Abstract: Provided are compounds comprising a ligand LA of Formula I where the ligand LA is coordinated to Pt.

Abstract: Provided are compounds having a first ligand LA having a structure of Formula I: that are useful in OLED application and provide improved OLED properties.

Abstract: The present disclosure provides a metal coordination complex compound. The metal complex compound is capable of functioning as an emitter in an organic light emitting device (OLED) at room temperature, and has a vertical dipole ratio (VDR) greater than 0.33 in the OLED. Formulations, OLEDs, and consumer products including the same are also provided.

Abstract: Provided are organic compounds comprising a central seven-membered Ge or Si atom comprising ring to which three 6-membered carbocyclic aromatic groups are fused. Also provided are formulations comprising these organic compounds. Further provided are organic light emitting devices (OLEDs) as well as related consumer products that utilize these organic compounds.

Abstract: Provided are organic compounds comprising at least two 6-membered aromatic rings which are linked together via a direct bond and additionally via an nitrogen atom so to form a 5-membered nitrogen-containing ring, wherein a silyl or germyl group is attached in o-position of one of the 6-membered aromatic rings. Also provided are formulations comprising these organic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organic compounds.

Abstract: A compound comprising a first ligand LA of Formula I, In Formula I, X1 to X7 are each C or N; K1 is a direct bond or a linker; R1 and R2 are substituents; each R3, R4, R5, R?, R?, RA, RB, and RC is hydrogen or a General Substituent defined herein; LA is coordinated to a metal M; when R1 is substituted or unsubstituted aryl, specific conditions must be met, and when R1 is alkyl, other conditions must be met. Formulations, OLEDs, and consumer products containing the compound are also provided.

Abstract: Provided is a composition A that includes: a first dopant; and a first host; where the first dopant has a HOMO energy HOMODopant and a LUMO energy LUMODopant; the first host has a HOMO energy HOMOHost and a LUMO energy LUMOHost; |LUMOHost?HOMODopant|=X1; |LUMODopant?HOMOHost|=X2; the first dopant has an optical bandgap energy, Y; at least one of X1 and X2 is less than or equal to Y+0.026 eV; the composition A has a vertical dipole ratio VDR(A); composition B is a reference composition comprising the first dopant and a second host, wherein the second host is the composition B having a vertical dipole ratio VDR(B); the ratio of the first dopant and the first host in the composition A is identical to the ratio of the first dopant and second host in the composition B; and VDR(A)?VDR(B) is ?0.05.

Abstract: Provided is a compound having a formula of M(LA)(LB)(LC); where LA, LB and LC are each a bidentate ligand and are different from each other; M is selected from the group consisting of Ir, Os, Rh, Ru, Pt, and Pd; two or three of LA, LB and LC are optionally linked together to form a tetradentate or hexadentate ligand; LA has a structure of Formula I: where moieties A and B are each independently a monocyclic ring or a polycyclic fused ring system, where the monocyclic ring or each ring of the polycyclic fused ring system is independently a 5-membered to 10-membered carbocyclic or heterocyclic ring; X1 to X4 are each independently C or N; Z1 and Z2 are each independently C or N; K1 and K2 are each independently a direct bond, O, S, N(R?), P(R?), B(R?), C(R?)(R?), and Si(R?)(R?); Z1 is C if K1 is not a direct bond, Z2 is C if K2 is not a direct bond; L1 is a direct bond or an organic linker; RA and RB each independently represent mono to the maximum allowable substitution, or no substitution; wherein each R?

Abstract: The present disclosure provides a metal coordination complex compound. The metal complex compound is capable of functioning as an emitter in an organic light emitting device (OLED) at room temperature, and has a vertical dipole ratio (VDR) greater than 0.33 in the OLED. Formulations, OLEDs, and consumer products including the same are also provided.

Abstract: A compound comprising a first ligand LA of Formula I, is provided. In Formula I, moiety A and moiety B either a monocyclic ring or a polycyclic fused ring system; each of X1 to X4, Z1, and Z2 is C or N; K1 is a direct bond, O, S, N(R?), P(R?), B(R?), C(R?)(R?), or Si(R?)(R?); L1 is a direct bond or a linking group; each R?, R?, RA and RB is hydrogen or a General Substituent; and LA is coordinated to a metal M. In addition, RA or RB alone or in combination with a substituent of L1 form a 7-membered ring. Formulations, OLEDs, and consumer products containing the compound are also provided.

Abstract: Provided are compounds comprising a ligand LA of Formula I where the ligand LA is coordinated to Ir.

