Patents by Inventor Graziano Vignali

Graziano Vignali has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9751902
    Abstract: Described is a production process for the preparation of an organic titanium derivative useful for the preparation of yellow inks for digital printing on ceramics, comprising the following steps: (i) mixing an organic and/or inorganic compound of titanium (IV) and a 1,3-diol of formula: wherein R1, R2, R3 and R4 are independently selected from H and a linear or branched C1-C6 alkyl radical, in the presence of at least an organic solvent immiscible with water and subsequent removal of reaction by-products; (ii) adding water to the reaction mixture in a H2O:Ti?2 molar ratio and subsequent removal of unreacted water and reaction by-products; (iii) maturing the reaction mixture at a temperature of 180-200° C. for 16-50 hours. Also described are the titanium derivative obtainable by means of the above-reported process, an ink that contains the derivative and a method of digital printing on ceramics that uses said ink.
    Type: Grant
    Filed: July 23, 2015
    Date of Patent: September 5, 2017
    Inventor: Graziano Vignali
  • Publication number: 20170015687
    Abstract: Described is a production process for the preparation of an organic titanium derivative useful for the preparation of yellow inks for digital printing on ceramics, comprising the following steps: (i) mixing an organic and/or inorganic compound of titanium (IV) and a 1,3-diol of formula: wherein R1, R2, R3 and R4 are independently selected from H and a linear or branched C1-C6 alkyl radical, in the presence of at least an organic solvent immiscible with water and subsequent removal of reaction by-products; (ii) adding water to the reaction mixture in a H2O:Ti?2 molar ratio and subsequent removal of unreacted water and reaction by-products; (iii) maturing the reaction mixture at a temperature of 180-200° C. for 16-50 hours. Also described are the titanium derivative obtainable by means of the above-reported process, an ink that contains the derivative and a method of digital printing on ceramics that uses said ink.
    Type: Application
    Filed: July 23, 2015
    Publication date: January 19, 2017
    Inventor: Graziano Vignali
  • Patent number: 8603233
    Abstract: The present invention relates to an ink set containing chromophoric metals for digital printing on ceramic materials additive-treated with silica and titanium dioxide, a process for decorating ceramic materials by digital printing using said ink set and decorated ceramic articles obtainable by said process.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: December 10, 2013
    Assignee: Metco S.r.l.
    Inventors: Graziano Vignali, Fabrizio Guizzardi, Elisa Canto, Iuri Bernardi, Michele Giorgi
  • Publication number: 20110207595
    Abstract: The invention relates to a new process for colouring ceramic materials by using aqueous solutions of chromophore ions. In particular, certain types of silica are added to the ceramic mixes which are to be coloured, after which aqueous or organic solutions comprising inorganic salts of Fe(II) and/or Fe (III), or organic derivatives of Fe (II) and/or Fe (III) are applied to the surface of the said additive-containing ceramic mixes.
    Type: Application
    Filed: October 10, 2010
    Publication date: August 25, 2011
    Inventors: Graziano VIGNALI, Fabrizio Guizzardi, Michele Giorgi
  • Publication number: 20100291362
    Abstract: The present invention relates to an ink set containing chromophoric metals for digital printing on ceramic materials additive-treated with silica and titanium dioxide, a process for decorating ceramic materials by digital printing using said ink set and decorated ceramic articles obtainable by said process.
    Type: Application
    Filed: December 18, 2008
    Publication date: November 18, 2010
    Inventors: Graziano Vignali, Fabrizio Guizzardi, Elisa Canto, Luri Bernardi, Michele Giorgi
  • Patent number: 7811508
    Abstract: The invention relates to a new process for coloring ceramic materials by using aqueous solutions of chromophore ions. In particular, certain types of silica are added to the ceramic mixes which are to be colored, after which aqueous or organic solutions comprising inorganic salts of Fe (II) and/or Fe (III), or organic derivatives of Fe (II) and/or Fe (III) are applied to the surface of the said additive-containing ceramic mixes.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: October 12, 2010
    Inventors: Graziano Vignali, Fabrizio Guizzardi, Michele Giorgi
  • Publication number: 20090305065
    Abstract: The present invention relates to new liquid coloring compositions to be applied before firing to obtain, after firing, the white coloration of ceramic manufactured articles, or the decoloration of colored ceramic manufactured articles. The present invention also relates to new processes for coloring or decoloring using said liquid coloring compositions as well as to colored or decolored ceramic objects, obtainable with the new processes.
