomas Schladt
  • Patent number: 12009526
    Abstract: A method for the production of an electrode for a fuel cell is provided that comprises providing a multitude of catalyst particles carried on at least one electrically conductive particle carrier, and depositing one or more atomic or molecular layers of an ionomer from the gas phase on the catalyst particles and/or the at least one particle carrier, thereby forming a proton-conducting ionomer coating. Furthermore, an electrode for a fuel cell is also provided.
    Type: Grant
    Filed: December 5, 2019
    Date of Patent: June 11, 2024
    Assignees: Volkswagen AG, Audi AG
    Inventors: Thomas Schladt, Lasse Schmidt, Tanja Graf, Gerold Hübner, Jonathan Edward Müller
  • Patent number: 11973233
    Abstract: A catalyst structure includes: (1) a substrate; (2) a catalyst layer on the substrate; and (3) an adhesion layer disposed between the substrate and the catalyst layer. In some implementations, an average thickness of the adhesion layer is about 1 nm or less. In some implementations, a material of the catalyst layer at least partially extends into a region of the adhesion layer. In some implementations, the catalyst layer is characterized by a lattice strain imparted by the adhesion layer.
    Type: Grant
    Filed: December 11, 2020
    Date of Patent: April 30, 2024
    Assignees: The Board of Trustees of the Leland Stanford Junior University, Volkswagen Aktiengesellschaft
    Inventors: Friedrich B. Prinz, Shicheng Xu, Yongmin Kim, Thomas Jaramillo, Drew C. Higgins, Maha Yusuf, Zhaoxuan Wang, Kyung Min Lee, Marat Orazov, Dong Un Lee, Tanja Graf, Thomas Schladt, Gerold Huebner, Hanna-Lena Wittern, Jonathan Edward Mueller
  • Patent number: 11936051
    Abstract: A catalyst structure includes: (1) a substrate; (2) a catalyst layer on the substrate; and (3) an adhesion layer disposed between the substrate and the catalyst layer. In some implementations, an average thickness of the adhesion layer is about 1 nm or less. In some implementations, a material of the catalyst layer at least partially extends into a region of the adhesion layer. In some implementations, the catalyst layer is characterized by a lattice strain imparted by the adhesion layer.
    Type: Grant
    Filed: December 13, 2019
    Date of Patent: March 19, 2024
    Assignees: The Board of Trustees of the Leland Stanford Junior University, Volkswagen Aktiengesellschaf
    Inventors: Friedrich B. Prinz, Shicheng Xu, Yongmin Kim, Thomas Jaramillo, Drew C. Higgins, Maha Yusuf, Zhaoxuan Wang, Kyung Min Lee, Marat Orazov, Dong Un Lee, Tanja Graf, Thomas Schladt, Gerold Huebner, Hanna-Lena Wittern, Jonathan Edward Mueller
  • Publication number: 20230089402
    Abstract: A method for production of a fuel cell includes: a) Preparing a plurality of catalyst pastes which differ from each other at least in regard to one parameter influencing the catalytic activity, b) Filling of at least two of the plurality of catalyst pastes into a first application means having a number of chambers corresponding to the number of catalyst pastes being filled, where only one of the catalyst pastes is filled into each of the chambers, c) Filling of at least two of the plurality of catalyst pastes into a second application means having a number of chambers corresponding to the number of catalyst pastes being filled, where only one of the catalyst pastes is filled into each of the chambers, d) Coating of a first side of a foil web of an electrolyte membrane which is moved past the first application means and the second application means by means of the first application means, e) Coating of a second side of the foil web by means of the second application means, f) Cutting of the resulting coated el
    Type: Application
    Filed: December 15, 2020
    Publication date: March 23, 2023
    Inventors: Gerold HÜBNER, Hannes SCHOLZ
  • Publication number: 20230079048
    Abstract: A manufacturing process includes: depositing a first catalyst on a first gas diffusion layer (GDL) to form a first catalyst-coated GDL; depositing a first ionomer on the first catalyst-coated GDL to form a first gas diffusion electrode (GDE); depositing a second catalyst on a second GDL to form a second catalyst-coated GDL; depositing a second ionomer on the second catalyst-coated GDL to form a second GDE; and laminating the first GDE with the second GDE and with an electrolyte membrane disposed between the first GDE and the second GDE to form a membrane electrode assembly (MEA). A MEA includes a first GDL; a second GDL; an electrolyte membrane disposed between the first GDL and the second GDL; a first catalyst layer disposed between the first GDL and the electrolyte membrane; and a second catalyst layer disposed between the second GDL and the electrolyte membrane, wherein a thickness of the electrolyte membrane is about 15 ?m or less.
