Patents by Inventor Giuliana Schimperna

Giuliana Schimperna has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240120519
    Abstract: Non-aqueous redox flow battery (RFB) comprising:—a positive compartment in which a positive electrode is placed and in which a non-aqueous liquid positive electrolyte is made to flow;—a negative compartment in which a negative electrode is placed and in which a non-aqueous liquid negative electrolyte is made to flow;—an ion exchange membrane placed between the positive compartment and the negative compartment; wherein:—said non-aqueous liquid positive electrolyte comprises a solution of copper triflate or tetrafluoroborate complexes [Cu(I) or Cu(II)] in at least one organic solvent;—said non-aqueous liquid negative electrolyte comprises a solution of at least one benzothiadiazole having general formula (I): wherein:—R1 and R2, equal or different from each other, represent a hydrogen atom; or represent a C1-C20 alkyl group, preferably C1-C10, linear or branched, saturated or unsaturated; or represent a —O—R3 group wherein R3 is selected from C1-C20 alkyl groups, preferably C1-C10, linear or branched, saturated
    Type: Application
    Filed: November 23, 2021
    Publication date: April 11, 2024
    Inventors: Luigi ABBONDANZA, Giuliana SCHIMPERNA, Alessandra TACCA
  • Patent number: 11930705
    Abstract: There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia): The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.
    Type: Grant
    Filed: November 12, 2020
    Date of Patent: March 12, 2024
    Assignee: ENI S.P.A.
    Inventors: Giuliana Schimperna, Luigi Abbondanza, Antonio Alfonso Proto, Stefano Zanardi
  • Patent number: 11856806
    Abstract: There is a disubstituted diaryloxybenzoheterodiazole compound having general formula (I): This disubstituted diaryloxybenzoheterodiazole compound having general formula (I) may advantageously be used as a spectrum converter in luminescent solar concentrators (“Luminescent Solar Concentrators”—LSCs) which, in turn, are capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on either a rigid or flexible support.
    Type: Grant
    Filed: October 18, 2019
    Date of Patent: December 26, 2023
    Assignee: ENI S.P.A.
    Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
  • Patent number: 11713314
    Abstract: A process for the preparation of a disubstituted diaryloxybenzoheterodiazole compound having general formula (XII): wherein: Z represents a sulfur atom, an oxygen atom, a selenium atom; or a group NR6 wherein R6 is selected from linear or branched C1-C20 alkyl groups, or from optionally substituted aryl groups; R2 and R3, identical or different, represent a hydrogen atom, provided that R1 does not represent a hydrogen atom; or R1, R2 and R3 are selected from linear or branched C1-C20 alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted, linear or branched C1-C20 alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1 and R2, may optionally be bound together so as to form, together with carbon atoms to which R1 and R2 are bound, a saturated, unsaturated, or aromatic, cyclic or a polycyclic system containing from 3 to 14 carbon atoms, optionally containing one or more heteroatoms selected
    Type: Grant
    Filed: October 20, 2021
    Date of Patent: August 1, 2023
    Assignee: Eni S.P.A.
    Inventors: Giuliana Schimperna, Antonio Alfonso Proto
  • Patent number: 11706979
    Abstract: Disubstituted diaryloxybenzoheterodiazole compound of general formula (I): in which: Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, or from optionally substituted aryl groups; R1, R2, R3 and R4 are as defined in the claims. The disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.
    Type: Grant
    Filed: July 20, 2021
    Date of Patent: July 18, 2023
    Assignee: Eni S.P.A.
    Inventors: Luigi Abbondanza, Andrea Alessi, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
  • Publication number: 20220399509
    Abstract: There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia): The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.
    Type: Application
    Filed: November 12, 2020
    Publication date: December 15, 2022
    Applicant: ENI S.P.A.
    Inventors: Giuliana Schimperna, Luigi Abbondanza, Antonio Alfonso Proto, Stefano Zanardi
  • Patent number: 11427755
    Abstract: The present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. In particular the present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye, its process of preparation and use. The present invention concerns also objects or articles comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. The present invention concerns as well a photovoltaic module comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye.
    Type: Grant
    Filed: May 18, 2017
    Date of Patent: August 30, 2022
    Assignees: Eni S.P.A., Arkema France
    Inventors: Roberto Fusco, Antonio Alfonso Proto, Giuliana Schimperna, Jean Marc Boutillier, Sylvain Bourrigaud, Sylvain Tombolato, Véronique Carrere
  • Publication number: 20220165959
    Abstract: Disubstituted fluoroaryloxybenzoheterodiazole compound having general formula (I): Said disubstituted fluoroaryloxybenzoheterodiazole compound having general formula (I) may be advantageously used as a spectrum converter in luminescent solar concentrators (LSCs) capable, in turn, of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support.
    Type: Application
    Filed: March 19, 2020
    Publication date: May 26, 2022
    Applicant: ENI S.P.A.
    Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
  • Publication number: 20220098185
    Abstract: Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) wherein—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group wherein R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups;—R1, R2 and R3, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1, R2, may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen
    Type: Application
    Filed: October 20, 2021
    Publication date: March 31, 2022
    Inventors: Giuliana SCHIMPERNA, Antonio Alfonso PROTO
  • Publication number: 20210408393
    Abstract: Disubstituted diaryloxybenzoheterodiazole compound of general formula (I): in which: Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, or from optionally substituted aryl groups; R1, R2, R3 and R4 are as defined in the claims. The disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.
