Abstract: A novel copolymer for use in organic photovoltaics and other related electronic fields and related synthesis pathway. The novel copolymer displays the first example of an H2DPP co-monomer being directly incorporated into the main chain of a polymer repeat unit to form a co-polymer. An example co-polymer includes H2DPP-co-ProDOT. The related synthesis pathway displays significant simplicity and eliminates needs for reaction pathways, reagents, conditions, and the like associated with waste, toxicity, and other undesired properties.