Abstract: An optical construction includes optical stacks arranged across the construction and spaced apart from each other. Each of the optical stacks has a transmittance of at least 60% for at least one visible wavelength and includes one or more electrically conductive layers. The optical stacks are co-extensive with first and second antennas. Each of the electrically conductive layers defines a through opening aligned with at least one of the first and second antennas. For each of an s-polarized first incident signal incident on the optical construction in a first incident plane and a p-polarized second incident signal incident on the optical construction in a second incident plane orthogonal to the first incident plane, for at least one frequency in a range from 0.5 GHz to 10 GHz, and for incident angles of up to 40 degrees, the optical construction has a transmission coefficient of between 0 dB and ?10 dB.

Abstract: A cation exchange membrane comprising a supported membrane having first and second opposed major surfaces, wherein the membrane comprises ionomer, and wherein at least one of: the membrane is supported on the first major surface, but unsupported on the second major surface; the cation exchange membrane has a porosity, wherein at least 90 (in some embodiments, at least 95, 96, 97, 98, or even at least 99) percent by volume of the porosity is filled with ionomer, and wherein at least one of the first or second major surfaces of the cation exchange membrane is free of a continuous ionomer layer thereon external to the electrolyte diffusion layer; or the ionomer has a cohesive strength, wherein the ionomer has a maximum annealing temperature that maximizes the cohesive strength of the ionomer, wherein the membrane is supported by at least one support layer, and wherein the support layer has a melting temperature that is less than the maximum annealing temperature of the ionomer.

Abstract: Membrane electrode assembly comprising oxygen evolution reaction catalyst disposed in gas distribution layer (100, 700) or between gas distribution layer (100, 700 and gas dispersion layer (200, 600). Membrane electrode assemblies described herein are useful, for example, in electrochemical devices such as a fuel cell.

Abstract: The method includes providing a component of an assembly having an interior portion and a peripheral portion and adhering separate strips of an adhesive tape to the peripheral portion of the component to surround the interior portion. The short side of a first strip is positioned adjacent a second strip. The adhesive tape includes an adhesive disposed on a backing, and the adhesive includes an amorphous fluoropolymer. The method further includes applying at least one of heat or pressure to the separate strips such that the adhesive flows seals any gap between the first and second strips and crosslinks. The method can be useful, for example, when the assembly is an electrochemical cell assembly and when the component includes at least one of an electrolyte membrane or a current collector.

Abstract: The present disclosure relates membrane-electrode assemblies and electrochemical cells and liquid flow batteries produced therefrom. The membrane-electrode assemblies include a first porous electrode; an ion permeable membrane, having a first major surface and an opposed second major surface; a first discontinuous transport protection layer disposed between the first porous electrode and the first major surface of the ion permeable membrane; and a first adhesive layer in contact with the first porous electrode and at least one of the first discontinuous transport protection layer and the ion permeable membrane. The first adhesive layer is disposed along the perimeter of the membrane-electrode assembly.

Abstract: The present disclosure relates to electrode assemblies, membrane-electrode assemblies and electrochemical cells and liquid flow batteries produced therefrom. The electrode and membrane-electrode assemblies include (i) a porous electrode having a first major surface with a first surface area, Ae, an opposed second major surface and a plurality of voids; (ii) a discontinuous transport protection layer, comprising polymer, disposed on the first major surface and having a cross-sectional area, Ap, substantially parallel to the first major surface; and (iii) an interfacial region wherein the interfacial region includes a portion of the polymer embedded in at least a portion of the plurality of voids, a portion of the porous electrode embedded in a portion of the polymer or a combination thereof; and wherein 0.02Ae?Ap?0.85Ae and the porous electrode and discontinuous transport protection layer form an integral structure.

Abstract: The present disclosure relates to porous electrodes and electrochemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making electrodes. The porous electrodes include polymer, e.g. non-electrically conductive polymer particulate fiber, and an electrically conductive carbon particulate. The non-electrically conductive, polymer particulate fibers may be in the form of a first porous substrate, wherein the first porous substrate is at least one of a woven or nonwoven paper, felt, mat and cloth. The porous electrode may have an electrical resistivity of less than about 100000 ?Ohm·m. The porous electrode may have a thickness from about 10 microns to about 1000 microns. Electrochemical cells and liquid flow batteries may be produced from the porous electrodes of the present disclosure.

Abstract: The present disclosure relates to porous electrodes, membrane-electrode assemblies, electrode assemblies and electrochemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making porous electrodes, membrane-electrode assemblies and electrode assemblies. The porous electrodes include a porous electrode material comprising a polymer and an electrically conductive carbon particulate; and a solid film substrate having a first major surface and a second major surface, wherein the solid film substrate includes a plurality of through holes extending from the first major surface to the second major surface. The porous electrode material is disposed on at least the first major surface and within the plurality of through holes of the solid film substrate. The plurality of through holes with the porous electrode material provide electrical communication between the first major surface and the opposed second major surface of the porous electrode.

Abstract: The present disclosure relates to membrane assemblies, electrode assemblies and membrane-electrode assemblies; and electrochemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making the membrane assemblies, electrode assemblies and membrane-electrode assemblies. The membrane assemblies includes an ion exchange membrane and at least one microporous protection layer. The electrode assemblies includes a porous electrode and a microporous protection layer. The membrane-electrode assembly includes an ion exchange membrane, at least one microporous protection layer and at least one porous electrode. The microporous protection layer includes a resin and at least one of an electrically conductive particulate and a non-electrically conductive particulate. The ratio of the weight of the resin to total weight of particulate is from about 1/99 to about 10/1. The resin may be at least one of an ionic resin and a non-ionic resin.