    Type: Application
    Filed: June 25, 2007
    Publication date: December 10, 2009
    Inventor: Graziano Vignali
  • Publication number: 20070152381
    Abstract: The invention relates to a new process for colouring ceramic materials by using aqueous solutions of chromophore ions. In particular, certain types of silica are added to the ceramic mixes which are to be coloured, after which aqueous or organic solutions comprising inorganic salts of Fe (II) and/or Fe (III), or organic derivatives of Fe (II) and/or Fe (III) are applied to the surface of the said additive-containing ceramic mixes.
    Type: Application
    Filed: December 22, 2004
    Publication date: July 5, 2007
    Inventors: Graziano Vignali, Fabrizio Guizzardi, Michele Giorgi
  • Publication number: 20030164582
    Abstract: Process for colouring with pink/orange shades on surface and to a variable depth manufactured items obtained from a ceramic mass added with zinc oxide in an amount of 5% to 20% by weight, or with zinc silicate, said process uses a composition being in form of an aqueous or hydroalcoholic solution comprising Cr organic derivatives or inorganic salts alone or in combination with Fe organic derivatives or inorganic salts and/or Zn organic derivatives or inorganic salts, which is applied by controlled absorption onto the surface of the ceramic body before its firing in an oven according to a standard ceramic cycle.
    Type: Application
    Filed: January 22, 2003
    Publication date: September 4, 2003
    Inventors: Graziano Vignali, Frabrizio Guizzardi
  • Patent number: 6607816
    Abstract: Composition whereby ceramic manufactured articles are colored in shades from pink to violet, such composition includes of a monovalent gold thiolate water solution or mixture of water with a water soluble organic solvent according to the following formulas Au—S—R—X and Au—S—R—H, where R stands for a linear or branched bivalent radical of aliphatic or aromatic or cycloaliphatic or heterocyclic type optionally with substituents, such as for example aminic, amidic, hydroxylic, carboxylic, hydrocarbylic or carbonylic groups or CONH—, in the chain; X stands for a monovalent group selected out of —COOH, SO2OH, —OH, —CONH2, —NH2; O—P(O)(OH)2, in which H atoms may be replaced by alkyl groups and wherein acid group may be salified with amines or alkaline or alkaline earth metals and basic groups may optionally be salified with organic acids
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: August 19, 2003
    Inventors: Graziano Vignali, Fabrizio Guizzardi
  • Patent number: 6286278
    Abstract: Composition whereby ceramic manufactured articles, obtained by molding pressing a ceramic mixture added with 1% to 10% TiO2 by wt., are colored in shades from yellow ocher to sienna, said composition being an aqueous or hydroalcoholic solution including tungsten and chromium inorganic compounds or organic derivatives, which is applied by controlled absorption to the surface of the ceramic material before firing.
