Patents by Inventor Giuseppe Penzo
Giuseppe Penzo has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20150322178Abstract: Process for treating polyolefin particles obtained by gas-phase polymerization of one or more olefins in the presence of a polymerization catalyst system and a C3-C5 alkane as polymerization diluent in a gas-phase polymerization reactor, the process comprising the steps of a) discharging the polyolefin particles continuously or discontinuously from the gas-phase polymerization reactor and transferring the particles to a first degassing vessel; b) contacting therein the polyolefin particles with a gaseous stream comprising at least 85 mol-% of C3-C5 alkane while the polyolefin particles have an average residence time in the first degassing vessel of from 5 minutes to 5 hours; c) transferring the polyolefin particles to a second degassing vessel; d) contacting therein the polyolefin particles with a stream comprising nitrogen and steam while the polyolefin particles have an average residence time in the second degassing vessel of from 5 minutes to 2 hours, wherein the contacting is carried out at conditions unType: ApplicationFiled: December 11, 2013Publication date: November 12, 2015Inventors: Giuseppe Penzo, Giulia Mei, Gabriele Mei, Antonio De Lucia, Pietro Baita
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Publication number: 20150315302Abstract: Process for preparing a polyolefin polymer comprising the steps of a) forming a particulate polyolefin polymer by polymerizing one or more olefins in the presence of a polymerization catalyst system in a polymerization reactor; b) discharging the formed polyolefin particles from the polymerization reactor; c) degassing the polyolefin particles by a process comprising at least a final step of contacting the polyolefin particles with a nitrogen stream in a degassing vessel; and d) transferring the polyolefin particles from the vessel, in which the contacting of the polyolefin particles with the nitrogen stream is carried out, to a melt mixing device, in which the polyolefin particles are melted, mixed and thereafter pelletized, without passing the particles through a buffering device, wherein the degassing vessel is only partly filled with polyolefin particles and the empty volume within the degassing vessel is sufficient to take up additional polyolefin particles for at least 3 hours if the transfer of polType: ApplicationFiled: December 11, 2013Publication date: November 5, 2015Inventors: Giuseppe Penzo, Giulia Mei, Gabriele Mei, Antonio De Lucia, Pietro Baita
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Patent number: 9133291Abstract: Process for transferring polyolefin particles from a first gas-phase polymerization reactor to a second gas-phase polymerization reactor in a multistage polymerization of olefins carried out in at least two serially connected gas-phase polymerization reactors, wherein the first gas-phase reactor is a fluidized-bed reactor comprising a gas distribution grid and a settling pipe, which is integrated with its upper opening into the distribution grid and contains a bed of polyolefin particles which moves from top to bottom of the settling pipe, the process comprising the steps of introducing a fluid into the settling pipe in an amount that an upward stream of the fluid is induced in the bed of polyolefin particles above the fluid introduction point; withdrawing polyolefin particles from the lower end of the settling pipe; and transferring the withdrawn polyolefin particles into the second gas-phase polymerization reactor, process for polymerizing olefins comprising such a process for transferring polyolefin pType: GrantFiled: December 4, 2012Date of Patent: September 15, 2015Assignee: Basell Polyolefine GmbHInventors: Massimo Covezzi, Giuseppe Penzo, Gabriele Mei, Giulia Mei, Pietro Baita, Gerhardus Meier, Antonio De Lucia, Ulf Schueller, Gianpiero Ferraro
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Patent number: 9073027Abstract: A gas-phase polymerization reactor having interconnected polymerization zones comprising:—a riser through which the polymer particles flow upwards under fast fluidization conditions or transport conditions;—a downcomer through which the polymer particles flow downward in a densified form under the action of gravity, the bottom of said downcomer being connected to the lower region of said riser by means of a transport section, said transport section being designed as a bend descending from the downcomer to the riser.Type: GrantFiled: September 2, 2011Date of Patent: July 7, 2015Assignee: Basell Poliolefine Italia S.r.l.Inventors: Silvia Soffritti, Riccardo Rinaldi, Maurizio Dorini, Giuseppe Penzo