Abstract: The present disclosure relates to porous electrodes, membrane-electrode assemblies, electrode assemblies and electro-chemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making porous electrodes, membrane-electrode assemblies and electrode assemblies. The porous electrodes include a porous electrode material comprising a non-electrically conductive, polymer particulate; and an electrically conductive carbon particulate; wherein the electrically conductive carbon particulate is at least one of carbon nanotubes and branched carbon nanotubes. The electrically conductive carbon particulate is adhered directly to the surface of the non-electrically conductive, polymer particulate and at least a portion of the non-electrically conductive polymer particulate surface is fused to form a unitary, porous electrode material.

Abstract: The present disclosure relates to porous electrodes, membrane-electrode assemblies, electrode assemblies and electrochemical cells and liquid flow batteries produced therefrom. The disclosure further provides methods of making electrodes, membrane-electrode assemblies and electrode assemblies. The porous electrodes include polymer, e.g. non-electrically conductive polymer particulate fiber, and an electrically conductive carbon particulate. The non-electrically conductive, polymer particulate fibers may be in the form of a first porous substrate, wherein the first porous substrate is at least one of a woven or nonwoven paper, felt, mat and cloth. Membrane-electrode assemblies and electrode assemblies may be produced from the porous electrodes of the present disclosure. Electrochemical cells and liquid flow batteries may be produced from the porous electrodes, membrane-electrode assemblies and electrode assemblies of the present disclosure.

Abstract: Described herein is a polymeric electrolyte membrane for a redox flow battery comprising (i) a polymer, (ii) a plurality of pendent groups comprising a sulfonic acid, and (iii) a plurality of pendent groups comprising a sulfonamide.

Abstract: Membrane electrode assembly comprising oxygen evolution reaction catalyst disposed in gas distribution layer (100, 700) or between gas distribution layer (100, 700 and gas dispersion layer (200, 600). Membrane electrode assemblies described herein are useful, for example, in electrochemical devices such as a fuel cell.

Abstract: A fuel cell electrode layer may include a catalyst, an electronic conductor, and an ionic conductor. Within the electrode layer are a plurality of electronic conductor rich networks and a plurality of ionic conductor rich networks that are interspersed with the electronic conductor rich networks. A volume ratio of the ionic conductor to the electronic conductor is greater in the ionic conductor rich networks than in the electronic conductor rich networks. During operation of a fuel cell that includes the electrode layer, conduction of electrons occurs predominantly within the electronic conductor rich networks and conduction of ions occurs predominantly within the ionic conductor rich networks.

Abstract: A fuel cell electrode layer may include a catalyst, an electronic conductor, and an ionic conductor. Within the electrode layer are a plurality of electronic conductor rich networks and a plurality of ionic conductor rich networks that are interspersed with the electronic conductor rich networks. A volume ratio of the ionic conductor to the electronic conductor is greater in the ionic conductor rich networks than in the electronic conductor rich networks. During operation of a fuel cell that includes the electrode layer, conduction of electrons occurs predominantly within the electronic conductor rich networks and conduction of ions occurs predominantly within the ionic conductor rich networks.

Abstract: Polymer electrolyte membrane (PEM) fuel cell membrane electrode assemblies (MEA's) are provided which have nanostructured thin film (NSTF) catalyst electrodes and additionally a sublayer of dispersed catalyst situated between the NSTF catalyst and the PEM of the MEA.

Abstract: Fuel cell anodes comprising (a) a catalyst comprising Pt, (b) an oxygen evolution reaction catalyst, and (c) at least one of Au, a refractory metal (e.g., at least one of Hf, Nb, Os, Re, Rh, Ta, Ti, W, or Zr), a refractory metal oxide, a refractory metal boride, a refractory metal carbide, a refractory metal nitride, or a refractory metal silicide. The fuel cell anodes are useful in fuel cells.

Abstract: In one aspect, the present disclosure describes a first article comprising nanostructured whiskers having a first layer thereon comprising an organometallic compound comprising at least one of Ru or Ir. Optionally, the first layer further comprises an complex comprising at least one of Ru or Ir. Typically, the article includes at least one or more additional layers (e.g., a second layer comprising at least one of metallic Ir, Ir oxide, or Ir hydrated oxide on the first layer). Articles described herein are useful, for example, in fuel cell catalysts (i.e., an anode or cathode catalyst).

Abstract: Fuel cell membrane electrode assemblies and fuel cell polymer electrolyte membranes are provided comprising bound anionic functional groups and polyvalent cations, such as Mn or Ru cations, which demonstrate increased durability. Methods of making same are also provided.

Abstract: A fuel cell electrode layer may include a catalyst, an electronic conductor, and an ionic conductor. Within the electrode layer are a plurality of electronic conductor rich networks and a plurality of ionic conductor rich networks that are interspersed with the electronic conductor rich networks. A volume ratio of the ionic conductor to the electronic conductor is greater in the ionic conductor rich networks than in the electronic conductor rich networks. During operation of a fuel cell that includes the electrode layer, conduction of electrons occurs predominantly within the electronic conductor rich networks and conduction of ions occurs predominantly within the ionic conductor rich networks.