    Type: Grant
    Filed: June 21, 2000
    Date of Patent: September 11, 2001
    Inventor: Graziano Vignali
  • Patent number: 6271157
    Abstract: Composition whereby ceramic manufactured articles, obtained by moulding a conventional ceramic mixture without added TiO2., are colored from yellow to orange, said composition consisting of an aqueous solution of inorganic compounds or organic complexes of titanium and chromium combined with antimony or tungsten or mixtures thereof, in quantities corresponding to 2 to 6% by wt. Ti, 3 to 12% Sb (or 4 to 14% tungsten) and 0.2 to 2.5% chromium.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: August 7, 2001
    Inventors: Graziano Vignali, Fabrizio Guizzardi
  • Patent number: 6132672
    Abstract: Composition for coloring ceramic articles obtained from ceramic mass containing TiO.sub.2 as such, in shades ranging from yellow to orange, consisting of an aqueous or hydroalcoholic solution to be applied to the surface to colored before final firing and containing soluble compounds of chromium/antimony or of chromium/zinc or chromium/zirconium or chromium/manganese mixtures.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: October 17, 2000
    Inventor: Graziano Vignali
  • Patent number: 6099633
    Abstract: Composition whereby ceramic manufactured articles, obtained by molding pressing a ceramic mixture added with 1% to 10% TiO.sub.2 by wt., are colored in shades from yellow ocher to sienna, said composition being an aqueous or hydroalcoholic solution including tungsten and chromium inorganic compounds or organic derivatives, which is applied by controlled absorption to the surface of the ceramic material before firing.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: August 8, 2000
    Inventor: Graziano Vignali
  • Patent number: 5696261
    Abstract: Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilisers, heat stabilisers and oxidation stabilisers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: December 9, 1997
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Valerio Borzatta, Graziano Vignali, Fabrizio Guizzardi
  • Patent number: 5679794
    Abstract: Compounds possessing both a hindered amine moiety, such as a derivative of 2,2,6,6-tetramethylpiperidine, and a hydroxylamine moiety where the N-hydroxy group is not attached to a nitrogen atom in a piperidine ring are valuable stabilizers for protecting polymer compositions against the deleterious effects of actinic light and from the adverse effects of high temperature polymer processing environments.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 21, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Suhadolnik, Ramanathan Ravichandran, Valerio Borzatta, Graziano Vignali
  • Patent number: 5668198
    Abstract: Compounds possessing both a hindered amine moiety, such as a derivative of 2,2,6,6-tetramethylpiperidine, and a hydroxylamine moiety where the N-hydroxy group is not attached to a nitrogen atom in a piperidine ring are valuable stabilizers for protecting polymer compositions against the deleterious effects of actinic light and from the adverse effects of high temperature polymer processing environments.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 16, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Suhadolnik, Ramanathan Ravichandran, Valerio Borzatta, Graziano Vignali
  • Patent number: 5668199
    Abstract: Compounds possessing both a hindered amine moiety, such as a derivative of 2,2,6,6-tetramethylpiperidine, and a hydroxylamine moiety where the N-hydroxy group is not attached to a nitrogen atom in a piperidine ring are valuable stabilizers for protecting polymer compositions against the deleterious effects of actinic light and from the adverse effects of high temperature polymer processing environments.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 16, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Suhadolnik, Ramanathan Ravichandran, Valerio Borzatta, Graziano Vignali
  • Patent number: 5652364
    Abstract: Novel process for the preparation of 2,2,6,6-tetramethyl-4-piperidyloxy-1,3,5-triazines, based on the reaction of cyanuric chloride with C.sub.1 -C.sub.4 alkanols or with sodium or potassium C.sub.1 -C.sub.4 alkoxides and subsequent reaction with 2,2,6,6-tetramethyl-4-piperidinols in the presence of a transesterification catalyst.The various reactions can be carried out in the same reactor, without isolation of the intermediates.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: July 29, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Graziano Vignali, Fabrizio Guizzardi, Graziano Zagnoni, Roberto Scrima
  • Patent number: 5552464
    Abstract: Compounds possessing both a hindered amine moiety, such as a derivative of 2,2,6,6-tetramethylpiperidine, and a hydroxylamine moiety where the N-hydroxy group is not attached to a nitrogen atom in a piperidine ring are valuable stabilizers for protecting polymer compositions against the deleterious effects of actinic light and from the adverse effects of high temperature polymer processing environments.
    Type: Grant
    Filed: January 12, 1995
    Date of Patent: September 3, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Suhadolnik, Ramanathan Ravichandran, Valerio Borzatta, Graziano Vignali