Patents by Inventor Giuseppe Cantatore

Giuseppe Cantatore has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4927925
    Abstract: Compounds of formula (I) ##STR1## in which R.sub.1 is hydrogen, O.sup.., CN, NO, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl, OH-monosubstituted C.sub.2 -C.sub.6 -alkyl or 2,3-dihydroxypropyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.18 -cycloalkyl, C.sub.6 -C.sub.18 -aryl or C.sub.7 -C.sub.18 -aralkyl, R.sub.3 is C.sub.6 -C.sub.18 -aryl or a group of the formula (II) ##STR2## in which R.sub.1 is as defined above, n is an integer from 1 to 4 and R.sub.4 is an organic or inorganic radical of a valency equal to n are useful for stabilizing organic material against oxidative, thermal and/or light induced degradation.
    Type: Grant
    Filed: October 13, 1988
    Date of Patent: May 22, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4906678
    Abstract: Compounds of the formula (I) ##STR1## wherein R.sub.1 and R.sub.5 are independently hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or a group of the formula (II), ##STR2## R.sub.2, R.sub.3 and R.sub.4 are independently C.sub.2 -C.sub.12 -alkylene, R is a group of the formula (III) ##STR3## wherein R.sub.6 is C.sub.2 -C.sub.8 -dialkylamino, C.sub.1 -C.sub.4 -alkoxy, a 5-membered to 7-membered heterocyclic group containing a nitrogen atom which is attached to the triazine residue or a group of the formula (IV), ##STR4## R.sub.7 and R.sub.8 are independently C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, benzyl or a group of the formula (II), subject to the proviso that both, R.sub.1 and R.sub.5 are different from hydrogen, if R is a group ##STR5## are useful as light stabilizers, heat stabilizers and/or oxidation stabilizers for organic materials, in particular synthetic polymers.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: March 6, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Francois Gugumus
  • Patent number: 4883870
    Abstract: The compounds of the formula (I) ##STR1## in which R.sub.1 is C.sub.1 -C.sub.8 -alkyloxy, allyloxy, allylamino, di(C.sub.1 -C.sub.4 -alkyl)amino, diallylamino, a 5-membered to 7-membered nitrogen containing heterocyclic group with the nitrogen atom linked to the triazine ring, or a group of the formula (II), ##STR2## R.sub.2 is hydrogen, O.sup.., OH, NO, CH.sub.2 CN, C.sub.1 -C.sub.8 -alkyl, allyl, benzyl, C.sub.1 -C.sub.8 -acyl, C.sub.1 -C.sub.18 -alkyloxy, C.sub.5 -C.sub.12 -cycloalkyloxy or OH-monosubstituted C.sub.2 -C.sub.4 -alkyl, R.sub.3 and R.sub.5 independently are hydrogen, C.sub.1 -C.sub.12 -alkyl,* monosubstituted by OH, by C.sub.1 -C.sub.4 -alkyloxy or by di(C.sub.1 -C.sub.4 -alkyl)amino, or a group of the formula (III) ##STR3## with R.sub.2 as defined above, R.sub.4 is hydrogen, C.sub.1 -C.sub.12 -alkyl or cyclohexyl and n is an integer from 2 to 6, are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers. * C.sub.5 -C.
    Type: Grant
    Filed: July 11, 1988
    Date of Patent: November 28, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
  • Patent number: 4859724
    Abstract: Bicyclic piperidine compounds of the general formula (I) ##STR1## in which R.sub.1 is hydrogen, O.cndot., OH, NO, CH.sub.2 CN, C.sub.1 -C.sub.8 -alkyl, allyl, benzyl, C.sub.1 -C.sub.8 -acyl, OH-monosubstituted C.sub.2 -C.sub.4 -alkyl, 2,3-epoxypropyl, C.sub.1 -C.sub.18 -alkyloxy, C.sub.5 -C.sub.12 -cycloalkyloxy or 2,3-dihydroxypropyl and R.sub.2 is a direct bond or --CH.sub.2 --, can be used as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular, synthetic polymers.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: August 22, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4855434
    Abstract: The novel compounds of the formula (I) ##STR1## in which n is 1 or 2, R.sub.1 is hydrogen, 0.sup..multidot. NO, cyanomethyl, C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, benzyl, C.sub.1 -C.sub.7 acyl or OH-monosubstituted C.sub.2 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl, R.sub.3 is a group of the formula (II) ##STR2## with R.sub.6 being as defined for R.sub.1, R.sub.4 is --COOR.sub.3 or --CN and, if n is 1, R.sub.5 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.4 alkyl substituted by C.sub.1 -C.sub.12 alkoxy or di(C.sub.1 -C.sub.6 alkyl)amino, or C.sub.5 -C.sub.12 cycloalkyl unsubstituted or substituted by 1, 2 or 3 C.sub.1 -C.sub.4 alkyl radicals, benzyl, benzyl substituted by 1, 2 or 3 C.sub.1 -C.sub.4 alkyl radicals, or a group of the formula (II), and, if n is 1 and R.sub.4 is --CN, R.sub.
