Patents by Inventor Gregory Schmidt
Gregory Schmidt has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20190379088Abstract: A method for drying and purifying a lithium bis(fluorosulfonyl)imide salt. Also, a method for producing a lithium bis(fluorosulfonyl)imide salt which is then dried and purified by the method. Further, a composition containing lithium bis(fluorosulfonyl)imide salt having a water content by mass of between 5 and 45 ppm. And, the use of the composition C in Li-ion batteries.Type: ApplicationFiled: December 7, 2017Publication date: December 12, 2019Applicant: Arkema FranceInventors: Grégory Schmidt, Rémy Teissier
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Patent number: 10466651Abstract: Watch glass (1) including a first element (2) made of a first material and a second element (3) made of a second material different from the first, more elastic than the first material, the second element (3) includes a skirt (3b) in its lower part, and the two elements (2, 3) are fixed to each other so that the first element (2) is oriented toward the exterior of a watch and the skirt of the second element (3) is adapted for the assembly of the watch glass (1) to a watch middle (4).Type: GrantFiled: September 7, 2017Date of Patent: November 5, 2019Assignee: MONTRES TUDOR SAInventors: Gregory Schmidt, Frank Vernay
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Publication number: 20190312309Abstract: An electrolytic composition including at least one lithium salt of formula (A) wherein Rf represents a fluorine atom, a nitrile group, an optionally fluorinated or perfluorinated alkyl group having from 1 to 5 carbons, an optionally fluorinated or perfluorinated alkoxy group having from 1 to 5 carbons or an optionally fluorinated or perfluorinated oxa-alkoxy group having from 1 to 5 carbons; and the following solvent mixture: ethylene carbonate, ?-butyrolactone, and methyl propanoate. Also, to the use of the compositions in Li-ion batteries.Type: ApplicationFiled: November 30, 2017Publication date: October 10, 2019Applicants: Arkema France, Universite de ToursInventors: Grégory Schmidt, Mérièm Anouti, Daniel Lemordant, Laure Timperman, Christopher Berhaut
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Publication number: 20190292053Abstract: The present invention relates to a method for drying and purifying a lithium bis(fluorosulfonyl)imide salt in solution in an organic solvent S1, said method comprising the following steps: a) adding deionised water to dissolve and extract the lithium bis(fluorosulfonyl)imide salt, forming an aqueous solution of said salt; b) extracting the lithium bis(fluorosulfonyl)imide salt from said aqueous solution, using an organic solvent S2, said step being repeated at least once; c) concentrating the lithium bis(fluorosulfonyl)imide salt by evaporating said organic solvent S2 and the water, in a short-path thin-film evaporator, under the following conditions: temperature of 30° C. to 95° C., pressure of 10?3 mbar abs to 5 mbar abs, residence time no longer than 15 min; and d) optionally crystallising the lithium bis(fluorosulfonyl)imide salt. The present invention likewise relates to a composition made of lithium bis(fluorosulfonyl)imide salt, and the uses thereof in Li-ion batteries.Type: ApplicationFiled: December 7, 2017Publication date: September 26, 2019Applicant: Arkema FranceInventors: Grégory Schmidt, Rémy Teissier
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Patent number: 10388988Abstract: Salts of bicyclic imidazole compounds (IV) having general structural formulae in which A represents a monovalent cation, X represents independently a carbon atom, an oxygen atom, a sulphur atom or a nitrogen atom. Also, an associated production method and a use thereof, in particular as an electrolyte component for batteries.Type: GrantFiled: April 25, 2013Date of Patent: August 20, 2019Assignee: ARKEMA FRANCEInventor: Grégory Schmidt
