Abstract: The invention relates to thermosetting powder coating compositions comprising an unsaturated resin comprising ethylenic unsaturations and a thermal radical initiator comprising a first thermal radical initiator, wherein the first thermal radical initiator is a methyl-substituted benzoyl peroxide abbreviated herein as MBPO. The invention further relates to a process for making said thermosetting powder coating composition and processes for coating an article with said thermosetting powder coating composition. The invention further relates to a cured thermosetting powder coating composition derived upon curing of the thermosetting powder coating composition of the invention. The invention further relates to an article having coated thereon said thermosetting powder coating composition as well as to an article having coated and cured thereon said thermosetting powder coating composition.

Abstract: The invention relates to thermosetting powder coating compositions comprising an unsaturated resin comprising ethylenic unsaturations and a thermal radical initiator comprising a first thermal radical initiator, wherein the first thermal radical initiator is a methyl-substituted benzoyl peroxide abbreviated herein as MBPO. The invention further relates to a process for making said thermosetting powder coating composition and processes for coating an article with said thermosetting powder coating composition. The invention further relates to a cured thermosetting powder coating composition derived upon curing of the thermosetting powder coating composition of the invention. The invention further relates to an article having coated thereon said thermosetting powder coating composition as well as to an article having coated and cured thereon said thermosetting powder coating composition.

Abstract: Heat-curable powder coating compositions are provided which include i) at least one crystalline polyester resin present in an amount of at least 7.5 wt %; ii) at least one amorphous polyester resin present in an amount of at most 92.5 wt %; and iii) at least one peroxide present in an amount of at least 0.65 parts of peroxide in hundred parts of i)+ii) (pph), wherein the at least one crystalline polyester resin has 2-butenedioic acid ethylenic unsaturations and/or the at least one amorphous polyester resin has 2-butenedioic acid ethylenic unsaturations. The compositions may be cured to an acceptable degree at low temperature, e.g., 130° C. /20 minutes offering powder coatings that may exhibit enhanced flexibility and good adhesion. In addition, the compositions can suitably be used on heat- and/or non heat-sensitive substrates, even if the composition is highly pigmented.

Abstract: The invention relates to heat-curable powder coating composition comprising: i) at least one crystalline polyester resin present in an amount of at least 7.5 wt %; and ii) at least one amorphous polyester resin present in an amount of at most 92.5 wt %; and iii) at least one peroxide present in an amount of at least 0.