Abstract: Flame retardant compositions that include a thermoplastic polyurethane, a metal hydrate flame retardant and a phosphorus-based flame retardant are provided. The compositions are characterized by good flame retardant properties, as well as high insulation resistance.

Abstract: Halogen-free, flame retardant compositions comprising in weight percent based on the weight of the composition: A. 20 to 60% TPU/Si-g-EVA polymer blend in which the Si-g-EVA is crosslinked, B. 1 to 25% organic phosphate ester, C. 30 to 60% metal hydrate, and D. 0.1 to 10% epoxidized novolac. Optionally, the compositions further comprise in weight percent based on the weight of the composition, one or more of: E. 0.01 to 0.5% anti-dripping agent, F. 0.1 to 2% additive; and G. 0.1 to 5% filler.

Abstract: This invention provides intumescent, halogen-free, polymeric, silicon-phosphorus-nitrogen (SPN) flame retardant, a process for their preparation, and systems, compositions and articles into which they are incorporated. The inventive intumescent, halogen-free, SPN polymer compositions afford good flame retardant performance at a lower loading compared to conventional phosphorus and nitrogen based intumescent flame retardant compositions.

Abstract: Halogen-free, thermoplastic polyurethane-based compositions having good mechanical and flame-retardant properties are provided. The compositions include flame-retardant aromatic organic phosphate compounds that do not exhibit migration in molded products, such as cable and wire jacketing and insulation. The compositions include a continuous resin phase comprising a thermoplastic polyurethane elastomer, at least one aromatic organic phosphate flame retardant having a melting point of at least 50.

Abstract: The present invention is a flame-retardant polyurethane composition comprising (a) a thermoplastic polyurethane-based resin component, (b) a phosphorus flame retardant particulate filler, and (c) a low melting temperature phosphorus flame retardant agent.

Abstract: The present disclosure provides a flexible, halogen-free, flame retardant composition. The composition includes from about 25 wt % to about 95 wt % of a thermoplastic polyurethane (TPU); from about 5 wt % to about 50 wt % of an olefin block copolymer (OBC); and from about 30 wt % to about 70 wt % of a flame retardant. The flame retardant is selected from resorcinol bis(diphenyl 5 phosphate) (RDP), bis diphenyl phosphate (BDP), bisphenol-A bis(diphenyl phosphate) (BPADP), aluminum trihydrate (ATH), a nitrogen/phosphorus-based halogen-free flame retardant, epoxidized novolac resin, and combinations thereof. The composition requires no compatibilizer for the TPU and OBC. The composition finds application in wire and cable structures.

Abstract: Halogen-free TPU compositions comprise in weight percent based on the weight of the composition: A. 1 to 99% thermoplastic polyurethane (TPU), B. 1 to 50% tris(2-butoxyethyl)phosphate (TBEP), C. 1 to 70% metal hydrate, and D. 1 to 70% organic phosphate ester other than tris(2-butoxyethyl)phosphate. These compositions exhibit better smoke suppression as compared with conventional organic phosphate flame retardant TPU compositions such as those based on resorcinol bis(diphenyl phosphate) (RDP) and bisphenol-A bis(diphenyl phosphate) (BPADP) in the absence of TBEP.

Abstract: Halogen-free, thermoplastic polyurethane-based compositions having good mechanical and flame-retardant properties are provided. The compositions include flame-retardant aromatic organic phosphate compounds that do not exhibit migration in molded products, such as cable and wire jacketing and insulation.

Abstract: Halogen-free, flame-retardant thermoplastic polyester elastomer (TPE-E) compositions that include at least one thermoplastic polyester elastomer, at least one low-melting, phosphorus-based flame retardant having a melting temperature no higher than 150° C., and a blend of solid intumescent flame retardants comprising a phosphorus-based, organic salt flame retardant and a nitrogen-based organic flame retardant are provided. The presence of the low-melting, phosphorus-based flame retardant renders the compositions more resistant to scratch-whitening.

Abstract: This invention provides intumescent, halogen-free, polymeric, silicon-phosphorus-nitrogen (SPN) flame retardant, a process for their preparation, and systems, compositions and articles into which they are incorporated. The inventive intumescent, halogen-free, SPN polymer compositions afford good flame retardant performance at a lower loading compared to conventional phosphorus and nitrogen based intumescent flame retardant compositions.

Abstract: A halogen-free, flame retardant composition comprises thermoplastic polyurethane, olefin block copolymer, carbonyl-containing olefin polymer compatibilizer, and flame retardant package comprising bisphenol-A bis(diphenyl phosphate) and/or resorcinol bis(diphenyl phosphate), a nitrogen/phosphorus based, halogen-free flame retardant, and epoxidized novolac. The composition that will not only be processed easily to make a wire or cable sheath but also pass both the VW-1 flame retardancy test and the UL1581 heat deformation test at 150° C. exhibits good tensile and flexibility properties.