    Type: Grant
    Filed: February 16, 1988
    Date of Patent: August 8, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4843159
    Abstract: A compound of formula (I) ##STR1## in which R.sub.1 and R.sub.2 are e.g. hydrogen or methyl, R.sub.3 is e.g. a group ##STR2## or a group R.sub.5 X-- with R.sub.5 being e.g. hydrogen, C.sub.1 -C.sub.18 -alkyl or C.sub.3 -C.sub.18 -alkenyl and X being e.g. --O--, --S-- or ##STR3## and R.sub.6 is as defined for R.sub.5, or R.sub.3 represents a 5-membered to 7-membered nitrogen containing heterocyclic group with the free valency on the nitrogen, n is an integer from 2 to 6, and R.sub.4 is a nitrogen containing organic radical of a valency equal to n.The compounds of formula (I) are particularly effective in stabilizing organic material against oxidative, thermal and/or light induced degradation.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: June 27, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4803234
    Abstract: Compounds of formula (I) ##STR1## in which R.sub.1 is hydrogen, O.sup.., CN, NO, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl, OH-monosubstituted C.sub.2 -C.sub.6 -alkyl or 2,3-dihydroxypropyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.18 -cycloalkyl, C.sub.6 -Chd 18-aryl or C.sub.7 -C.sub.18 -aralkyl, R.sub.3 is C.sub.6 -C.sub.18 -aryl or a group of the formula (II) ##STR2## in which R.sub.1 is as defined above, n is an integer from 1 to 4 and R.sub.4 is an organic or inorganic radical of a valency equal to n are useful for stabilizing organic material against oxidative, thermal and/or light induced degradation.
    Type: Grant
    Filed: January 29, 1987
    Date of Patent: February 7, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4780493
    Abstract: Novel piperidine compounds of the general formula (I) ##STR1## in which m is an integer from 1 to 4, R.sub.1 and R.sub.2 are as defined in claim 1 and at least one 2,2,6,6-tetramethylpiperidinyl group, being present in R.sub.1 or R.sub.2 are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic material, especially for synthetic polymers.
    Type: Grant
    Filed: April 22, 1986
    Date of Patent: October 25, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4769443
    Abstract: Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R.sub.3 and R.sub.4 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R.sub.5 additionally can be a radical of formula VII ##STR3## and R.sub.4 is C.sub.2 -C.sub.
    Type: Grant
    Filed: August 3, 1987
    Date of Patent: September 6, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Giuseppe Cantatore
  • Patent number: 4751281
    Abstract: Novel polymeric compounds of the repeating structural unit (I) ##STR1## in which R.sub.1 is hydrogen, 0.degree., CN, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl or C.sub.2 -C.sub.6 -alkyl substituted by OH, R.sub.2 is C.sub.2 -C.sub.18 -alkylene, C.sub.4 -C.sub.18 -alkylene substituted by 1 or 2 oxygen or nitrogen atoms in the chain, C.sub.5 -C.sub.18 -cycloalkylene, C.sub.6 -C.sub.18 -arylene or C.sub.8 -C.sub.18 -aralkylene, R.sub.3 is as defined for R.sub.2 or is a group of the formula (II) or (III) ##STR2## in which R.sub.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sub.5 is C.sub.2 -C.sub.12 -alkylene, C.sub.4 -C.sub.12 -alkenylene subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, or is C.sub.8 -C.sub.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: June 14, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4696961
    Abstract: Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R.sub.3 and R.sub.5 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R.sub.5 additionally can be a radical of formula VII ##STR3## and R.sub.4 is C.sub.2 -C.sub.
    Type: Grant
    Filed: September 20, 1984
    Date of Patent: September 29, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Giuseppe Cantatore
  • Patent number: 4695599
    Abstract: The use of piperidine compounds of the formula ##STR1## as light stabilizers, heat stabilizers and oxidation stabilizers is described.
