Abstract: The present invention relates to the use of thermoplastic polymer compositions for impregnating reinforcing materials in the form of fabric or industrial fabrics for the manufacture of composite materials. The field of the invention is that of composite materials as well as molding/consolidation processes and obtained parts. The invention more particularly relates to a method of manufacturing a composite article by injection molding comprising at least the steps of introducing at least one reinforcement fabric into a preheated mold, partial closure of the mold, a temperature rise step of the mold, optionally a step of maintaining the temperature of the mold before injection of a thermoplastic polymer composition, a step of injecting a thermoplastic polymer composition into the mold, a step of mold closure to the final part thickness allowing the flow of the resin through the reinforcing fabric, a cooling step and a recovery step of the obtained composite article.

Abstract: The invention relates to a method for continuous production of a composite material profile by injection-pultrusion from at least one reinforcing fabric and at least one thermoplastic polymer having high fluidity, said method being characterized in that: i) said fabric is continuously pulled with a pulling speed of at least 0.4 m.min?1 in the course of said process; ii) the impregnation stage is performed by injection of a polymeric composition having high fluidity through the fabric; iii) the profile is then shaped with a specific thermal profile. The invention also relates to a profile obtained according to the method of the invention and a composite article comprising such a profile the curvature whereof may be modified in its curvature by bending and/or its profile by rotational molding.

Abstract: The present invention relates to the use of thermoplastic polymer compositions for impregnating reinforcing materials in the form of fabric or industrial fabrics for the manufacture of composite materials. The field of the invention is that of composite materials as well as molding/consolidation processes and obtained parts. The invention more particularly relates to a method of manufacturing a composite article by injection molding comprising at least the steps of introducing at least one reinforcement fabric into a preheated mold, partial closure of the mold, a temperature rise step of the mold, optionally a step of maintaining the temperature of the mold before injection of a thermoplastic polymer composition, a step of injecting a thermoplastic polymer composition into the mold, a step of mold closure to the final part thickness allowing the flow of the resin through the reinforcing fabric, a cooling step and a recovery step of the obtained composite article.

Abstract: Novolak resins are incorporated for enhancing the acid resistance of polyamide compositions. Polyamide compositions containing such novolak resins are useful for producing various plastic shaped articles, such as calibrated particles or injection-molded parts, and are particularly useful for the recovery of sludge, liquids, and gases present in underground reservoirs, especially in the field of hydrocarbon extraction such as crude oil or natural gas.

Abstract: The invention relates to a thermoplastic composition having improved fluidity in the molten state, comprising at least: (a) a polyamide that has a melt viscosity greater than or equal to 50 Pa·s, and (b) a non-evolutive polyamide having a melt viscosity lower than the melt viscosity of said polyamide (a), above 0.8 Pa·s, and having a number-average molecular weight Mn lower than that of said polyamide (a), said composition having a melt viscosity that is stabilized at a value below the melt viscosity of said polyamide (a), said polyamide (b) having: a concentration of amine end groups (AEG) and/or of carboxyl end groups (CEG) less than or equal to 20 meq/kg, or a concentration of amine end groups (AEG) greater than or equal to 25 meq/kg; a concentration of acid end groups (CEG) greater than or equal to 25 meq/kg; and a concentration of blocked end groups (BEG) greater than or equal to 25 meq/kg.

Abstract: The invention concerns a thermoplastic composition having high fluidity in the molten state, comprising at least: (a) one thermoplastic polymer matrix; (b) one oligomer selected from cyclic ester oligomers, ether oligomers and mixtures thereof, said oligomer having a degree of polymerization of between 2 and 25; and (c) one phenolic polymer; said compounds (b) and (c) being present in a weight ratio (c)/(b) varying from 0.25 to 6, and preferably from approximately 0.75 to 2.75. The invention also concerns a process for producing a composite article from such a composition by impregnating a reinforcement such as a fabric or a preform, the composite article obtained according to this process, and the use of an oligomer (b) in combination with at least one phenolic polymer (c), as a plasticizing additive in a thermoplastic polymer matrix.

Abstract: The invention relates to a method for continuous production of a composite material profile by injection-pultrusion from at least one reinforcing fabric and at least one thermoplastic polymer having high fluidity, said method being characterized in that: i) said fabric is continuously pulled with a pulling speed of at least 0.4 m·min?1 in the course of said process; ii) the impregnation stage is performed by injection of a polymeric composition having high fluidity through the fabric; iii) the profile is then shaped with a specific thermal profile. The invention also relates to a profile obtained according to the method of the invention and a composite article comprising such a profile the curvature whereof may be modified in its curvature by bending and/or its profile by rotational molding.

Abstract: The invention concerns a thermoplastic composition having high fluidity in the molten state, comprising at least: (a) one thermoplastic polymer matrix; (b) one oligomer selected from cyclic ester oligomers, ether oligomers and mixtures thereof, said oligomer having a degree of polymerization of between 2 and 25; and (c) one phenolic polymer; said compounds (b) and (c) being present in a weight ratio (c)/(b) varying from 0.25 to 6, and preferably from approximately 0.75 to 2.75. The invention also concerns a process for producing a composite article from such a composition by impregnating a reinforcement such as a fabric or a preform, the composite article obtained according to this process, and the use of an oligomer (b) in combination with at least one phenolic polymer (c), as a plasticizing additive in a thermoplastic polymer matrix.