Abstract: Halogen-free, flame-retardant thermoplastic compositions that include a styrenic block copolymer, a low-melting, phosphorus-based flame retardant having a melting temperature no higher than 170° C., and a blend of solid intumescent phosphorus and nitrogen-containing flame retardants. The blend of solid intumescent flame retardants include at least two phosphorous and nitrogen-containing phosphoric acid salts that synergistically enhance the flame-retardant properties of the compositions relative to compositions that include other flame-retardant packages.

Abstract: Halogen-free TPU compositions comprise in weight percent based on the weight of the composition: A. 1 to 99% thermoplastic polyurethane (TPU), B. 1 to 50% tris(2-butoxyethyl)phosphate (TBEP), C. 1 to 70% metal hydrate, and D. 1 to 70% organic phosphate ester other than tris(2-butoxyethyl)phosphate. These compositions exhibit better smoke suppression as compared with conventional organic phosphate flame retardant TPU compositions such as those based on resorcinol bis(diphenyl phosphate) (RDP) and bisphenol-A bis(diphenyl phosphate) (BPADP) in the absence of TBEP.

Abstract: Halogen-free, flame retardant compositions comprising in weight percent based on the weight of the composition: A. 20 to 60% TPU/Si-g-EVA polymer blend in which the Si-g-EVA is crosslinked, B. 1 to 25% organic phosphate ester, C. 30 to 60% metal hydrate, and D. 0.1 to 10% epoxidized novolac. Optionally, the compositions further comprise in weight percent based on the weight of the composition, one or more of: E. 0.01 to 0.5% anti-dripping agent, F. 0.1 to 2% additive; and G. 0.1 to 5% filler.

Abstract: Halogen-free, flame-retardant thermoplastic polyester elastomer (TPE-E) compositions that include at least one thermoplastic polyester elastomer, at least one low-melting, phosphorus-based flame retardant having a melting temperature no higher than 150° C., and a blend of solid intumescent flame retardants comprising a phosphorus-based, organic salt flame retardant and a nitrogen-based organic flame retardant are provided. The presence of the low-melting, phosphorus-based flame retardant renders the compositions more resistant to scratch-whitening.

Abstract: A halogen-free, flame retardant composition comprises thermoplastic polyurethane, olefin block copolymer, carbonyl-containing olefin polymer compatibilizer, and flame retardant package comprising bisphenol-A bis(diphenyl phosphate) and/or resorcinol bis(diphenyl phosphate), a nitrogen/phosphorus based, halogen-free flame retardant, and epoxidized novolac. The composition that will not only be processed easily to make a wire or cable sheath but also pass both the VW-1 flame retardancy test and the UL1581 heat deformation test at 150° C. exhibits good tensile and flexibility properties.

Abstract: The present disclosure provides a flexible, halogen-free, flame retardant composition. The composition includes from about 25 wt % to about 95 wt % of a thermoplastic polyurethane (TPU); from about 5 wt % to about 50 wt % of an olefin block copolymer (OBC); and from about 30 wt % to about 70 wt % of a flame retardant. The flame retardant is selected from resorcinol bis(diphenyl 5 phosphate) (RDP), bis diphenyl phosphate (BDP), bisphenol-A bis(diphenyl phosphate) (BPADP), aluminum trihydrate (ATH), a nitrogen/phosphorus-based halogen-free flame retardant, epoxidized novolac resin, and combinations thereof. The composition requires no compatibilizer for the TPU and OBC. The composition finds application in wire and cable structures.

Abstract: Polymer blends comprising a first phase comprising a thermoplastic polyurethane matrix and a second phase comprising a crosslinked polar olefin polymer are provided. The first phase is a continuous phase and the second phase can be co-continuous with the first phase, or dispersed as a non-continuous phase in the first phase. The first phase further comprises a metal hydroxide flame retardant and an organic flame retardant. The second phase further includes a metal hydroxide which is coupled to the olefin polymer via a silane coupling agent.

Abstract: Flame retardant compositions that include a thermoplastic polyurethane, a metal hydrate flame retardant and a phosphorus-based flame retardant are provided. The compositions are characterized by good flame retardant properties, as well as high insulation resistance.

Abstract: The present invention is a flame-retardant polyurethane composition comprising (a) a thermoplastic polyurethane-based resin component, (b) a phosphorus flame retardant particulate filler, and (c) a low melting temperature phosphorus flame retardant agent.