Abstract: A process for repairing a marine surface is provided that includes the mixing of the part A and the part B until a terminal color change occurs within ±5 minutes of cure. The mixture is applied to a substrate of the marine surface in need of repair to a thickness of up to 6.35 mm. The cured mass has water absorption less than of 0.2% in freshwater or 0.15% in ocean water salinity. A marine repair composition is provided that includes in a part A: an unsaturated vinyl ester resin, a reactive diluent, a cure promoter, a cure inhibitor, a corrosion inhibitor and a filler. The part B includes a free-radical cure initiator stored separately from the part A until mixed with the part A to form the composition.

Abstract: A method for repairing a defect in a vehicle exterior body surface is provided that includes a scan data set being generated that corresponds to the dimensional surface boundaries of the defect. A manufacturing data set is created for an object at least in part complementary to the defect from the scan data. The object is formed from the manufacturing data set with a layered manufacturing device. The object is joined to the defect to repair the vehicle exterior body surface. An object is also provided formed of a thermoplastic or a UV cured polymer with a shape that is at least at least in part complementary to a defect vehicle exterior body surface. The object having a void therein with the shape configured to receive an insert or a fastener therein.

Abstract: A method for repairing small surface imperfections on a vehicle body is provided that includes the application of an uncured layer to a thickness of up to 1.02 mm of a composition inclusive of a polyester resin, an acrylated urethane resin, a defoamer, and a particulate filler to the vehicle body or a cured putty thereon. The uncured layer is then exposed to actinic radiation to induce cure of the uncured layer to form a coating to fill the small surface imperfection on the vehicle body. A one component, UV-cured putty material for repairing small surface imperfections is also provides inclusive of a polyester resin, an acrylated urethane oligomer or polymer, a defoamer, a photoinitiator, and a particulate filler. The composition has an uncured viscosity of between 9,000 and 13,000 centiPoise.

Abstract: A method for repairing surface imperfections on a vehicle body includes the application of an uncured layer to a thickness of up to 0.254 mm of a primer composition comprising: a polyester resin, an acrylated urethane resin, a crosslinking agent, a solvent, and a particulate filler to the vehicle body. The uncured layer is exposed to actinic radiation to induce cure of the uncured layer to form a coating to fill the surface imperfection on the vehicle body. A surface coating primer composition is also provided that includes a polyester resin; an acrylated urethane oligomer or polymer; a crosslinking agent; a solvent; a photoinitiator; and a particulate filler. The uncured composition has a viscosity of between 100 and 800 centipoise.

Abstract: A method of repairing a surface defect with a patch is provided. A fibrous substrate is impregnated with a formulation that includes a polyester resin, a crosslinking agent, a solvent, and a particulate filler. The fibrous substrate is contacted with the surface defect. The formulation is exposed to actinic radiation to induce cure of the formulation to form the patch to repair the surface defect. A kit is also provided that includes a bottle containing the formulation. A sheet of fibrous support material is also provided that is adapted to receive the formulation therethrough. Instructions for repairing a surface defect by the aforementioned method are also provided as part of the kit. 3D printing of an article to fit in the surface defect is also disclosed.

Abstract: A method for repairing a surface imperfection in a clear topcoat overlying a pigmented color coat of a panel includes the application of an amount of a repair composition to the surface imperfection in an amount to fill the surface imperfection. The repair composition is exposed to actinic radiation inducing cure of the repair composition to form a cured fill. A ceramic coating is readily applied after cure to overlie the fill with bonded ceramic particulate. A composition is also provided. An exterior body panel is also provided that includes a substrate having a shape of the panel. A pigmented color coat is present on a surface of the substrate. A clear topcoat overlies the pigmented color coat. A cured composition as detailed above fills surface imperfections in the topcoat.

Abstract: An exterior body panel is provided that includes a substrate having a shape of the panel. A clear topcoat is on the panel. A cured composition of polysilazane moisture cured with interspersed disulfide moieties derived from disulfide monomers overlies the topcoat. A ceramic generating composition kit is also provided. A method for creating a ceramic coating on a topcoat overlying an exterior panel includes combining a first part including a polysilazane and a solvent in which said polysilazane is dissolved, with a second part stored separately from said first part that includes a monomer disulfide to form a reactive gel. The reactive gel cure is applied to the topcoat in ambient air. After allowing sufficient time, moisture cure of the reactive gel occurs and with evaporation of the solvent, the ceramic coating forms with disulfide bonds therein.

