Patents by Inventor Grant C. Edwards

Grant C. Edwards has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5102530
    Abstract: Cracking catalysts which yield higher octane gasoline than conventional cracking catalysts are made with large pore size zeolites such as zeolite Beta and zeolite ZSM-20 in the low sodium, H.sup.+ form. These zeolites are mixed with a matrix which contains at least a binder and formed into catalyst particles. These catalysts are especially suitable to be used in fluid catalytic cracking.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: April 7, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Grant C. Edwards, Alan W. Peters
  • Patent number: 4898846
    Abstract: Cracking catalysts which yield higher octane gasoline than conventional cracking catalysts are made with large pore size zeolites such as zeolite Beta and zeolite ZSM-20 in the low sodium, H.sup.+ form. These zeolites are mixed with a matrix which contains at least a binder and formed into catalyst particles. These catalysts are especially suitable to be used in fluid catalytic cracking.
    Type: Grant
    Filed: March 21, 1986
    Date of Patent: February 6, 1990
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Grant C. Edwards, Alan W. Peters
  • Patent number: 4764269
    Abstract: Catalytic cracking catalyst compositions having a high degree of activity and selectivity for the production of high octane gasoline fractions which comprise stabilized crystalline molecular sieve SAPO-37 dispersed in an inorganic oxide matrix. The crystalline structure and activity of the SAPO-37 molecular sieve component is preserved by including a stabilizing amount of the organic template compound used in the manufacture of the molecular sieve within the pore structure thereof until such time as the catalyst is thermally activated during use.
    Type: Grant
    Filed: February 12, 1987
    Date of Patent: August 16, 1988
    Assignee: W. R. Grace & Co.
    Inventors: Grant C. Edwards, Jean-Pierre Gilson, Carl V. McDaniel
  • Patent number: 4681864
    Abstract: Catalytic cracking catalyst compositions having a high degree of activity and selectivity for the production of high octane gasoline fractions which comprise stabilized crystalline molecular sieve SAPO-37 dispersed in an inorganic oxide matrix. The crystalline structure and activity of the SAPO-37 molecular sieve component is preserved by including a stabilizing amount of the organic template compound used in the manufacture of the molecular sieve within the pore structure thereof until such time as the catalyst is thermally activated during use.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: July 21, 1987
    Assignee: W. R. Grace & Co.
    Inventors: Grant C. Edwards, Jean-Pierre Gilson, Carl V. McDaniel
  • Patent number: 4340573
    Abstract: Synthetic crystalline alumino-silicate zeolites are prepared by combining reactant quantities of alumina, silica, sodium hydroxide and water with zeolite-forming alumino-silicate seeds having the composition 16 Na.sub.2 O: 2 to 9 Al.sub.2 O.sub.3 : 15 SiO.sub.2 : 500 to 2000 H.sub.2 O. The seed compositions may be used to produce Type A, X and Y crystalline alumino-silicate zeolites.
    Type: Grant
    Filed: January 9, 1980
    Date of Patent: July 20, 1982
    Assignee: W. R. Grace & Co.
    Inventors: David E. W. Vaughan, Grant C. Edwards, Michael G. Barrett
  • Patent number: 4178352
    Abstract: Type Y zeolite is prepared using a minimum excess of reactants by a method wherein required sodium hydroxide, silica, alumina and water reactants are combined in multi-stage procedure to obtain a uniform fluid reaction slurry. The procedure permits the efficient commercial production of high quality type Y zeolite and minimizes the formation of excess silicate containing by-product effluent.
    Type: Grant
    Filed: September 21, 1978
    Date of Patent: December 11, 1979
    Assignee: W. R. Grace & Co.
    Inventors: David E. W. Vaughan, Grant C. Edwards, Michael G. Barrett
  • Patent number: 4175059
    Abstract: A process for preparing a synthetic faujasite having a novel platelet-type crystalline shape and a silica to alumina ratio above 2.2 by adding potassium ions to a seeded faujasite synthesis slurry and heating to convert to the synthetic faujasite. The use of the novel zeolite form as a catalyst promoter and an adjuvant for strengthening formed zeolite such as beads, balls, pills and extrudates is also disclosed.
