Patent number: 9951291
Abstract: A lubricant composition includes an oil including a plurality of long-chain hydrocarbon molecules. A quantity of a catalytically active metal-organic additive is mixed with the oil. The metal-organic additive is formulated to fragment the long-chain hydrocarbon molecules of the oil into at least one of dimers and trimers under the influence of at least one of a mechanical loading and a thermal loading. In some embodiments, the metal-organic additive includes a compound of formula II: where: X is Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Rf, Db, Sg, Bh, Hs, Mt, Ds, Rg or Cn, and R1, R2, R3 and R4 are alkyl or alkyl halide.
Type:
Grant
Filed:
May 22, 2015
Date of Patent:
April 24, 2018
Assignee:
UChicago Argonne, LLC
Inventors:
Ali Erdemir, Anil U. Mane, Jeffrey W. Elam, Giovanni Ramirez, Osman Eryilmaz
Publication number: 20160340602
Abstract: A lubricant composition includes an oil including a plurality of long-chain hydrocarbon molecules. A quantity of a catalytically active metal-organic additive is mixed with the oil. The metal-organic additive is formulated to fragment the long-chain hydrocarbon molecules of the oil into at least one of dimers and trimers under the influence of at least one of a mechanical loading and a thermal loading. In some embodiments, the metal-organic additive includes a compound of formula II: where: X is Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Rf, Db, Sg, Bh, Hs, Mt, Ds, Rg or Cn, and R1, R2, R3 and R4 are alkyl or alkyl halide.
Type:
Application
Filed:
May 22, 2015
Publication date:
November 24, 2016
Applicant:
UChicago Argonne, LLC
Inventors:
Ali Erdemir, Anil U. Mane, Jeffrey W. Elam, Giovanni Ramirez, Osman Eryilmaz