Patents by Inventor Gilbert Valdez
Gilbert Valdez has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7645847Abstract: A novel liquid phase polymerization process for preparing a polyolefin product having preselected properties is disclosed. The process includes the steps of providing a liquid feedstock which contains an olefinic component and a catalyst composition consisting of a stable complex of BF3 and a complexing agent therefor. The feedstock may comprise any one or more of a number of olefins including branched olefins such as isobutylene, C3 to C15 linear alpha olefins and C4 to C15 reactive non-alpha olefins. The feedstock and the catalyst composition are introduced into a residual reaction mixture recirculating in a loop reactor reaction zone provided in the tube side of a shell and tube heat exchanger at a recirculation rate sufficient to cause intimate intermixing of the residual reaction mixture, the added feedstock and the added catalyst composition.Type: GrantFiled: October 12, 2004Date of Patent: January 12, 2010Assignee: Texas Petrochemicals LLCInventors: C. Edward Baxter, Jr., Gilbert Valdez, Christopher Lobue, Timothy Lowry, Armen Abazajian
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Patent number: 7498396Abstract: A mid-range vinylidene content PIB polymer composition made by a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF3/methanol catalyst complex and a contact time of no more than 4 minutes. At least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof, and the content of tetra-substituted internal double bonds is very low, advantageously no more than about 10%, preferably less than about 5% and ideally less than about 1-2%.Type: GrantFiled: November 17, 2005Date of Patent: March 3, 2009Assignee: Texas Petrochemicals LPInventors: C. Edward Baxter, Jr., Gilbert Valdez, Christopher Lobue, Timothy Lowry, Armen Abazajian
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Patent number: 7091285Abstract: A reaction product comprising an adduct of a mid-range vinylidene content PIB polymer composition and maleic anhydride, a phenolic compound or a compound having a reactive site for subsequent amination. The PIB composition comprises a relatively low molecular weight, mid-range vinylidene content PIB polymer product wherein at least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof and the content of tetra-substituted internal double bonds is very low, preferably less than about 5% and ideally less than about 1–2%. The mid-range vinylidene content PIB polymer products may be prepared employing a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF3/methanol catalyst complex and a contact time of no more than 4 minutes.Type: GrantFiled: July 22, 2004Date of Patent: August 15, 2006Assignee: Texas Petrochemicals LPInventors: C. Edward Baxter, Jr., Christopher Lobue, Gilbert Valdez, Daniel Herndon, Timothy Lowry
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Patent number: 7056990Abstract: A process for making a relatively low molecular weight, mid-range vinylidene content PIB polymer product comprising a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF3/methanol catalyst complex and a contact time of no more than 4 minutes. At least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof, and the content of tetra-substituted internal double bonds is very low, advantageously no more than about 10%, preferably less than about 5% and ideally less than about 1–2%.Type: GrantFiled: October 19, 2004Date of Patent: June 6, 2006Assignee: Texas Petrochemicals, LPInventors: C. Edward Baxter, Jr., Gilbert Valdez, Christopher Lobue, Timothy Lowry, Armen Abazajian
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Patent number: 7037999Abstract: A relatively low molecular weight, mid-range vinylidene content PIB polymer product and a process for making the same. At least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof and the content of tetra-substituted internal double bonds is very low, preferably less than about 5% and ideally less than about 1–2%. The midrange vinylidene content PIB polymer products are prepared by a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF3/methanol catalyst complex and a contact time of no more than 4 minutes.Type: GrantFiled: March 19, 2002Date of Patent: May 2, 2006Assignee: Texas Petrochemicals LPInventors: C. Edward Baxter, Jr., Christopher Lobue, Gilbert Valdez, Daniel Herndon, Timothy Lowry
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Publication number: 20060079652Abstract: A mid-range vinylidene content PIB polymer composition made by a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF3/methanol catalyst complex and a contact time of no more than 4 minutes. At least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof, and the content of tetra-substituted internal double bonds is very low, advantageously no more than about 10%, preferably less than about 5% and ideally less than about 1-2%.Type: ApplicationFiled: November 17, 2005Publication date: April 13, 2006Inventors: C. Baxter, Gilbert Valdez, Christopher Lobue, Timothy Lowry, Armen Abazajian
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Publication number: 20060030684Abstract: Polyolefin product produced using process conducted in apparatus for olefin polymerization which includes one or more shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus may also include an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: ApplicationFiled: October 11, 2005Publication date: February 9, 2006Inventors: Christopher Lobue, Gilbert Valdez, Daniel Herndon, C. Baxter, Russell Reid
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Patent number: 6992152Abstract: Apparatus for olefin polymerization includes one or more shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus may also include an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: GrantFiled: August 19, 2004Date of Patent: January 31, 2006Assignee: Texas Petrochemicals LPInventors: Christopher Lobue, Gilbert Valdez, Daniel Herndon, C. Edward Baxter, Jr., Russell E. Reid, Sr.