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Publication number: 20140309384Abstract: Process for transferring polyolefin particles from a first gas-phase polymerization reactor to a second gas-phase polymerization reactor in a multistage polymerization of olefins carried out in at least two serially connected gas-phase polymerization reactors, wherein the first gas-phase reactor is a fluidized-bed reactor comprising a gas distribution grid and a settling pipe, which is integrated with its upper opening into the distribution grid and contains a bed of polyolefin particles which moves from top to bottom of the settling pipe, the process comprising the steps of introducing a fluid into the settling pipe in an amount that an upward stream of the fluid is induced in the bed of polyolefin particles above the fluid introduction point; withdrawing polyolefin particles from the lower end of the settling pipe; and transferring the withdrawn polyolefin particles into the second gas-phase polymerization reactor, process for polymerizing olefins comprising such a process for transferring polyolefin particType: ApplicationFiled: December 4, 2012Publication date: October 16, 2014Applicant: Basell Polyolefine GmbHInventors: Massimo Covezzi, Giuseppe Penzo, Gabriele Mei, Giulia Mei, Pietro Baita, Gerhardus Meier, Antonio De Lucia, Ulf Schueller, Gianpiero Ferraro
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Publication number: 20130165605Abstract: A gas-phase polymerization reactor having interconnected polymerization zones comprising:—a riser through which the polymer particles flow upwards under fast fluidization conditions or transport conditions—a dowcomer through which the polymer particles flow downward in a densified form under the action of gravity, the bottom of said downcomer being connected to the lower region of said riser by means of a transport section, said transport section being designed as a bend descending from the downcomer to the riser.Type: ApplicationFiled: September 2, 2011Publication date: June 27, 2013Applicant: Basell Poliolefine Italia S.r.I.Inventors: Silvia Soffritti, Riccardo Rinaldi, Maurizio Dorini, Giuseppe Penzo
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Patent number: 8198383Abstract: A process for the gas-phase polymerization of ?-olefins carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate Fp of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.Type: GrantFiled: December 17, 2008Date of Patent: June 12, 2012Assignee: Basell Poliolefine Italia, s.r.l.Inventors: Antonio Mazzucco, Riccardo Rinaldi, Silvia Soffritti, Enrico Balestra, Giuseppe Penzo, Gabriele Mei
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Patent number: 8148478Abstract: A process for the polymerization of olefins carried out in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, a gas recycle stream being withdrawn from said first polymerization zone, subjected to cooling below its dew point and then returned to said first polymerization zone, the process being characterized in that said gas recycle stream is cooled at a temperature Tc ranging from 0.05° C. to 3° C. below its dew point.Type: GrantFiled: May 15, 2009Date of Patent: April 3, 2012Assignee: Basell Poliolefine Italia s.r.l.Inventors: Riccardo Rinaldi, Antonio Mazzucco, Enrico Balestra, Giuseppe Penzo, Maurizio Dorini, Gabriele Mei
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Patent number: 8097686Abstract: A process for the multistage polymerization of olefins in a sequence of an upstream slurry reactor and a downstream gas-phase reactor, the transfer of polymer from the upstream reactor to the downstream reactor comprising the following steps: a) heating the slurry of polyolefin particles to evaporate the liquid polymerization medium; b) separating the polyolefin particles from the obtained gaseous phase in at least a separation chamber; c) transferring the polyolefin particles to said downstream reactor by means of a couple of lock hoppers working intermittently in parallel, where one of said lock hoppers is continuously filled with the polymer coming from said separation chamber, while simultaneously the other one is continuously pressurized by means of a gas comprising the reaction mixture coming from said downstream reactor.Type: GrantFiled: August 27, 2008Date of Patent: January 17, 2012Assignee: Basell Poliolefine Italia s.r.l.Inventors: Dorini Maurizio, Giuseppe Penzo, Rinaldi Riccardo
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Publication number: 20110054127Abstract: A process for the polymerisation of olefins carried out in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, a gas recycle stream being withdrawn from said first polymerisation zone, subjected to cooling below its dew point and then returned to said first polymerisation zone, the process being characterised in that said gas recycle stream is cooled at a temperature Tc ranging from 0.05° C. to 3° C. below its dew point.Type: ApplicationFiled: May 15, 2009Publication date: March 3, 2011Applicant: Basell Polyolefine Italia s.r.l.Inventors: Riccardo Rinaldi, Antonio Mazzucco, Enrico Balestra, Giuseppe Penzo, Maurizio Dorini, Gabriele Mei