    Type: Application
    Filed: February 12, 2021
    Publication date: March 16, 2023
    Applicants: Board of Trustees of the Leland Stanford Junior University, Volkswagen Aktiengesellschaft
    Inventors: Friedrich B. Prinz, Timothy Goh, Shicheng Xu, Zhaoxuan Wang, Soonwook Hong, Yongmin Kim, Samuel Dull, Dong Un Lee, Thomas Francisco Jaramillo, Thomas Schladt, Gerold Huebner, Jonathan Müller, Glavas Vedran
  • Publication number: 20230009452
    Abstract: A catalyst structure includes: (1) a substrate; (2) a catalyst layer on the substrate; and (3) an adhesion layer disposed between the substrate and the catalyst layer. In some implementations, an average thickness of the adhesion layer is about 1 nm or less. In some implementations, a material of the catalyst layer at least partially extends into a region of the adhesion layer. In some implementations, the catalyst layer is characterized by a lattice strain imparted by the adhesion layer.
    Type: Application
    Filed: December 11, 2020
    Publication date: January 12, 2023
    Applicants: The Board of Trustees of the Leland Stanford Junior University, Volkswagen Aktiengesellschaft
    Inventors: Friedrich B. PRINZ, Shicheng XU, Yongmin KIM, Thomas JARAMILLO, Drew C. HIGGINS, Maha YUSUF, Zhaoxuan WANG, Kyung Min LEE, Marat ORAZOV, Dong Un LEE, Tanja GRAF, Thomas SCHLADT, Gerold HUEBNER, Hanna-Lena WITTERN, Jonathan Edward MUELLER
  • Patent number: 11462744
    Abstract: A manufacturing process includes: depositing a first catalyst on a first gas diffusion layer (GDL) to form a first catalyst-coated GDL; depositing a first ionomer on the first catalyst-coated GDL to form a first gas diffusion electrode (GDE); depositing a second catalyst on a second GDL to form a second catalyst-coated GDL; depositing a second ionomer on the second catalyst-coated GDL to form a second GDE; and laminating the first GDE with the second GDE and with an electrolyte membrane disposed between the first GDE and the second GDE to form a membrane electrode assembly (MEA). A MEA includes a first GDL; a second GDL; an electrolyte membrane disposed between the first GDL and the second GDL; a first catalyst layer disposed between the first GDL and the electrolyte membrane; and a second catalyst layer disposed between the second GDL and the electrolyte membrane, wherein a thickness of the electrolyte membrane is about 15 ?m or less.
    Type: Grant
    Filed: February 14, 2020
    Date of Patent: October 4, 2022
    Assignees: The Board of Trustees of the Leland Stanford Junior University, Volkswagen Aktiengesellschaft
    Inventors: Friedrich B. Prinz, Timothy Goh, Shicheng Xu, Zhaoxuan Wang, Soonwook Hong, Yongmin Kim, Samuel Dull, Dong Un Lee, Thomas Francisco Jaramillo, Thomas Schladt, Gerold Huebner, Jonathan Müller, Glavas Vedran
  • Publication number: 20220190354
    Abstract: A method for the production of an electrode for a fuel cell is provided that comprises providing a multitude of catalyst particles carried on at least one electrically conductive particle carrier, and depositing one or more atomic or molecular layers of an ionomer from the gas phase on the catalyst particles and/or the at least one particle carrier, thereby forming a proton-conducting ionomer coating. Furthermore, an electrode for a fuel cell is also provided.