Abstract: The invention relates to a thermoplastic composition having improved fluidity in the molten state, comprising at least: (a) a polyamide that has a melt viscosity greater than or equal to 50 Pa·s, and (b) a non-evolutive polyamide having a melt viscosity lower than the melt viscosity of said polyamide (a), above 0.8 Pa·s, and having a number-average molecular weight Mn lower than that of said polyamide (a), said composition having a melt viscosity that is stabilized at a value below the melt viscosity of said polyamide (a), said polyamide (b) having: a concentration of amine end groups (AEG) and/or of carboxyl end groups (CEG) less than or equal to 20 meq/kg, or a concentration of amine end groups (AEG) greater than or equal to 25 meq/kg; a concentration of acid end groups (CEG) greater than or equal to 25 meq/kg; and a concentration of blocked end groups (BEG) greater than or equal to 25 meq/kg.

Abstract: Novolak resins ere incorporated for enhancing the acid resistance of polyamide compositions. Polyamide compositions containing such novolak resins are useful for producing various plastic shaped articles, such as calibrated particles or injection-molded parts, and are particularly useful for the recovery of sludge, liquids, and gases present in underground reservoirs, especially in the field of hydrocarbon extraction such as crude oil or natural gas.

Abstract: Uses of low molecular mass, non-evolutive polyamide resins for making composite articles are described. Articles obtained from such resins having good mechanical properties, such as rigidity, breaking load, impact resistance, and fatigue behavior in particular, even when the articles are manufactured according to cycles shorter than those usually used, and without any processing before or after the manufacture of the composite articles, are also described.

Abstract: High fluidity polyamides are used for the impregnation of reinforcing cloth materials, namely, industrial fabrics, which impregnated cloths are converted into composite shaped articles.

Abstract: A method for manufacturing a composite article is described that includes a step of impregnating a reinforcing fabric with a semi-aromatic polyester composition in the molten state, having a melt viscosity ? of 20 Pa·s to 200 Pa·s. The reinforcing fabric can be maintained at a temperature of plus or minus 50° C. relative to the melting temperature of the polyester.

Abstract: The use of a polyamide including hydroxyaromatic units in order to increase the acid resistance of a polyamide composition is described. A polyamide composition comprising a polyamide that includes hydroxyaromatic units and use thereof for the manufacture of various plastic articles such as, for example, calibrated particles or injection-molded parts is also described. Such a composition is especially useful in the field of the recovery of slurries, liquids and gases present in underground reservoirs, and in particular in the field of the extraction of hydrocarbons, such as crude oil or natural gas.

Abstract: The present invention relates especially to a composition for manufacturing an article comprising one or more superposed layers each less than 5 centimeters thick, comprising a hydraulic binder and at least one compound chosen from an organic compound comprising at least two hydrophilic functions and a hydrophobic chain, and a polyamide oligomer. The use of these additives in the presence of hydraulic binder allows the manufacture of articles and coatings with good protection against water uptake, satisfactory water resistance and good mechanical properties such as breaking strength.

Abstract: An additive for a bitumen or polymer modified bitumen product, which is prepared by mixing together a sulphur-based product, a vulcanized rubber, for example, a waste vulcanized rubber, preferably a fatty acid, and a bitumen, is described. The use of this additive for preparing, with very limited gaseous emissions, elastomer-containing bituminous product is also described. Such use may be especially suitable for making bituminous coated material including, for example, asphalt concrete.

Abstract: Composite propping agents of low density and of high mechanical strength are based on a thermoplastic polymer matrix, in particular having low compressive deformation at high temperatures are especially useful in the field of well fracturing for the recovery of sludges, liquids and gases present in underground reservoirs, and in particular in the field of the extraction of hydrocarbons, such as crude oil or natural gas.

Abstract: An additive for a bitumen or polymer modified bitumen product, which is prepared by mixing together a sulphur-based product, a vulcanized rubber, for example, a waste vulcanized rubber, preferably a fatty acid, and a bitumen, is described. The use of this additive for preparing, with very limited gaseous emissions, elastomer-containing bituminous product is also described. Such use may be especially suitable for making bituminous coated material including, for example, asphalt concrete.

Abstract: The use of a polyamide modified by hydroxyl aromatic compounds used to impregnate reinforcement materials assuming the form of industrial fabric cloth for manufacturing composite materials is described. Also described, is a composite material produced and a method by which the composite material is produced. Further, the method by which the composite material is produced can include: a) impregnating a reinforcing cloth with a polyamide composition in a molten state, the polyamide including hydroxy aromatic units which are chemically linked to the polyamide chain; the composition including a novolac resin; and b) cooling and then recovering the composite article.

Abstract: A method for manufacturing a composite article is described that includes a step of impregnating a reinforcing fabric with a semi-aromatic polyester composition in the molten state, having a melt viscosity ? of 20 Pa·s to 200 Pa·s. The reinforcing fabric can be maintained at a temperature of plus or minus 50° C. relative to the melting temperature of the polyester.