    Type: Grant
    Filed: August 7, 1978
    Date of Patent: November 20, 1979
    Assignee: W. R. Grace & Co.
    Inventors: Grant C. Edwards, David E. W. Vaughan, Edwin W. Albers
  • Patent number: 4088739
    Abstract: An improved process for preparing synthetic ferrierites having the absorption and catalytic properties characteristic of 5 to 8 angstrom zeolites which comprises promoting an alkaline reaction mixture comprising Group I and/or Group II cations, a source of silica, a source of alumina with lithium cations. The promoted reaction mixture is seeded with natural or synthetic ferrierite seeds, and heated to convert the mass to the synthetic ferrierite.The product has the empirical formula, 0.1 to 0.9 Li.sub.2 O:0.1:0.9 R.sub.2 0:Al.sub.2 O.sub.3 :6 to 25 SiO.sub.2 wherein R.sub.2 O is Na.sub.2 O, K.sub.2 O, or Rb.sub.2 O and/or Cs.sub.2 O; 0.1 to 0.9 Li.sub.2 O:0.1 to 0.9 WO:Al.sub.2 O.sub.3 :6 to 25 SiO.sub.2 wherein WO is BaO, CaO, MgO or SrO; or (Li.sub.2 O:R.sub.2 O:WO):Al.sub.2 O.sub.3 :6-25 SiO.sub.2 where R.sub.2 O is any R.sub.2 O above and WO is any WO above.
    Type: Grant
    Filed: June 25, 1976
    Date of Patent: May 9, 1978
    Assignee: W. R. Grace & Co.
    Inventors: David E. W. Vaughan, Grant C. Edwards
  • Patent number: H191
    Abstract: A catalyst composition containing 5 to 50 weight percent of small particle type Y faujasite zeolite is described. A cracking process using the above catalyst can be used to obtain increased conversion of the heavier portion of commercial crudes as well as to generate increased yield of gasoline and distillate.
    Type: Grant
    Filed: June 5, 1985
    Date of Patent: January 6, 1987
    Assignee: W. R. Grace & Co.
    Inventors: Grant C. Edwards, Kuppuswamy Rajagopalan
  • Patent number: H196
    Abstract: A highly active hydrocarbon conversion catalyst is disclosed which by virtue of it being promoted by larger than conventional particle size zeolite exhibits significantly improved hydrothermal stability.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: January 6, 1987
    Assignee: W. R. Grace & Co.
    Inventors: Grant C. Edwards, Kuppuswamy Rajagopalan
  • Patent number: H222
    Abstract: Hydrocarbon conversion catalysts are prepared from synthetic faujasite Type Y zeolites which have an initial (as synthesized) silica to alumina ratio in excess of 5.6 and preferably above 5.8. The catalysts are highly active for the catalytic cracking of hydrocarbons and are particularly resistant to deactivation by high temperature steam in the presence of metals such as nickel and vanadium.
    Type: Grant
    Filed: March 20, 1986
    Date of Patent: March 3, 1987
    Assignee: W. R. Grace & Co.
    Inventors: Grant C. Edwards, William A. Welsh, Alan W. Peters
  • Patent number: H282
    Abstract: A sodium Y type faujasite having a high silica/alumina ratio is obtained by lowering the active soda content below the conventionally employed levels. This is done by adding an acid and/or an aluminum salt solution such as an aluminum sulfate solution to the sodium silicate in the zeolite synthesis slurry. Alternatively, the desired alumina and silica starting materials can be supplied in part by using an aluminum salt gelled mother liquor such as an alum gelled mother liquor. This permits the use of less reactants which are high in soda such as sodium silicate and sodium aluminate which in turn reduces the amount of soda present. The addition of these soda removers or the use of low soda reactants permits the production of NaY having a silica/alumina ratio of 5.0 and higher. These Y zeolites have a high degree of crystallinity as measured by an NMR sharpness index defined herein and they have an absence of occluded silica. The final product can be ion exchanged to a low level of Na.sub.
    Type: Grant
    Filed: March 11, 1985
    Date of Patent: June 2, 1987
    Assignee: W. R. Grace & Co.
    Inventors: Grant C. Edwards, Robert L. Chiang