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Patent number: 10351493Abstract: The present invention relates to a method for preparing a polyinsaturated perfluorinated compound B from a polyinsaturated perhalogenated compound D having the formula CnX2(n?m+1), in which X is independently selected from one of the halogens, F, Cl, Br or I, provided at least one X is not fluorine; n is the number of carbon atoms and is at least higher than or equal to 4, m is the number of double carbon-carbon bonds and is higher than or equal to 2, wherein the method comprises a step in which compound D is fluorinated in the presence of a fluorinating agent of general formula AFp, in which A is hydrogen, an alkali metal or an alkaline earth metal, and p is 1 or 2, and in the presence of an aprotic organic polar solvent; the method being carried out with a molar ratio of AFp to compound D of less than 1.45*2(n?m+1).Type: GrantFiled: March 20, 2017Date of Patent: July 16, 2019Assignee: ARKEMA FRANCEInventors: Grégory Schmidt, Rémy Teissier
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Patent number: 10336669Abstract: The present invention relates to a method for preparing hexafluorobutadiene comprising the following steps: (a) hydrodechlorinating hexachlorobutadiene to form a first stream comprising 1,2,3,4-tetrachlorobutadiene and optionally unreacted hexachlorobutadiene; (b) fluorinating the first stream comprising 1,2,3,4-tetrachlorobutadiene obtained in step (a) to form a second stream comprising 1,1,2,3,4,4-hexafluorobutane, (c) dehydrogenating the second stream comprising 1,1,2,3,4,4-hexafluorobutane to form a third stream comprising hexafluorobutadiene.Type: GrantFiled: March 20, 2017Date of Patent: July 2, 2019Assignee: ARKEMA FRANCEInventors: Grégory Schmidt, Rémy Teissier
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Publication number: 20190157721Abstract: A lithium bis(fluorosulfonyl)imide salt, wherein, after dissolving in water to form an aqueous solution, the aqueous solution has a pH of between 4 and 8, in particular at a temperature of 25° C., and the uses thereof in Li-ion batteries. Also, a lithium bis(fluorosulfonyl)imide salt, including a content of H+ ions of between 0.08 ppb and 0.80 ppm, between 0.08 ppb and 0.63 ppm or between 0.25 ppb and 2.53 ppb.Type: ApplicationFiled: January 22, 2019Publication date: May 23, 2019Applicant: Arkema FranceInventors: Grégory Schmidt, Rémy Teissier, Philippe Bonnet
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Publication number: 20190112244Abstract: The present invention relates to a method for preparing hexafluorobutadiene comprising the following steps: (a) hydrodechlorinating hexachlorobutadiene to form a first stream comprising 1,2,3,4-tetrachlorobutadiene and optionally unreacted hexachlorobutadiene; (b) fluorinating the first stream comprising 1,2,3,4-tetrachlorobutadiene obtained in step (a) to form a second stream comprising 1,1,2,3,4,4-hexafluorobutane, (c) dehydrogenating the second stream comprising 1,1,2,3,4,4-hexafluorobutane to form a third stream comprising hexafluorobutadiene.Type: ApplicationFiled: March 20, 2017Publication date: April 18, 2019Applicant: Arkema FranceInventors: Grégory Schmidt, Rémy Teissier
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Publication number: 20190112243Abstract: The present invention relates to a method for preparing a polyinsaturated perfluorinated compound B from a polyinsaturated perhalogenated compound D having the formula CnX2(n?m+1), in which X is independently selected from one of the halogens, F, Cl, Br or I, provided at least one X is not fluorine; n is the number of carbon atoms and is at least higher than or equal to 4, m is the number of double carbon-carbon bonds and is higher than or equal to 2, wherein the method comprises a step in which compound D is fluorinated in the presence of a fluorinating agent of general formula AFp, in which A is hydrogen, an alkali metal or an alkaline earth metal, and p is 1 or 2, and in the presence of an aprotic organic polar solvent; the method being carried out with a molar ratio of AFp to compound D of less than 1.45*2(n?m+1).Type: ApplicationFiled: March 20, 2017Publication date: April 18, 2019Applicant: Arkema FranceInventors: Grégory Schmidt, Rémy Teissier
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Publication number: 20180366764Abstract: A process for preparing a fluoro compound of formula: R2—(SO2)—NX—(SO2)—F (III) including: (a) a first step for obtaining the chloro compound of formula: R1—(SO2)—NX—(SO2)—Cl; (II) this first step including the reaction of the sulfamide of formula: R0—(SO2)—NH2 (I) with a sulfurous acid and a chlorinating agent; and (b) a second step for obtaining the fluoro compound of formula (III), this second step including the reaction of the chloro compound of formula (II) with anhydrous hydrofluoric acid in at least one organic solvent; in which: X represents either a hydrogen atom or a monovalent cation M; R1 represents an electron-withdrawing group having a positive Hammett parameter ?p; if R1 represents Cl, then R0 represents OH; otherwise, R0 is identical to R1; and if R1 represents Cl, then R2 represents F; otherwise, R2 is identical to R1.Type: ApplicationFiled: August 24, 2018Publication date: December 20, 2018Applicant: ARKEMA FRANCEInventors: Gregory SCHMIDT, Sophie AUDUREAU