Abstract: A compound of Formula I, is provided. In Formula I, one of Z1, Z2, and Z3 is N and the remainder are C; each of L1 and L2 is independently selected from a direct bond and a linking group; at least one of R1, R2, RA, RB, RC, RD, and RE comprises a group R* having a structure selected form the group consisting of Formula II, -Q(R3)(R4)a(R5)b, Formula III, and Formula IV, Each R, R?, R?, R1, R2, R3, R4, R5, RA, RB, RC, RD, RE, RF, RG, and RH is independently hydrogen or a General Substituent, with the proviso that group R* is not adamantyl. Formulations, OLEDs, and consumer products containing the compound are also provided.

Abstract: Provided are organic light emitting devices (OLED) comprising an anode; a cathode, and an organic layer between the anode and the cathode, the organic layer comprising a light-emitting dopant within a host material, the light-emitting dopant being an optically active Pt complex comprising a tetradentate ligand; wherein one enantiomer of the optically active Pt complex is present in an enantiomeric excess (ee) of at least 5%. Further provided are OLEDs comprising an anode, a cathode, and an organic layer between the anode and the cathode, the organic layer the organic layer comprising a light-emitting chiral dopant within a chiral host material, the light-emitting chiral dopant being an optically active complex; wherein one enantiomer of the optically active complex of the chiral dopant is present in an ee of at least 5%, and wherein one enantiomer of the chiral host material is present in an ee of at least 5%.

Abstract: A compound having a structure of the formula Ir(LA)(LB), in which LA is a bidentate, tridentate, tetradentate, pentadentate, or hexadentate ligand and LB is a monodentate, bidentate, tridentate, or tetradentate ligand, or not present, and where the total denticity of LA plus LB is 6, and LA includes at least one structure of Formula I: is disclosed as a useful phosphorescent emitter compound.

Abstract: Provided are organometallic compounds comprising a first ligand LA which may be a bidentate, tridentate, tetradentate, pentadentate, or hexadentate ligand and which forms at least one 5-membered ring with a metal atom. Also provided are formulations comprising these organometallic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds.

Abstract: Provided are organometallic compounds comprising a chelating tetradentate ligand with at least four cyclic structures located around a central Pt or Pd atom that can be used as light-emitters. Also provided are formulations comprising these organometallic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds.

Abstract: Provided are compounds comprising ligands LA that are ligands of Pt and Ir complexes for OLED applications. Also provided are formulations comprising these compounds comprising ligands LA that are ligands of Pt and Ir complexes for OLED applications. Further provided are OLEDs and related consumer products that utilize these compounds comprising ligands LA that are ligands of Pt and Ir complexes for OLED applications.

Abstract: The present disclosure provides a metal coordination complex compound. The metal complex compound is capable of functioning as an emitter in an organic light emitting device (OLED) at room temperature, and has a vertical dipole ratio (VDR) greater than 0.33 in the OLED. Formulations, OLEDs, and consumer products including the same are also provided.

Abstract: Provided is an OLED structure includes an organic layer having a primary phosphorescent emitter and a first host; where one of the following conditions is true: (1) the organic layer further includes a secondary emitter; or (2) the OLED further includes a second organic layer where the second organic layer includes a secondary emitter. The primary phosphorescent emitter has a peak emission wavelength ?max that is ?600 nm and ?750 nm; the secondary emitter has a peak emission wavelength ?max that is ?750 nm; the primary phosphorescent emitter is capable of transferring energy to the secondary emitter; the first host has a lowest excited state triplet energy T1 that is at least 0.1 eV higher than that of the primary phosphorescent emitter; the primary phosphorescent emitter has the formula Pt(L1)m; L1 can represent one or more ligands that are the same or different; each L1 is independently monodentate or multidentate; and m represents a maximum possible number of ligands L1 that can coordinate to Pt.

Abstract: In one aspect, provided is a compound of Formula I, In Formula I, M is Pt or Pd; L has the structure F1 is or a direct bond; rings A, B, C, D, and F are independently monocyclic rings or multicyclic fused ring systems; each of X1 to X10 is independently C or N; each of Z1 to Z4 is C or N; each of L1 to L5 is a direct bond or an organic linker, each of a, b, c, and d is 0 or 1; each K1 to K4 is a direct bond, O, or S; each of Z1 to Z4 that is connected to O or S is C; and each RA, RB, RC, RD, RE, and RX is independently hydrogen or a substituent.