Patents by Inventor Grant C. Edwards
Grant C. Edwards has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5102530Abstract: Cracking catalysts which yield higher octane gasoline than conventional cracking catalysts are made with large pore size zeolites such as zeolite Beta and zeolite ZSM-20 in the low sodium, H.sup.+ form. These zeolites are mixed with a matrix which contains at least a binder and formed into catalyst particles. These catalysts are especially suitable to be used in fluid catalytic cracking.Type: GrantFiled: November 13, 1989Date of Patent: April 7, 1992Assignee: W. R. Grace & Co.-Conn.Inventors: Grant C. Edwards, Alan W. Peters
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Patent number: 4898846Abstract: Cracking catalysts which yield higher octane gasoline than conventional cracking catalysts are made with large pore size zeolites such as zeolite Beta and zeolite ZSM-20 in the low sodium, H.sup.+ form. These zeolites are mixed with a matrix which contains at least a binder and formed into catalyst particles. These catalysts are especially suitable to be used in fluid catalytic cracking.Type: GrantFiled: March 21, 1986Date of Patent: February 6, 1990Assignee: W. R. Grace & Co.-Conn.Inventors: Grant C. Edwards, Alan W. Peters
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Patent number: 4764269Abstract: Catalytic cracking catalyst compositions having a high degree of activity and selectivity for the production of high octane gasoline fractions which comprise stabilized crystalline molecular sieve SAPO-37 dispersed in an inorganic oxide matrix. The crystalline structure and activity of the SAPO-37 molecular sieve component is preserved by including a stabilizing amount of the organic template compound used in the manufacture of the molecular sieve within the pore structure thereof until such time as the catalyst is thermally activated during use.Type: GrantFiled: February 12, 1987Date of Patent: August 16, 1988Assignee: W. R. Grace & Co.Inventors: Grant C. Edwards, Jean-Pierre Gilson, Carl V. McDaniel
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Patent number: 4681864Abstract: Catalytic cracking catalyst compositions having a high degree of activity and selectivity for the production of high octane gasoline fractions which comprise stabilized crystalline molecular sieve SAPO-37 dispersed in an inorganic oxide matrix. The crystalline structure and activity of the SAPO-37 molecular sieve component is preserved by including a stabilizing amount of the organic template compound used in the manufacture of the molecular sieve within the pore structure thereof until such time as the catalyst is thermally activated during use.Type: GrantFiled: July 15, 1985Date of Patent: July 21, 1987Assignee: W. R. Grace & Co.Inventors: Grant C. Edwards, Jean-Pierre Gilson, Carl V. McDaniel
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Patent number: 4340573Abstract: Synthetic crystalline alumino-silicate zeolites are prepared by combining reactant quantities of alumina, silica, sodium hydroxide and water with zeolite-forming alumino-silicate seeds having the composition 16 Na.sub.2 O: 2 to 9 Al.sub.2 O.sub.3 : 15 SiO.sub.2 : 500 to 2000 H.sub.2 O. The seed compositions may be used to produce Type A, X and Y crystalline alumino-silicate zeolites.Type: GrantFiled: January 9, 1980Date of Patent: July 20, 1982Assignee: W. R. Grace & Co.Inventors: David E. W. Vaughan, Grant C. Edwards, Michael G. Barrett
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Patent number: 4178352Abstract: Type Y zeolite is prepared using a minimum excess of reactants by a method wherein required sodium hydroxide, silica, alumina and water reactants are combined in multi-stage procedure to obtain a uniform fluid reaction slurry. The procedure permits the efficient commercial production of high quality type Y zeolite and minimizes the formation of excess silicate containing by-product effluent.Type: GrantFiled: September 21, 1978Date of Patent: December 11, 1979Assignee: W. R. Grace & Co.Inventors: David E. W. Vaughan, Grant C. Edwards, Michael G. Barrett
