Patents by Inventor Gilbert Robert Bernard Germaine
Gilbert Robert Bernard Germaine has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9556396Abstract: A grease formulation containing a thickener and a Fischer-Tropsch derived base oil, in particular a heavy or extra heavy base oil. The use of a Fischer-Tropsch oil results in an increase in thickener concentration and in improved properties such as anti-wear and copper corrosion performance. Also provided is the use of a Fischer-Tropsch derived base oil in a grease formulation, for the purpose of improving its anti-wear and/or copper corrosion performance, and/or for reducing the concentration of an additive in the formulation.Type: GrantFiled: December 9, 2008Date of Patent: January 31, 2017Assignee: SHELL OIL COMPANYInventors: Gilbert Robert Bernard Germaine, David John Wedlock, Alan Richard Wheatley
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Patent number: 8221614Abstract: Base oil formulation containing (i) a Fischer-Tropsch derived light base oil and (ii) a Fischer-Tropsch derived gas oil. The formulation can be prepared by back-blending a Fischer-Tropsch derived light base oil with a Fischer-Tropsch derived gas oil, for instance derived from the same Fischer-Tropsch synthesis. Also provided is the use of a Fischer-Tropsch derived gas oil in a base oil formulation containing a Fischer-Tropsch derived light base oil, for the purpose of improving the cold flow properties of the formulation while maintaining its flash point above a desired target value, and/or for the purpose of reducing the concentration of a cold flow additive in the formulation, preferably with less of a reduction in the flash point of the formulation than theory would have predicted to occur due to the incorporation of the Fischer-Tropsch derived gas oil.Type: GrantFiled: December 4, 2008Date of Patent: July 17, 2012Assignee: Shell Oil CompanyInventors: Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20110290702Abstract: The present invention relates to a lubricating base oil blend comprising (a) a mineral oil derived base oil having a saturates content of more than 90 wt %, a sulphur content of less than 0.03 wt % and a viscosity index of between 80-150, and (b) a paraffinic base oil component having a viscosity at 1000 C of from 7 to 30 cSt (7 to 30 mm2/s), wherein component (b) is an isomerised Fischer-Tropsch derived bottoms product having a ratio of percentage of recurring methylene carbons which are four or more carbons removed from an end group and a branch to the percentage of isopropyl carbon atoms, as determined by 13C-NMR, of below 8.2.Type: ApplicationFiled: August 12, 2008Publication date: December 1, 2011Inventors: Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20100298187Abstract: A grease formulation containing a thickener and a Fischer-Tropsch derived base oil, in particular a heavy or extra heavy base oil. The use of a Fischer-Tropsch oil results in an increase in thickener concentration and in improved properties such as anti-wear and copper corrosion performance. Also provided is the use of a Fischer-Tropsch derived base oil in a grease formulation, for the purpose of improving its anti-wear and/or copper corrosion performance, and/or for reducing the concentration of an additive in the formulation.Type: ApplicationFiled: December 9, 2008Publication date: November 25, 2010Inventors: Gilbert Robert Bernard Germaine, David John Wedlock, Alan Richard Wheatley
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Publication number: 20100268004Abstract: Base oil formulation containing (i) a Fischer-Tropsch derived light base oil and (ii) a Fischer-Tropsch derived gas oil. The formulation can be prepared by back-blending a Fischer-Tropsch derived light base oil with a Fischer-Tropsch derived gas oil, for instance derived from the same Fischer-Tropsch synthesis. Also provided is the use of a Fischer-Tropsch derived gas oil in a base oil formulation containing a Fischer-Tropsch derived light base oil, for the purpose of improving the cold flow properties of the formulation whilst maintaining its flash point above a desired target value, and/or for the purpose of reducing the concentration of a cold flow additive in the formulation, preferably with less of a reduction in the flash point of the formulation than theory would have predicted to occur due to the incorporation of the Fischer-Tropsch derived gas oil.Type: ApplicationFiled: December 4, 2008Publication date: October 21, 2010Inventors: Gilbert Robert Bernard Germaine, David John Wedlock
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Patent number: 7674363Abstract: Process to prepare a haze free base oil having a cloud point of below 0° C. and a kinematic viscosity at 100° C. of greater than 10 cSt by performing the following steps: (a) hydroisomerisation of a Fischer-Tropsch synthesis product, (b) isolating one or more fuel products and a distillation residue, (c) reducing the wax content of the residue by contacting the feed with a hydroisomerization catalyst under hydroisomerization conditions, and (d) solvent dewaxing the product of step (c) to obtain the haze free base oil.Type: GrantFiled: December 21, 2004Date of Patent: March 9, 2010Assignee: Shell Oil CompanyInventors: Nicholas James Adams, Gilbert Robert Bernard Germaine