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Publication number: 20100317811Abstract: A process for the gas-phase polymerization of ?-olefins carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate Fp of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.Type: ApplicationFiled: December 17, 2008Publication date: December 16, 2010Applicant: Basell Poliolefine Italia s.r.l.Inventors: Antonio Mazzucco, Riccardo Rinaldi, Silvia Soffritti, Enrico Balestra, Giuseppe Penzo, Gabriele Mei
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Publication number: 20100305283Abstract: A process for the multistage polymerization of olefins in a sequence of an upstream slurry reactor and a downstream gas-phase reactor, the transfer of polymer from the upstream reactor to the downstream reactor comprising the following steps: a) heating the slurry of polyolefin particles to evaporate the liquid polymerization medium; b) separating the polyolefin particles from the obtained gaseous phase in at least a separation chamber; c) transferring the polyolefin particles to said downstream reactor by means of a couple of lock hoppers working intermittently in parallel, where one of said lock hoppers is continuously filled with the polymer coming from said separation chamber, while simultaneously the other one is continuously pressurized by means of a gas comprising the reaction mixture coming from said downstream reactor.Type: ApplicationFiled: August 27, 2008Publication date: December 2, 2010Applicant: Basell Poliolefine Italia s.r.lInventors: Maurizio Dorini, Giuseppe Penzo, Riccardo Rinaldi
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Patent number: 7786254Abstract: A process to perform the finishing of polyolefins produced by gas-phase catalytic polymerization of one or more ?-olefins in the presence of a polymerization diluent selected from a C3-C5 alkane, wherein the polyolefin granules discharged from the gas-phase reactor are subjected to: (1) a first degassing step in which said polyolefin is counter-currently contacted with a gaseous stream containing at least 85% by mol of a stripping agent selected from a C3-C5 alkane, said gaseous stream being continuously derived from the monomer recovery section of the polymerization plant; (2) a second degassing step in which said polyolefin is counter-currently contacted with steam, the amount of steam being from 10 to 200 Kg per 1000 kg of polyolefin.Type: GrantFiled: August 1, 2007Date of Patent: August 31, 2010Assignee: Basell Polyolefine GmbHInventors: Pietro Baita, Giuseppe Penzo, Gabriele Mei
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Patent number: 7763685Abstract: A method of discharging polymer from a continuously operated polymerization reactor, wherein at least a monomer is polymerized to form polymer particles, the method comprising adjusting the discharge rate of the polymer particles by means of a piston valve having a piston element connected to an actuator, said actuator being able to modulate the piston stroke inside said piston valve.Type: GrantFiled: July 4, 2005Date of Patent: July 27, 2010Assignee: Basell Poliolefine Italia s.r.l.Inventors: Luciano Michielin, Maurizio Dorini, Giuseppe Penzo, Riccardo Rinaldi
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Patent number: 7732551Abstract: A continuous process for minimizing the agglomeration of freshly manufactured polyolefin pellets comprising the steps of: feeding an aqueous stream containing polyolefin pellets to a tower, cooling said polyolefin pellets during their upward flow along said tower by means of a downward flow of a cooling agent having a density higher than said polyolefin, collecting the cooled pellets from the top of said tower after a residence time in the tower comprised between 2 and 20 minutes.Type: GrantFiled: May 27, 2004Date of Patent: June 8, 2010Assignee: Basell Poliolefine Italia s.r.l.Inventors: Pier Luigi Di Federico, Carlo Ciccarone, Luciano Michielin, Giuseppe Penzo
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Publication number: 20100004408Abstract: A process to perform the finishing of polyolefins produced by gas-phase catalytic polymerization of one or more ?-olefins in the presence of a polymerization diluent selected from a C3-C5 alkane, wherein the polyolefin granules discharged from the gas-phase reactor are subjected to: (1) a first degassing step in which said polyolefin is counter-currently contacted with a gaseous stream containing at least 85% by mol of a stripping agent selected from a C3-C5 alkane, said gaseous stream being continuously derived from the monomer recovery section of the polymerization plant; (2) a second degassing step in which said polyolefin is counter-currently contacted with steam, the amount of steam being from 10 to 200 Kg per 1000 kg of polyolefin.Type: ApplicationFiled: August 1, 2007Publication date: January 7, 2010Inventors: Pietro Baita, Giuseppe Penzo, Gabriele Mei
