Patents by Inventor Giuliana Schimperna
Giuliana Schimperna has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240120519Abstract: Non-aqueous redox flow battery (RFB) comprising:—a positive compartment in which a positive electrode is placed and in which a non-aqueous liquid positive electrolyte is made to flow;—a negative compartment in which a negative electrode is placed and in which a non-aqueous liquid negative electrolyte is made to flow;—an ion exchange membrane placed between the positive compartment and the negative compartment; wherein:—said non-aqueous liquid positive electrolyte comprises a solution of copper triflate or tetrafluoroborate complexes [Cu(I) or Cu(II)] in at least one organic solvent;—said non-aqueous liquid negative electrolyte comprises a solution of at least one benzothiadiazole having general formula (I): wherein:—R1 and R2, equal or different from each other, represent a hydrogen atom; or represent a C1-C20 alkyl group, preferably C1-C10, linear or branched, saturated or unsaturated; or represent a —O—R3 group wherein R3 is selected from C1-C20 alkyl groups, preferably C1-C10, linear or branched, saturatedType: ApplicationFiled: November 23, 2021Publication date: April 11, 2024Inventors: Luigi ABBONDANZA, Giuliana SCHIMPERNA, Alessandra TACCA
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Patent number: 11930705Abstract: There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia): The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.Type: GrantFiled: November 12, 2020Date of Patent: March 12, 2024Assignee: ENI S.P.A.Inventors: Giuliana Schimperna, Luigi Abbondanza, Antonio Alfonso Proto, Stefano Zanardi
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Patent number: 11856806Abstract: There is a disubstituted diaryloxybenzoheterodiazole compound having general formula (I): This disubstituted diaryloxybenzoheterodiazole compound having general formula (I) may advantageously be used as a spectrum converter in luminescent solar concentrators (“Luminescent Solar Concentrators”—LSCs) which, in turn, are capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on either a rigid or flexible support.Type: GrantFiled: October 18, 2019Date of Patent: December 26, 2023Assignee: ENI S.P.A.Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
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Patent number: 11713314Abstract: A process for the preparation of a disubstituted diaryloxybenzoheterodiazole compound having general formula (XII): wherein: Z represents a sulfur atom, an oxygen atom, a selenium atom; or a group NR6 wherein R6 is selected from linear or branched C1-C20 alkyl groups, or from optionally substituted aryl groups; R2 and R3, identical or different, represent a hydrogen atom, provided that R1 does not represent a hydrogen atom; or R1, R2 and R3 are selected from linear or branched C1-C20 alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted, linear or branched C1-C20 alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1 and R2, may optionally be bound together so as to form, together with carbon atoms to which R1 and R2 are bound, a saturated, unsaturated, or aromatic, cyclic or a polycyclic system containing from 3 to 14 carbon atoms, optionally containing one or more heteroatoms selectedType: GrantFiled: October 20, 2021Date of Patent: August 1, 2023Assignee: Eni S.P.A.Inventors: Giuliana Schimperna, Antonio Alfonso Proto
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Patent number: 11706979Abstract: Disubstituted diaryloxybenzoheterodiazole compound of general formula (I): in which: Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, or from optionally substituted aryl groups; R1, R2, R3 and R4 are as defined in the claims. The disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.Type: GrantFiled: July 20, 2021Date of Patent: July 18, 2023Assignee: Eni S.P.A.Inventors: Luigi Abbondanza, Andrea Alessi, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
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Publication number: 20220399509Abstract: There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia): The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.Type: ApplicationFiled: November 12, 2020Publication date: December 15, 2022Applicant: ENI S.P.A.Inventors: Giuliana Schimperna, Luigi Abbondanza, Antonio Alfonso Proto, Stefano Zanardi
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Patent number: 11427755Abstract: The present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. In particular the present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye, its process of preparation and use. The present invention concerns also objects or articles comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. The present invention concerns as well a photovoltaic module comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye.Type: GrantFiled: May 18, 2017Date of Patent: August 30, 2022Assignees: Eni S.P.A., Arkema FranceInventors: Roberto Fusco, Antonio Alfonso Proto, Giuliana Schimperna, Jean Marc Boutillier, Sylvain Bourrigaud, Sylvain Tombolato, Véronique Carrere
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Publication number: 20220165959Abstract: Disubstituted fluoroaryloxybenzoheterodiazole compound having general formula (I): Said disubstituted fluoroaryloxybenzoheterodiazole compound having general formula (I) may be advantageously used as a spectrum converter in luminescent solar concentrators (LSCs) capable, in turn, of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support.Type: ApplicationFiled: March 19, 2020Publication date: May 26, 2022Applicant: ENI S.P.A.Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
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Publication number: 20220098185Abstract: Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) wherein—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group wherein R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups;—R1, R2 and R3, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1, R2, may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygenType: ApplicationFiled: October 20, 2021Publication date: March 31, 2022Inventors: Giuliana SCHIMPERNA, Antonio Alfonso PROTO
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Publication number: 20210408393Abstract: Disubstituted diaryloxybenzoheterodiazole compound of general formula (I): in which: Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, or from optionally substituted aryl groups; R1, R2, R3 and R4 are as defined in the claims. The disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.Type: ApplicationFiled: July 20, 2021Publication date: December 30, 2021Inventors: Luigi ABBONDANZA, Andrea ALESSI, Antonio Alfonso PROTO, Giuliana SCHIMPERNA, Liliana GILA