    Type: Grant
    Filed: October 4, 1985
    Date of Patent: September 22, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Giuseppe Cantatore
  • Patent number: 4618634
    Abstract: Novel compounds containing piperidine groups, of the general formula ##STR1## in which R.sub.1 is hydrogen, O--, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or -alkynyl, C.sub.7 -C.sub.12 -aralkyl or C.sub.1 -C.sub.12 -acyl, m is an integer from 1 to 12, n is an integer from 1 to 3 and A is an amine radical, are suitable as light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers. Processes for their preparation are also described.
    Type: Grant
    Filed: February 27, 1985
    Date of Patent: October 21, 1986
    Assignee: Ciba-Geigy S.p.A.
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4608436
    Abstract: Novel piperidine compounds having a stabilizing activity for organic material, especially for synthetic polymers, are of the formula ##STR1## in which R.sub.1, R.sub.2, X and n are as defined in the text.
    Type: Grant
    Filed: April 9, 1985
    Date of Patent: August 26, 1986
    Assignee: Ciba-Geigy S.p.A.
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4578454
    Abstract: A novel class of polymeric compounds containing piperidine radicals of the formula ##STR1## in which X is a divalent radical selected from the group comprising ##STR2## is described. The novel compounds are light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers and are particularly effective in polyolefine films, fibres and tapes.
    Type: Grant
    Filed: May 8, 1984
    Date of Patent: March 25, 1986
    Assignee: Ciba-Geigy S.p.A.
    Inventor: Giuseppe Cantatore
  • Patent number: 4547548
    Abstract: Polycondensation compounds containing piperidine and triazine groups, having a mean molecular weight from 1000 to 20,000 and constituted by structural units a and b of the formula ##STR1## are suitable as anti-actinic stabilizers for incorporation in polymeric materials.
    Type: Grant
    Filed: July 19, 1984
    Date of Patent: October 15, 1985
    Assignee: Ciba-Geigy S.p.A.
    Inventor: Giuseppe Cantatore
  • Patent number: 4546148
    Abstract: Novel polycondensed compounds containing piperidine groups of polycarbamate structure, of the general formula: ##STR1##
    Type: Grant
    Filed: July 19, 1984
    Date of Patent: October 8, 1985
    Assignee: Ciba-Geigy S.p.A.
    Inventor: Giuseppe Cantatore
  • Patent number: 4536581
    Abstract: A process for preparing 2,2,6,6-tetramethyl-4-piperidone from ammonia and acetone, wherein acetone and ammonia are reacted in a single stage for a time of 2 to 8 hours in an acetone:ammonia molar ratio of 20:1 to 4:1, at a temperature of 50.degree. to 120.degree. C. and at a pressure of 1 to 50 atmospheres, in the presence of 0.001-0.1 moles of acid catalysts per mole of acetone used in the reaction.
    Type: Grant
    Filed: May 18, 1983
    Date of Patent: August 20, 1985
    Assignee: Ciba-Geigy S.p.A.
    Inventors: Giuseppe Cantatore, Paolo Cassandrini
  • Patent number: 4525503
    Abstract: The invention relates to new piperidine compounds which act as light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers, in particular for hydrocarbon polymers. The compounds are piperidinol carbamates of the formula: ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and A have the meanings defined in the description and y is an integer from 1 to 4. In particular, A represents a monovalent to tetravalent radical, always bonded to the carboxy-piperidine radicals via nitrogen atoms.
    Type: Grant
    Filed: September 8, 1982
    Date of Patent: June 25, 1985
    Assignee: Ciba-Geigy S.p.A.
    Inventor: Giuseppe Cantatore
  • Patent number: 4501837
    Abstract: The invention relates to new piperidine compounds which act as light stabilisers, heat stabilisers and oxidation stabilisers for synthetic polymers, in particular for hydrocarbon polymers. The compounds are piperidinol carbamates of the formula: ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and A have the meanings defined in the description and y is an integer from 1 to 4. In particular, A represents a monovalent to tetravalent radical, always bonded to the carboxy-piperidine radicals via nitrogen atoms.
    Type: Grant
    Filed: August 31, 1982
    Date of Patent: February 26, 1985
    Assignee: Ciba-Geigy S.p.A.
    Inventor: Giuseppe Cantatore