Abstract: Disclosed are polymer blends comprising a mixture of (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a metallic catalyst; (B) at least one phosphite ester compound; and (C) at least one hindered amine light stabilizer. The polymer blends exhibit improved color, especially when used as a component of a polyester/polycarbonate blend.

Abstract: Disclosed are stabilized aliphatic polyester compositions comprising an aliphatic polyester, a HALS, and a tris-aryl-S-triazine UV absorber that show low embrittlement, haze formation, and discoloration during weathering. Also disclosed are aliphatic polyester compositions comprising aliphatic polyester, a hindered amine light stabilizer, a triazine UV absorber, and a phosphite that exhibit low color prior to weathering but retain good clarity, color, and excellent impact strength after exposure to weathering conditions. The aliphatic polyester compositions may be used prepare shaped articles such as, for example, films, sheets, bottles, tubes, profiles, fibers, and molded articles.

Abstract: This invention relates to a polymer composition comprising (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid/or dialkyl ester thereof in the presence of a metallic catalyst; (B) a salt comprising at least one suitable phosphorus-containing acid and at least one suitable basic organic compound, such as a hindered amine light stabilizer; (C) at least one ultraviolet light absorbing compound and optionally at least one phenolic antioxidant. A second embodiment of the present invention pertains to a blend of (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid/or dialkyl ester thereof in the presence of a metallic catalyst; (B) a salt comprising at least one suitable phosphorus-containing acid and at least one suitable basic organic compound; (C) at least one ultraviolet light absorbing compound and, optionally, at least one phenolic antioxidant; and (D) at least one polycarbonate.

Abstract: This invention relates to polycarbonate compositions comprising: (A) at least one polycarbonate comprising repeating units derived from a dihydroxyaromatic compound or a dihydroxyaliphatic compound of the formula HO—Y—OH; and (B) at least one salt prepared from the reaction of one or more acidic phosphorus-containing compounds and one or more hindered amine light stabilizers. The polycarbonate compositions exhibit improved hydrolytic stability.

Abstract: Disclosed are polymer compositions comprising: (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a metallic catalyst; and (B) at least one salt prepared from the reaction of one or more acidic phosphorus-containing compounds and one or more basic organic compounds which contain nitrogen. The polyester compositions exhibit improved color, especially when used as a component of a polyester/polycarbonate blend. Also disclosed are polymer compositions comprising a polycarbonate in combination with components (A) and (B).

Abstract: This invention relates to a polyolefin composition comprising (A) at least one polyolefin prepared in the presence of at least one Ziegler Natta; (B) a salt comprising at least one suitable phosphorus-containing acid and at least one suitable basic organic compound, such as a hindered amine light stabilizer; (C) at least one phenolic species selected from one or more phenolic compounds selected from phenolic antioxidants and ultraviolet light absorbers.

Abstract: This invention relates to polycarbonate compositions comprising: (A) at least one polycarbonate comprising repeating units derived from a dihydroxyaromatic compound or a dihydroxyaliphatic compound of the formula HO—Y—OH; and (B) at least one salt prepared from the reaction of one or more acidic phosphorus-containing compounds and one or more hindered amine light stabilizers. The polycarbonate compositions exhibit improved hydrolytic stability.

Abstract: An ultraviolet absorption composition has been developed for the protection of packaging or container contents in the ultraviolet range of 290 nm to 390 nm, offering effective screening from all wavelengths of solar radiation. A combination of an optical brightener with an ultraviolet absorber has been found to provide effective screening without adding significant color to the polymer composition. This extended range of ultraviolet blocking over what can be achieved with ultraviolet absorbers alone is especially valuable in food and drink packaging applications where the contents of the packages need ultraviolet protection to prevent discoloration or development of undesirable flavors.

Abstract: The invention provides a biodegradable polymer composition comprising a biodegradable polymer and a phenol-containing compound mixed with the polymer. The phenol-containing compound is present in the biodegradable polymer at an amount sufficient to slow the degradation rate of the biodegradable polymer. The invention also pertains to a method for slowing the degradation rate of a biodegradable polymer.