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Publication number: 20060002828Abstract: Apparatus for olefin polymerization includes one or more shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus may also include an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: ApplicationFiled: June 28, 2005Publication date: January 5, 2006Inventors: Christopher Lobue, Gilbert Valdez, Daniel Herndon, C. Baxter,, Russell Reid,
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Publication number: 20050137363Abstract: A process for making a relatively low molecular weight, mid-range vinylidene content PIB polymer product comprising a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF3/methanol catalyst complex and a contact time of no more than 4 minutes. At least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof, and the content of tetra-substituted internal double bonds is very low, advantageously no more than about 10%, preferably less than about 5% and ideally less than about 1-2%.Type: ApplicationFiled: October 19, 2004Publication date: June 23, 2005Inventors: C. Baxter, Gilbert Valdez, Christopher Lobue, Timothy Lowry, Armen Abazajian
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Publication number: 20050101750Abstract: A novel liquid phase polymerization process for preparing a polyolefin product having preselected properties is disclosed. The process includes the steps of providing a liquid feedstock which contains an olefinic component and a catalyst composition consisting of a stable complex of BF3 and a complexing agent therefor. The feedstock may comprise any one or more of a number of olefins including branched olefins such as isobutylene, C3 to C15 linear alpha olefins and C4 to C15 reactive non-alpha olefins. The feedstock and the catalyst composition are introduced into a residual reaction mixture recirculating in a loop reactor reaction zone provided in the tube side of a shell and tube heat exchanger at a recirculation rate sufficient to cause intimate intermixing of the residual reaction mixture, the added feedstock and the added catalyst composition.Type: ApplicationFiled: October 12, 2004Publication date: May 12, 2005Inventors: C. Baxter, Gilbert Valdez, Christopher Lobue, Timothy Lowry, Armen Abazajian
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Patent number: 6884858Abstract: A novel liquid phase polymerization process for preparing a polyolefin product having preselected properties is disclosed. The process includes the steps of providing a liquid feedstock which contains an olefinic component and a catalyst composition consisting of a stable complex of BF3 and a complexing agent therefor. The feedstock may comprise any one or more of a number of olefins including branched olefins such as isobutylene, C3 to C15 linear alpha olefins and C4 to C15 reactive non-alpha olefins. The feedstock and the catalyst composition are introduced into a residual reaction mixture recirculating in a loop reactor reaction zone provided in the tube side of a shell and tube heat exchanger at a recirculation rate sufficient to cause intimate intermixing of the residual reaction mixture, the added feedstock and the added catalyst composition.Type: GrantFiled: July 30, 2002Date of Patent: April 26, 2005Assignee: Texas Petrochemicals LPInventors: C. Edward Baxter, Jr., Gilbert Valdez, Christopher Lobue, Timothy Lowry, Armen Abazajian
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Patent number: 6858188Abstract: Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: GrantFiled: May 9, 2003Date of Patent: February 22, 2005Assignee: Texas Petrochemicals, LPInventors: C. Edward Baxter, Jr., Daniel Herndon, James G. Wakeland, Russel E. Reid, Sr., Gilbert Valdez
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Publication number: 20050019227Abstract: Apparatus for olefin polymerization includes one or more shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus may also include an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: ApplicationFiled: August 19, 2004Publication date: January 27, 2005Inventors: Christopher Lobue, Gilbert Valdez, Daniel Herndon
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Patent number: 6844400Abstract: Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: GrantFiled: January 15, 2004Date of Patent: January 18, 2005Assignee: Texas Petrochemicals LPInventors: C. Edward Baxter, Jr., Daniel Herndon, James G. Wakeland, Russel E. Reid, Sr., Gilbert Valdez
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Patent number: 6844401Abstract: Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: GrantFiled: January 15, 2004Date of Patent: January 18, 2005Assignee: Texas Petrochemicals LPInventors: C. Edward Baxter, Jr., Daniel Herndon, James G. Wakeland, Russel E. Reid, Sr., Gilbert Valdez
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Publication number: 20040225084Abstract: Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: ApplicationFiled: January 15, 2004Publication date: November 11, 2004Applicant: Texas Petrochemicals, LPInventors: C. Edward Baxter, Daniel Herndon, James G. Wakeland, Russel E. Reid, Gilbert Valdez
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Publication number: 20040225083Abstract: Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: ApplicationFiled: January 15, 2004Publication date: November 11, 2004Applicant: Texas Petrochemicals, LPInventors: C. Edward Baxter, Daniel Herndon, James G. Wakeland, Russel E. Reid, Gilbert Valdez
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Publication number: 20040225087Abstract: Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: ApplicationFiled: May 9, 2003Publication date: November 11, 2004Inventors: C. Edward Baxter, Daniel Herndon, James G. Wakeland, Russel E. Reid, Gilbert Valdez
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Patent number: 6777506Abstract: Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition.Type: GrantFiled: January 15, 2004Date of Patent: August 17, 2004Assignee: Texas Petrochemicals, LPInventors: C. Edward Baxter, Jr., Daniel Herndon, James G. Wakeland, Russel T. Reid, Sr., Gilbert Valdez