    Type: Application
    Filed: December 5, 2019
    Publication date: June 16, 2022
    Inventors: Thomas SCHLADT, Lasse SCHMIDT, Tanja GRAF, Gerold HÜBNER, Jonathan Edward MÜLLER
  • Patent number: 11322758
    Abstract: A method for reducing cell degradation in a fuel cell system includes adding oxygen-containing gas to a fuel in the anode chamber to prevent an increase in a cell voltage above a predetermined maximum value.
    Type: Grant
    Filed: January 23, 2019
    Date of Patent: May 3, 2022
    Assignees: VOLKSWAGEN AG, AUDI AG
    Inventors: Miriam Stiefel, Lasse Schmidt, Gerold Hübner
  • Patent number: 11302927
    Abstract: A method for producing a noble metal-free catalyst comprises providing a catalyst support comprising organic heterocycles as catalyst, and applying an oxidation-inhibiting protective layer. Embodiments further relate to a noble metal-free catalyst, a fuel cell, and a motor vehicle.
    Type: Grant
    Filed: July 9, 2019
    Date of Patent: April 12, 2022
    Assignees: VOLKSWAGEN AG, AUDI AG
    Inventors: Gerold Hübner, Lasse Schmidt, Alexander Vollbrecht
  • Patent number: 11245124
    Abstract: A diagnostic system for determining the cathode gas quality of a fuel cell system has a fuel cell stack, with a diagnostic fuel cell which can be connected at the cathode side to a cathode supply line and at the anode side to an anode supply line of the fuel cell system. The diagnostic system furthermore comprises a detection unit which is configured to detect a measured value or the measured value time curve of the diagnostic fuel cell operating with the cathode gas provided via the cathode supply line and with the anode gas provided via the anode supply line. The present disclosure moreover relates to a fuel cell system having a diagnostic system, and to a corresponding method.
    Type: Grant
    Filed: November 16, 2018
    Date of Patent: February 8, 2022
    Assignees: VOLKSWAGEN AG, AUDI AG
    Inventors: Lasse Schmidt, Sebastian Kirsch, Gerold Hübner
  • Publication number: 20220029171
    Abstract: A manufacturing process includes: depositing a catalyst support on a gas diffusion layer to form a catalyst support-coated gas diffusion layer; depositing a catalyst on the catalyst support-coated gas diffusion layer to form a catalyst-coated gas diffusion layer; and depositing an ionomer on the catalyst-coated gas diffusion layer to form an ionomer-coated gas diffusion layer. A membrane electrode assembly for a fuel cell includes: a gas diffusion layer; a polymer electrolyte membrane; and a catalyst layer disposed between the gas diffusion layer and the polymer electrolyte membrane, wherein the catalyst layer includes an ionomer, and a concentration of the ionomer varies within the catalyst layer according to a concentration profile.
    Type: Application
    Filed: November 25, 2019
    Publication date: January 27, 2022
    Applicants: The Board of Trustees of the Leland Stanford Junior University, Volkswagen Aktiengesellschaft
    Inventors: Shicheng XU, Friedrich B. PRINZ, Thomas SCHLADT, Tanja GRAF, Jonathan Edward MUELLER, Sebastian KIRSCH, Gerold HUEBNER, Vedran GLAVAS
  • Patent number: 11201346
    Abstract: A fuel cell stack is provided comprising a plurality of fuel cells comprising a membrane electrode assembly and at least one gas diffusion layer, which fuel cells are divided into at least one first fuel cell segment having a portion of the plurality of fuel cells and a second fuel cell segment having a different portion of the plurality of fuel cells, wherein the first fuel cell segment and the second fuel cell segment are arranged in a common fuel cell cascade, wherein the first fuel cell segment comprises a first collector inlet line for an operating medium and a first collector outlet lined which is formed integrally with a second collector inlet line of the second fuel cell segment and wherein the second fuel cell segment comprises a second collector outlet line. The membrane electrode assemblies and/or the gas diffusion layers inside the second fuel cell segment are designed in such a way that they are more water-repellent than those of the first fuel cell segment.