Abstract: A free radical cure catalyst composition is provided that includes a free radical cure catalyst present as a paste at 20° C. A cure inhibitor is dissolved in a solvent compatible with the free radical cure catalyst paste to form an inhibitor solution that is mixed into the paste. A filler composition is also provided that includes an ethylenically unsaturated resin, a crosslinking agent; and the free radical cure catalyst composition. A method of repairing a vehicle body is provided that includes an uncured layer of the composition as noted above is applied to a substrate. The uncured layer is modified during a working time of from 8 to 35 minutes. The uncured layer is allowed to cure under free radical conditions to form a cured layer.

Abstract: A method of sealing surface imperfections on a sanded surface of a repair to a vehicle body is provided that includes an uncured layer of a formulation being applied to sanded cured body filler on the vehicle body. The formulation includes a polyester resin, a crosslinking agent, a solvent, and a particulate filler. The uncured layer is exposed to actinic radiation to induce cure of the uncured layer to form a sealing coating. The resulting seal coating has able to seal surface imperfections. A surface imperfection sealing formulation is also provided that includes a polyester resin and a multifunctional crosslinking agent. A solvent is provided. A photoinitiator renders the formulation curable upon exposure to ultraviolet light exposure. A particulate filler is also present in an amount to result in a formulation with an uncured viscosity of between 2600 and 3000 centipoises.

Abstract: A method of repairing a surface defect with a patch is provided. A fibrous substrate is impregnated with a formulation that includes a polyester resin, a crosslinking agent, a solvent, and a particulate filler. The fibrous substrate is contacted with the surface defect. The formulation is exposed to actinic radiation to induce cure of the formulation to form the patch to repair the surface defect. A kit is also provided that includes a bottle containing the formulation. A sheet of fibrous support material is also provided that is adapted to receive the formulation therethrough. Instructions for repairing a surface defect by the aforementioned method are also provided as part of the kit. 3D printing of an article to fit in the surface defect is also disclosed.

Abstract: A composition is provided that includes aliphatic urethane acrylate; a multifunctional crosslinking agent; photoinitiator; a chemical initiator system of a peroxide or azo group containing catalyst, and a cure promoter; and a particulate filler. The composition is amenable to rapid cure to a sandable condition as compared to conventional products. By adjusting the amount of particulate filler present, a product is provided that operates as a primer, a putty, or a filler. A method of vehicle body repair includes the application of an uncured layer of the composition to the vehicle body. The uncured layer is exposed to UV radiation to induce cure of the uncured layer to form a coating in a time of between 2 and 20 minutes even with an ultraviolet wavelength emitting light emitting diode (UV LED).

Abstract: A composition is also provided that includes mercapto modified resin; aliphatic urethane acrylate; a multifunctional crosslinking agent; photoinitiator; and a hindered amine light stabilizer. The composition provides a fast curing coating that utilizes photopolymerization reactions using a variety of light sources such as low energy consuming and environmentally-friendly UV-LED and sunlight. Features of the coating include clarity, hardness, non-yellowing, scratch resistance, and complete surface cure as well as outstanding adhesion to substrates such as plastic, wood, stone and metal.

Abstract: An aqueous coating composition and a coated packaging material prepared by applying the aqueous coating composition to packaging material comprise poly(vinyl alcohol-vinyl primary amine), poly(methyl vinyl ether-maleic anhydride), and a Ca++ microgranulated bentonite clay. The poly(vinyl alcohol-vinyl primary amine) is about 90-98.5 weight percent and the combined weight of poly(methyl vinyl ether-maleic anhydride) and the Ca++ microgranulated bentonite clay is from about 1.5-10 weight percent of the coating formed on the packaging material. The weight ratio of the poly(methyl vinyl ether-maleic anhydride) to the Ca++ microgranulated bentonite clay is from about 20:80 to about 80:20. The poly(methyl vinyl ether-maleic anhydride) is at least 0.8 weight percent of the coating formed on the packaging material and/or has a weight average molecular weight of at least about 1,000,000 Daltons. The applied coating composition is dried at a temperature of up to about 50° C. to form the coated packaging material.