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Publication number: 20090234083Abstract: A solution process for polymerizing one or more ?-olefins of formula CH2?CHR, where R is H or an alkyl radical C1-12, to produce a polymer that is soluble in the reaction medium, the process comprising: (a) polymerization in a solution phase of one or more ?-olefins in the presence of an organo-aluminum compound and a catalyst system comprising a transition metal compound as the catalyst component; (b) the polymeric solution obtained from step a) is then pressurized and transferred by means of a screw pump to a successive step for removing the unreacted monomers from the polymer; wherein the pumping capacity of said screw pump is kept constant by adding the polymeric solution with water at a feeding point upstream the screw pump.Type: ApplicationFiled: July 18, 2006Publication date: September 17, 2009Applicant: Basell Poliolefine Italia s.r.l.Inventors: Daniele Bigiavi, Giuseppe Penzo
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Patent number: 7582723Abstract: Process for the polymerization of ethylene or of ethylene with further 1-olefins, in which the ethylene is polymerized in the presence of a catalyst in a gas-phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove the heat of polymerization, wherein the polymer particles are discharged continuously or discontinuously from the reactor, the polymer particles are separated from the major part of the concomitantly discharged gas and the polymer particles are degassed, the gas is freed of entrained fine particles and is separated from a low-boiling fraction comprising ethylene or from a high boiling fraction containing further 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation stage, a propane fraction is separated off in a second separation stage and this propane fraction is used for degassing the polymer particles discharged from the reactor, with the proportion of ethylene in the propane fraction being less than 1 mol % and the proportion ofType: GrantFiled: January 30, 2006Date of Patent: September 1, 2009Assignee: Basell Polyolefine GmbHInventors: Giuseppe Penzo, Cyrus Ahmadzade-Youssefi, Rainer Karer, Ulrich Nieken
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Patent number: 7414095Abstract: A solution process for polymerizing one or more ?-olefins of the formula CH2?CHR, where R is H or an alkyl radical C1-C18, to produce a polymer that is soluble in the reaction medium, comprising the steps of: continuously polymerizing in a liquid phase the ?-olefin in the presence of a catalyst system based on a transition metal compound to obtain a solution of polymer in the reaction medium; the polymeric solution obtained from step a) is then mixed in one or more mixing stages with an aqueous mixture comprising one or more organic compounds having at least a hydroxy or epoxy group, said aqueous mixture having a dynamic viscosity at 30° C. higher than 50 cP (centiPoise).Type: GrantFiled: November 29, 2004Date of Patent: August 19, 2008Assignee: Basell Polioefine Italia s.r.l.Inventors: Giuseppe Penzo, Daniele Bigiavi, Massimo Covezzi, Maria Silvia Tonti, Anna Fait, Pietro Baita
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Publication number: 20080177012Abstract: Process for the polymerization of ethylene or of ethylene with further 1-olefins, in which the ethylene is polymerized in the presence of a catalyst in a gas-phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove the heat of polymerization, wherein the polymer particles are discharged continuously or discontinuously from the reactor, the polymer particles are separated from the major part of the concomitantly discharged gas and the polymer particles are degassed, the gas is freed of entrained fine particles and is separated from a low-boiling fraction comprising ethylene or from a high boiling fraction containing further 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation stage, a propane fraction is separated off in a second separation stage and this propane fraction is used for degassing the polymer particles discharged from the reactor, with the proportion of ethylene in the propane fraction being less than 1 mol % and the proportion ofType: ApplicationFiled: January 30, 2006Publication date: July 24, 2008Applicant: Basell Polyolefine GmbHInventors: Giuseppe Penzo, Cyrus Ahmadzade-Youssefi, Rainer Karer, Ulrich Nieken