    Type: Grant
    Filed: December 6, 2018
    Date of Patent: December 14, 2021
    Assignees: AUDI AG, VOLKSWAGEN AG
    Inventors: Natalja Ermatschenko, Christian Lucas, Gerold Hübner
  • Publication number: 20210320304
    Abstract: A method for producing a noble metal-free catalyst comprises providing a catalyst support comprising organic heterocycles as catalyst, and applying an oxidation-inhibiting protective layer. Embodiments further relate to a noble metal-free catalyst, a fuel cell, and a motor vehicle.
    Type: Application
    Filed: July 9, 2019
    Publication date: October 14, 2021
    Inventors: Gerold HÜBNER, Lasse SCHMIDT, Alexander VOLLBRECHT
  • Publication number: 20210305589
    Abstract: A layered structure for a fuel cell comprises a carbon-based catalyst-free gas diffusion layer substrate and a carbon-based microporous layer, which is joined to the gas diffusion layer substrate and comprises a plurality of carbon carriers or carbon fibers embedded into an ion-conducting polymer binder mixture. The polymer binder mixture comprises a sulfur-free binding polymer and a sulfonated polymer, and a fraction of the binding polymer at or near a surface of the microporous layer facing away from the gas diffusion layer substrate is less than or equal to a fraction of the sulfonated polymer. A method for producing a layered structure of this type is also provided.
    Type: Application
    Filed: July 8, 2019
    Publication date: September 30, 2021
    Inventors: Gerold HÜBNER, Tanja GRAF, Thomas SCHLADT
  • Publication number: 20210288343
    Abstract: A fuel cell stack is provided comprising a plurality of fuel cells comprising a membrane electrode assembly and at least one gas diffusion layer, which fuel cells are divided into at least one first fuel cell segment having a portion of the plurality of fuel cells and a second fuel cell segment having a different portion of the plurality of fuel cells, wherein the first fuel cell segment and the second fuel cell segment are arranged in a common fuel cell cascade, wherein the first fuel cell segment comprises a first collector inlet line for an operating medium and a first collector outlet lined which is formed integrally with a second collector inlet line of the second fuel cell segment and wherein the second fuel cell segment comprises a second collector outlet line. The membrane electrode assemblies and/or the gas diffusion layers inside the second fuel cell segment are designed in such a way that they are more water-repellent than those of the first fuel cell segment.
    Type: Application
    Filed: December 6, 2018
    Publication date: September 16, 2021
    Inventors: Natalja ERMATSCHENKO, Christian LUCAS, Gerold HÜBNER
  • Publication number: 20210257629
    Abstract: A manufacturing process includes: depositing a first catalyst on a first gas diffusion layer (GDL) to form a first catalyst-coated GDL; depositing a first ionomer on the first catalyst-coated GDL to form a first gas diffusion electrode (GDE); depositing a second catalyst on a second GDL to form a second catalyst-coated GDL; depositing a second ionomer on the second catalyst-coated GDL to form a second GDE; and laminating the first GDE with the second GDE and with an electrolyte membrane disposed between the first GDE and the second GDE to form a membrane electrode assembly (MEA). A MEA includes a first GDL; a second GDL; an electrolyte membrane disposed between the first GDL and the second GDL; a first catalyst layer disposed between the first GDL and the electrolyte membrane; and a second catalyst layer disposed between the second GDL and the electrolyte membrane, wherein a thickness of the electrolyte membrane is about 15 ?m or less.
    Type: Application
    Filed: February 14, 2020
    Publication date: August 19, 2021
    Inventors: Friedrich B. Prinz, Timothy Goh, Shicheng Xu, Zhaoxuan Wang, Soonwook Hong, Yongmin Kim, Samuel Dull, Dong Un Lee, Thomas Francisco Jaramillo, Thomas Schladt, Gerold Huebner, Jonathan Muller, Glavas Vedran
  • Publication number: 20210091392
    Abstract: A method for reducing cell degradation in a fuel cell system includes adding oxygen-containing gas to a fuel in the anode chamber to prevent an increase in a cell voltage above a predetermined maximum value.
    Type: Application
    Filed: January 23, 2019
    Publication date: March 25, 2021
    Inventors: Miriam STIEFEL, Lasse SCHMIDT, Gerold HÜBNER