Abstract: Optical brighteners are widely used for decreasing the apparent yellowness of polymeric materials. Polyethylene, as a coating film for photographic paper has presented unique problems because of its general lack of compatibility with conventional, large, fluorescent brightener molecules. The present invention provides a solution to this problem by incorporating into the polyethylene an optical brightener compatibilizing amount of a second polyolefin having alkyl groups pendant from the polymer backbone which serves to reduce the exudation of the optical brightener in articles or substrates comprised of or coated with such compositions.

Abstract: A blend of optical brighteners includes (a) from about 45 to 95 weight % of a mixture of benzoxazolyl stilbenes; and (b) from about 55 to about 5 weight % of at least one bis(benzoxazolyl)naphthalene based brightener, bis(benzoxazolyl)thiophene based brightener, a pyrazoline based brightener, a coumarin based brightener, and mixtures thereof, wherein the weight percents of the optical brightener blend are based on the total weight of optical brighteners in the blend. The optical brightener blend is useful for admixing with a polyolefin resin which in turn may be used for photo imaging applications.

Abstract: A thermoplastic polyolefin composition suitable for use as a coating for a photographic support includes an optical brightener and a polar additive. The polar additive substantially compatibilizes the polar optical brightener with the non-polar polyolefin. A method for adding a polar additive to a polyolefin is also disclosed.

Abstract: This invention provides cellulose ester fibers having an intermediate degree of substitution per anhydroglucose unit (DS/AGU) along with pigments which act as photooxidation catalyst. The fibers are useful as filler materials for tobacco products. The filter materials thus provided are easily dispersible and biodegradable and do not persist in the environment.

Abstract: This invention provides cellulose ester fibers having an intermediate degree of substitution per anhydroglucose unit (DS/AGU) along with pigments which act as photooxidation catalysts. The fibers are useful as filter materials for tobacco products. The filter materials thus provided are easily dispersible and biodegradable and do not persist in the environment.

Abstract: Provided is a facile three step process for preparing 2-phenylterephthalic acid starting with p-xylene, followed by alkylation, dehydrogenation, and oxidation of the methyl groups corresponding to the origional p-xylene. The product, 2-phenylterephthalic acid, is useful as an intermediate in the synthesis of polyesters comprised of residues of 2-phenylterephthalic acid.

Abstract: Disclosed are processes for the preparation of cyclohexanedicarboxylic acids by the non-catalytic hydrolysis or acidolysis of dialkyl cyclohexanedicarboxylate esters. The processes provide a means for converting dialkyl cyclohexanedicarboxylate esters to cyclohexanedicarboxylic acids without the co-production of solid by-products which present disposal problems.

Abstract: Disclosed are chemically-mixed, titanium-zinc oxide catalysts and the use of the catalysts in the manufacture of methanol and dimethyl ether wherein synthesis gas is contacted at elevated temperatures and pressures with the catalyst.

Abstract: Provided is a process for alkylating aromatic compounds in the presence of mixed oxides of titanium and gallium which have been found to be highly active catalysts for the alkylation of aromatics with alkyl esters, alcohols, olefins and ethers. When the alkyl acceptor is a phenol, the catalysts provide high reaction rates and high selectivity for ortho alkylated products.

Abstract: Provided are novel titania comprising anatase titanium dioxide and sodium, potassium, calcium, magnesium, barium, zinc, or magnesium salts of sulfuric or phosphoric acid. The titania of this invention are useful in the pigmentation of oxidizable polymers, while at the same time providing a catalyst system for the photooxidation of said oxidizable polymers.

Abstract: A process for preparation of 1,3- or 1,4-cyclohexanedicarboxylic acid comprising(A) preparing a solution comprised of the disodium salt of terephthalic acid or isophthalic acid and water,(B) continuously preparing the disodium salt of 1,3- or 1,4-cyclohexanedicarboxylic acid by continuously contacting the solution with hydrogen and the combination of ruthenium metal and a carbon support in a packed column,(C) preparing 1,3- or 1,4-cyclohexanedicarboxylic acid by contacting the disodium salt of 1,3- or 1,4-cyclohexanedicarboxylic acid with sulfuric acid or hydrochloric acid, and(D) recovering the 1,3- or 1,4-cyclohexanedicarboxylic acid by crystallization of the 1,3- or 1,4-cyclohexanedicarboxylic acid.