    Type: Application
    Filed: July 20, 2021
    Publication date: December 30, 2021
    Inventors: Luigi ABBONDANZA, Andrea ALESSI, Antonio Alfonso PROTO, Giuliana SCHIMPERNA, Liliana GILA
  • Patent number: 11208406
    Abstract: Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) and luminescent solar concentrator (LSC) including the same: wherein: Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group wherein R6 is selected from linear or branched C1-C20 alkyl groups, or from optionally substituted aryl groups; R1, R2 and R3, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20 alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20 alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1 and R2, may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, optionally containing one or more heteroatoms; or R2 and R3, may optionally be bound together so
    Type: Grant
    Filed: November 11, 2016
    Date of Patent: December 28, 2021
    Assignee: Eni S.P.A.
    Inventors: Giuliana Schimperna, Antonio Alfonso Proto
  • Publication number: 20210367176
    Abstract: A disubstituted diaryloxybenzoheterodiazole compound having general formula (I): wherein: R1, R2 and R3, which are the same as or different from each other, represent a hydrogen atom; or represent a halogen atom such as, for example, chlorine, bromine, fluorine, iodine, preferably fluorine; or are selected from optionally halogenated linear or branched C1-C12, preferably C1-C8, alkyl groups, optionally substituted phenoxy groups, provided that at least one of R1, R2 and R3 is an optionally substituted phenoxy group and, if R3 is an optionally substituted phenoxy group, at least one of R1, R2 is different from hydrogen; R4, which are the same as or different from each other, represent a hydrogen atom; or are selected from —COOR groups wherein R is selected from linear or branched C1-C8, preferably C1-C4, alkyl groups.
    Type: Application
    Filed: October 18, 2019
    Publication date: November 25, 2021
    Applicant: ENI S.P.A.
    Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
  • Publication number: 20210320262
    Abstract: Luminescent solar concentrator (LSC) having at least one dithienylpyridinethiadiazole compound having general formula (I) or (II): Said luminescent solar concentrator (LSC) can be advantageously used in the construction of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), both on rigid support, and on flexible support.
    Type: Application
    Filed: December 20, 2019
    Publication date: October 14, 2021
    Applicant: ENI S.P.A.
    Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
  • Patent number: 11133474
    Abstract: Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which:—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups;—R1, R2 and R3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.
    Type: Grant
    Filed: September 24, 2015
    Date of Patent: September 28, 2021
    Assignee: Eni S.P.A.
    Inventors: Luigi Abbondanza, Andrea Alessi, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
  • Publication number: 20200339560
    Abstract: Process for the preparation of a disubstituted diaryloxybenzoheterodiazole compound having general formula (I):
    Type: Application
    Filed: January 9, 2019
    Publication date: October 29, 2020
    Inventors: Giuliana Schimperna, Luca Beverina, Mauro Sassi
  • Publication number: 20200172799
    Abstract: The present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. In particular the present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye, its process of preparation and use. The present invention concerns also objects or articles comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. The present invention concerns as well a photovoltaic module comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye.
    Type: Application
    Filed: May 18, 2017
    Publication date: June 4, 2020
    Inventors: Roberto FUSCO, Antonio Alfonso PROTO, Giuliana SCHIMPERNA, Jean Marc BOUTILLIER, Sylvain BOURRIGAUD, Sylvain TOMBOLATO, Veronique CARRERE
  • Patent number: 10312395
    Abstract: Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoheterodiazole compound of general formula (I), in which: —Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group in which R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; —R1, R2 and R3, which are the same or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxyl groups, optionally substituted phenoxyl groups, or —COOR7 groups or —OCOR7 groups in which R7 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or is a cyano group, provided that when the substituents R1 represents a hydrogen atom, at least one of the substituents R2 and R3 represents an optionally substi
    Type: Grant
    Filed: September 24, 2015
    Date of Patent: June 4, 2019
    Assignee: Eni S.p.A.
    Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
  • Publication number: 20180327400
    Abstract: Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) wherein —Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group wherein R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; —R1, R2 and R3, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1, R2, may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxyg
    Type: Application
    Filed: November 11, 2016
    Publication date: November 15, 2018
    Inventors: Giuliana SCHIMPERNA, Antonio Alfonso PROTO
  • Patent number: 9920067
    Abstract: The present invention relates to bis-thienobenzothienothiophene compounds and a process for their preparation. More in particular, the present invention relates to a new angular bis-thienobenzothienothiophene compound and the process for its preparation wherein said process comprises reacting at least one dihalogenated dithiophene compound with at least one terminal alkyne and the subsequent double annulation reaction. Said bis-thienobenzothienothiophene compounds can be appropriately functionalized and polymerized to produce electron donor compounds that can be advantageously used in the construction of photovoltaic devices or semiconductor polymers. Furthermore, said bis-thienobenzothienothiophene compounds, after functionalization, may be advantageously used as spectral converters in luminescent solar concentrators.
    Type: Grant
    Filed: December 11, 2015
    Date of Patent: March 20, 2018
    Assignee: Eni S.p.A.
    Inventors: Gabriele Bianchi, Giuliana Schimperna
  • Publication number: 20170342087
    Abstract: The present invention relates to bis-thienobenzothienothiophene compounds and a process for their preparation. More in particular, the present invention relates to a new angular bis-thienobenzothienothiophene compound and the process for its preparation wherein said process comprises reacting at least one dihalogenated dithiophene compound with at least one terminal alkyne and the subsequent double annulation reaction. Said bis-thienobenzothienothiophene compounds can be appropriately functionalized and polymerized to produce electron donor compounds that can be advantageously used in the construction of photovoltaic devices or semiconductor polymers. Furthermore, said bis-thienobenzothienothiophene compounds, after functionalization, may be advantageously used as spectral converters in luminescent solar concentrators.
    Type: Application
    Filed: December 11, 2015
    Publication date: November 30, 2017
    Applicant: Eni S.p.A.it
    Inventors: Gabriele BIANCHI, Giuliana SCHIMPERNA