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Patent number: 7670996Abstract: A lubricant composition having a base oil and one or more additives wherein the lubricant composition has a kinematic viscosity at 100° C. of more than 5.6 cSt; a cold cranking simulated dynamic viscosity at ?35° C. according to ASTM D 5293 of less than 6200 centiPoise (cP); and, a mini rotary viscosity test value of less than 60000 cP according to ASTM D 4684, wherein the base oil has been obtained from a waxy paraffinic Fischer-Tropsch synthesized hydrocarbon.Type: GrantFiled: February 8, 2002Date of Patent: March 2, 2010Assignee: Shell Oil CompanyInventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20090230021Abstract: The invention relates to a process for reducing the cloud point of a base oil feed having a kinematic viscosity at 100° C. of greater than 10 cSt by separating the molecules inferring the high cloud point from the base oil by (a) depositing said molecules on one side of a cooled surface, (b) obtaining a base oil having a reduced cloud point and (c) melting the deposited molecules and separating the melted molecules from the surface and reusing said surface to perform step (a).Type: ApplicationFiled: July 17, 2006Publication date: September 17, 2009Inventors: Jakob Willem Duininck, Gilbert Robert Bernard Germaine, Wiecher Derk Evert Steenge
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Publication number: 20090159492Abstract: Lube base stocks and lube stock compositions, as well as a process for preparing lube base stocks and lube stock compositions, are disclosed. The lube oils preferably have a viscosity index above about 115. The process involves obtaining feed-stocks that have a 95% point below 1150° F. and feedstocks that have 95% point above 1150° F. The feedstocks that have a 95% point below 1150% are catalytically dewaxed, and the feedstocks that have 95% point above 1150% are solvent dewaxed. The resulting products can optionally be blended, and the base stocks can be combined with various additives to form lube oil compositions. Hydrotreatment can optionally be performed on the lube base stocks to remove olefins, oxygenates and other impurities. In one embodiment, one or more of the fractions are obtained from Fisher-Tropsch synthesis. One or more of the fractions can also be obtained from other sources, for example, via distillation of crude oil, provided that the fractions do not include appreciable amounts (i.e.Type: ApplicationFiled: June 23, 2005Publication date: June 25, 2009Inventors: Etienne Duhoux, Gilbert Robert Bernard Germaine, Yunus Sajad Hussein, Janet Marian Smithers, Wiecher Derk Evert Steenge, David John Wedlock
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Patent number: 7531081Abstract: A lubricating base oil composition having at least 95 wt % saturates, of which saturates fraction between 10 and 30 wt % are cyclo-paraffins and the remainder being n- and iso-paraffins, having a viscosity index of above 120 and a pour point of below ?15° C.Type: GrantFiled: February 13, 2002Date of Patent: May 12, 2009Assignee: Shell Oil CompanyInventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20090112041Abstract: The invention relates to a process to reduce the pour point of a waxy paraffinic feedstock comprising a fraction boiling above 450° C. by diluting said feedstock with a solvent comprising an aliphatic ketone compound and an aromatic compound, wherein the volume ratio of ketone compound to aromatic compound is lower than 0.7:1, chilling the mixture to a temperature at which wax is caused to precipitate, physically removing the wax from an oil phase and recovering an oil product having a lower pour point than the waxy paraffinic feedstock, wherein at least part of the waxy paraffinic feedstock is derived from Fischer-Tropsch synthesis products.Type: ApplicationFiled: June 22, 2006Publication date: April 30, 2009Inventors: Gilbert Robert Bernard Germaine, Francois Panissaud
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Patent number: 7497941Abstract: A process to prepare two or more lubricating base oil grades and a gas oil by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms; (b) separating the product of step (a) into one or more gas oil fractions and a base oil precursor fraction; (c) performing a pour point reducing step to the base oil precursor fraction obtained in step (b); and (d) separating the effluent of step (c) in two or more base oil grades.Type: GrantFiled: March 5, 2002Date of Patent: March 3, 2009Assignee: Shell Oil CompanyInventor: Gilbert Robert Bernard Germaine