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Patent number: 4175059Abstract: A process for preparing a synthetic faujasite having a novel platelet-type crystalline shape and a silica to alumina ratio above 2.2 by adding potassium ions to a seeded faujasite synthesis slurry and heating to convert to the synthetic faujasite. The use of the novel zeolite form as a catalyst promoter and an adjuvant for strengthening formed zeolite such as beads, balls, pills and extrudates is also disclosed.Type: GrantFiled: August 7, 1978Date of Patent: November 20, 1979Assignee: W. R. Grace & Co.Inventors: Grant C. Edwards, David E. W. Vaughan, Edwin W. Albers
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Patent number: 4088739Abstract: An improved process for preparing synthetic ferrierites having the absorption and catalytic properties characteristic of 5 to 8 angstrom zeolites which comprises promoting an alkaline reaction mixture comprising Group I and/or Group II cations, a source of silica, a source of alumina with lithium cations. The promoted reaction mixture is seeded with natural or synthetic ferrierite seeds, and heated to convert the mass to the synthetic ferrierite.The product has the empirical formula, 0.1 to 0.9 Li.sub.2 O:0.1:0.9 R.sub.2 0:Al.sub.2 O.sub.3 :6 to 25 SiO.sub.2 wherein R.sub.2 O is Na.sub.2 O, K.sub.2 O, or Rb.sub.2 O and/or Cs.sub.2 O; 0.1 to 0.9 Li.sub.2 O:0.1 to 0.9 WO:Al.sub.2 O.sub.3 :6 to 25 SiO.sub.2 wherein WO is BaO, CaO, MgO or SrO; or (Li.sub.2 O:R.sub.2 O:WO):Al.sub.2 O.sub.3 :6-25 SiO.sub.2 where R.sub.2 O is any R.sub.2 O above and WO is any WO above.Type: GrantFiled: June 25, 1976Date of Patent: May 9, 1978Assignee: W. R. Grace & Co.Inventors: David E. W. Vaughan, Grant C. Edwards
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Patent number: H191Abstract: A catalyst composition containing 5 to 50 weight percent of small particle type Y faujasite zeolite is described. A cracking process using the above catalyst can be used to obtain increased conversion of the heavier portion of commercial crudes as well as to generate increased yield of gasoline and distillate.Type: GrantFiled: June 5, 1985Date of Patent: January 6, 1987Assignee: W. R. Grace & Co.Inventors: Grant C. Edwards, Kuppuswamy Rajagopalan
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Patent number: H196Abstract: A highly active hydrocarbon conversion catalyst is disclosed which by virtue of it being promoted by larger than conventional particle size zeolite exhibits significantly improved hydrothermal stability.Type: GrantFiled: July 12, 1985Date of Patent: January 6, 1987Assignee: W. R. Grace & Co.Inventors: Grant C. Edwards, Kuppuswamy Rajagopalan
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Patent number: H222Abstract: Hydrocarbon conversion catalysts are prepared from synthetic faujasite Type Y zeolites which have an initial (as synthesized) silica to alumina ratio in excess of 5.6 and preferably above 5.8. The catalysts are highly active for the catalytic cracking of hydrocarbons and are particularly resistant to deactivation by high temperature steam in the presence of metals such as nickel and vanadium.Type: GrantFiled: March 20, 1986Date of Patent: March 3, 1987Assignee: W. R. Grace & Co.Inventors: Grant C. Edwards, William A. Welsh, Alan W. Peters
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Patent number: H282Abstract: A sodium Y type faujasite having a high silica/alumina ratio is obtained by lowering the active soda content below the conventionally employed levels. This is done by adding an acid and/or an aluminum salt solution such as an aluminum sulfate solution to the sodium silicate in the zeolite synthesis slurry. Alternatively, the desired alumina and silica starting materials can be supplied in part by using an aluminum salt gelled mother liquor such as an alum gelled mother liquor. This permits the use of less reactants which are high in soda such as sodium silicate and sodium aluminate which in turn reduces the amount of soda present. The addition of these soda removers or the use of low soda reactants permits the production of NaY having a silica/alumina ratio of 5.0 and higher. These Y zeolites have a high degree of crystallinity as measured by an NMR sharpness index defined herein and they have an absence of occluded silica. The final product can be ion exchanged to a low level of Na.sub.Type: GrantFiled: March 11, 1985Date of Patent: June 2, 1987Assignee: W. R. Grace & Co.Inventors: Grant C. Edwards, Robert L. Chiang