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Patent number: 11208406Abstract: Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) and luminescent solar concentrator (LSC) including the same: wherein: Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group wherein R6 is selected from linear or branched C1-C20 alkyl groups, or from optionally substituted aryl groups; R1, R2 and R3, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20 alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20 alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1 and R2, may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, optionally containing one or more heteroatoms; or R2 and R3, may optionally be bound together soType: GrantFiled: November 11, 2016Date of Patent: December 28, 2021Assignee: Eni S.P.A.Inventors: Giuliana Schimperna, Antonio Alfonso Proto
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Publication number: 20210367176Abstract: A disubstituted diaryloxybenzoheterodiazole compound having general formula (I): wherein: R1, R2 and R3, which are the same as or different from each other, represent a hydrogen atom; or represent a halogen atom such as, for example, chlorine, bromine, fluorine, iodine, preferably fluorine; or are selected from optionally halogenated linear or branched C1-C12, preferably C1-C8, alkyl groups, optionally substituted phenoxy groups, provided that at least one of R1, R2 and R3 is an optionally substituted phenoxy group and, if R3 is an optionally substituted phenoxy group, at least one of R1, R2 is different from hydrogen; R4, which are the same as or different from each other, represent a hydrogen atom; or are selected from —COOR groups wherein R is selected from linear or branched C1-C8, preferably C1-C4, alkyl groups.Type: ApplicationFiled: October 18, 2019Publication date: November 25, 2021Applicant: ENI S.P.A.Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
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Publication number: 20210320262Abstract: Luminescent solar concentrator (LSC) having at least one dithienylpyridinethiadiazole compound having general formula (I) or (II): Said luminescent solar concentrator (LSC) can be advantageously used in the construction of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), both on rigid support, and on flexible support.Type: ApplicationFiled: December 20, 2019Publication date: October 14, 2021Applicant: ENI S.P.A.Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
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Patent number: 11133474Abstract: Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which:—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups;—R1, R2 and R3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.Type: GrantFiled: September 24, 2015Date of Patent: September 28, 2021Assignee: Eni S.P.A.Inventors: Luigi Abbondanza, Andrea Alessi, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
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Publication number: 20200339560Abstract: Process for the preparation of a disubstituted diaryloxybenzoheterodiazole compound having general formula (I):Type: ApplicationFiled: January 9, 2019Publication date: October 29, 2020Inventors: Giuliana Schimperna, Luca Beverina, Mauro Sassi
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Publication number: 20200172799Abstract: The present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. In particular the present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye, its process of preparation and use. The present invention concerns also objects or articles comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. The present invention concerns as well a photovoltaic module comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye.Type: ApplicationFiled: May 18, 2017Publication date: June 4, 2020Inventors: Roberto FUSCO, Antonio Alfonso PROTO, Giuliana SCHIMPERNA, Jean Marc BOUTILLIER, Sylvain BOURRIGAUD, Sylvain TOMBOLATO, Veronique CARRERE
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Patent number: 10312395Abstract: Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoheterodiazole compound of general formula (I), in which: —Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group in which R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; —R1, R2 and R3, which are the same or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxyl groups, optionally substituted phenoxyl groups, or —COOR7 groups or —OCOR7 groups in which R7 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or is a cyano group, provided that when the substituents R1 represents a hydrogen atom, at least one of the substituents R2 and R3 represents an optionally substiType: GrantFiled: September 24, 2015Date of Patent: June 4, 2019Assignee: Eni S.p.A.Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
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Publication number: 20180327400Abstract: Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) wherein —Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group wherein R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; —R1, R2 and R3, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1, R2, may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygType: ApplicationFiled: November 11, 2016Publication date: November 15, 2018Inventors: Giuliana SCHIMPERNA, Antonio Alfonso PROTO
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Patent number: 9920067Abstract: The present invention relates to bis-thienobenzothienothiophene compounds and a process for their preparation. More in particular, the present invention relates to a new angular bis-thienobenzothienothiophene compound and the process for its preparation wherein said process comprises reacting at least one dihalogenated dithiophene compound with at least one terminal alkyne and the subsequent double annulation reaction. Said bis-thienobenzothienothiophene compounds can be appropriately functionalized and polymerized to produce electron donor compounds that can be advantageously used in the construction of photovoltaic devices or semiconductor polymers. Furthermore, said bis-thienobenzothienothiophene compounds, after functionalization, may be advantageously used as spectral converters in luminescent solar concentrators.Type: GrantFiled: December 11, 2015Date of Patent: March 20, 2018Assignee: Eni S.p.A.Inventors: Gabriele Bianchi, Giuliana Schimperna
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Publication number: 20170342087Abstract: The present invention relates to bis-thienobenzothienothiophene compounds and a process for their preparation. More in particular, the present invention relates to a new angular bis-thienobenzothienothiophene compound and the process for its preparation wherein said process comprises reacting at least one dihalogenated dithiophene compound with at least one terminal alkyne and the subsequent double annulation reaction. Said bis-thienobenzothienothiophene compounds can be appropriately functionalized and polymerized to produce electron donor compounds that can be advantageously used in the construction of photovoltaic devices or semiconductor polymers. Furthermore, said bis-thienobenzothienothiophene compounds, after functionalization, may be advantageously used as spectral converters in luminescent solar concentrators.Type: ApplicationFiled: December 11, 2015Publication date: November 30, 2017Applicant: Eni S.p.A.itInventors: Gabriele BIANCHI, Giuliana SCHIMPERNA