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Patent number: 7473347Abstract: Process to prepare two or more base oil grades, which base oil grades have different kinematic viscositys at 100° C. from a waxy paraffinic Fischer-Tropsch product having a content of non-cyclic iso-paraffins of more than 70 wt % by: (a) obtaining from the waxy paraffinic Fischer-Tropsch product a distillate fraction having a viscosity corresponding to one of the desired base oil products; (b) performing a catalytic dewaxing step using the distillate fraction obtained in step (a) as feed; (c) separating the lower boiling compounds from the dewaxed product obtained in step (b) in order to obtain the desired base oil; and (d) repeating steps (a)–(c) for each base oil.Type: GrantFiled: March 5, 2002Date of Patent: January 6, 2009Assignee: Shell Oil CompanyInventor: Gilbert Robert Bernard Germaine
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Patent number: 7354508Abstract: The invention relates to a process to prepare a heavy and a light lubricating base oil from a partly isomerized Fischer-Tropsch derived feedstock, the feedstock having an initial boiling point of below 400° C. and a final boiling point of above 600° C. by (a) separating the fraction via distillation into a light base oil precursor fraction and a heavy base oil precursor fraction; (b) reducing the pour point of each separate base oil precursor fraction via dewaxing; and, (c) isolating the desired base oil products from the dewaxed oil fractions as obtained in step (b).Type: GrantFiled: June 25, 2003Date of Patent: April 8, 2008Assignee: Shell Oil CompanyInventors: Nicholas James Adams, Jan Lodewijk Maria Dierickx, Gilbert Robert Bernard Germaine, Laurent Georges Huve, David John Wedlock
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Patent number: 7332072Abstract: A process to prepare a waxy raffinate product by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch derived feed, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch derived feed have at least 30 carbon atoms; and, (b) isolating from the product of step (a) a waxy raffinate product having a T10 wt % boiling point of between 200° C. and 450° C. and a T90 wt % boiling point of between 400° C. and 650° C.Type: GrantFiled: March 5, 2002Date of Patent: February 19, 2008Assignee: Shell Oil CompanyInventors: Gilbert Robert Bernard Germaine, David John Wedlock
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Patent number: 7285206Abstract: A process to prepare a lubricating base oil and a gas oil by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2, and, wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms; (b) separating the product of step (a) into one or more gas oil fractions, a base oil precursor fraction and a higher boiling fraction; and (c) performing a pour point reducing step to the base oil precursor fraction obtained in step (b).Type: GrantFiled: March 4, 2002Date of Patent: October 23, 2007Assignee: Shell Oil CompanyInventor: Gilbert Robert Bernard Germaine
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Publication number: 20040118744Abstract: A lubricating base oil composition having at least 95 wt % saturates, of which saturates fraction between 10 and 30 wt % are cyclo-paraffins and the remainder being n- and iso-paraffins, having a viscosity index of above 120 and a pour point of below −15° C.Type: ApplicationFiled: January 9, 2004Publication date: June 24, 2004Inventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20040104145Abstract: Process to prepare two or more base oil grades, which base oil grades having different kinematic viscosity's at 100° C. from a waxy paraffinic Fischer-Tropsch product having a content of non-cyclic iso-paraffins of more than 70 wt % by (a) obtaining from the waxy paraffinic Fischer-Tropsch product a distillate fraction having a viscosity corresponding to one of the desired base oil products, (b) performing a catalytic dewaxing step using the distillate fraction obtained in step (a) as feed, (c) separating the lower boiling compounds from the dewaxed product obtained in step (b) in order to obtain the desired base oil, and (d) repeating steps (a)-(c) for each base oil.Type: ApplicationFiled: September 4, 2003Publication date: June 3, 2004Inventor: Gilbert Robert Bernard Germaine
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Publication number: 20040099571Abstract: Process to prepare a waxy raffinate product by (a) hydrocraking/hydroisomerisating a Fisher-Tropsch derived feed, wherein weight ratio of compounds having a least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch dervided feed have at least 30 carbon atoms, (b) isolating from the product of step (a) a waxy raffinate product having a T10 wt % boiling point of between 200 and 450° C. and a T90 wt % boiling point of between 400 and 650 ° C.Type: ApplicationFiled: December 16, 2003Publication date: May 27, 2004Inventors: Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20040079678Abstract: Process to prepare two or more lubricating base oil grades and a gas oil by (a) hydrocracking/hydroisomerisating a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms, (b) separating the product of step (a) into one or more gas oil fractions and a base oil precursor fraction, (c) performing a pour point reducing step to the base oil precursor fraction obtained in step (b), and (d) separating the effluent of step (c) in two or more base oil grades.Type: ApplicationFiled: September 4, 2003Publication date: April 29, 2004Inventor: Gilbert Robert Bernard Germaine