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Patent number: 10128525Abstract: A process for preparing a fluoro compound of formula: R2—(SO2)—NX—(SO2)—F (III) including: (a) a first step for obtaining the chloro compound of formula: R1—(SO2)—NX—(SO2)—Cl; (II) this first step including the reaction of the sulfamide of formula: R0—(SO2)—NH2 (I) with a sulfureous acid and a chlorinating agent; and (b) a second step for obtaining the fluoro compound of formula (III), this second step including the reaction of the chloro compound of formula (II) with anhydrous hydrofluoric acid in at least one organic solvent; in which: X represents either a hydrogen atom or a monovalent cation M; R1 represents an electron-withdrawing group having a positive Hammett parameter ?p; if R1 represents Cl, then R0 represents OH; otherwise, R0 is identical to R1; and if R1 represents Cl, then R2 represents F; otherwise, R2 is identical to R1.Type: GrantFiled: April 1, 2015Date of Patent: November 13, 2018Assignee: ARKEMA FRANCEInventors: Gregory Schmidt, Sophie Audureau
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Patent number: 10033068Abstract: A composition including: (i) a lithium salt of imidazole compound of formula (I): wherein Rf is a fluorinated alkyl group having 1 to 5 carbon atoms, or a fluorine atom; and (ii) at least one cation selected from the group A including sodium, potassium, calcium, iron, magnesium, manganese, strontium, vanadium, ammonium, silver, aluminium, arsenic, barium, silicon, cadmium, cobalt, chromium, copper, nickel, lead, antimony, selenium, tin, strontium and titanium; and (iii) at least one anion chosen from the group B including fluoride, chloride, nitrate, sulphate, phosphate, trifluoroacetate, pentafluoroacetate and the anion of formula (II), with all the cation(s) and anion(s) being more than 0 wt % and at most 1 wt % of the composition. Also, the preparation of the composition as well as to the use of the composition as a battery electrolyte.Type: GrantFiled: September 22, 2014Date of Patent: July 24, 2018Assignee: ARKEMA FRANCEInventors: Grégory Schmidt, Bruno Van Hemelryck
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Publication number: 20180076444Abstract: The invention relates to the field of storing electrical energy in secondary lithium batteries of the Li-ion type. More precisely, the invention relates to an electrode material for a Li-ion battery, to the method for the production thereof, and to the use of same in a Li-ion battery. The invention also relates to Li-ion batteries produced using said electrode material.Type: ApplicationFiled: March 3, 2016Publication date: March 15, 2018Inventors: Jérôme CHAUVEAU, Grégory SCHMIDT, Stéphane BIZET
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Publication number: 20180074460Abstract: Watch glass (1) including a first element (2) made of a first material and a second element (3) made of a second material different from the first, more elastic than the first material, the second element (3) includes a skirt (3b) in its lower part, and the two elements (2, 3) are fixed to each other so that the first element (2) is oriented toward the exterior of a watch and the skirt of the second element (3) is adapted for the assembly of the watch glass (1) to a watch middle (4).Type: ApplicationFiled: September 7, 2017Publication date: March 15, 2018Applicant: MONTRES TUDOR SAInventors: Gregory Schmidt, Frank Vernay
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Publication number: 20180034106Abstract: The invention concerns an electrolyte composition, comprising: —a lithium bis(fluorosulfonyl)imide salt and/or a lithium 4,5-dicyano-(trifluoromethyl) imidazolate salt; and —a solvent of formula (I): in which: —n is an integer of between 0 and 15, —R1, R2 and R3 represent, independently, a halogen atom or a C1 to C6 linear or branched alkyl group, —X represents either a covalent bond or a C1 to C6 linear or branched alkylene alkenylene or alkynylene group, —Y represents either an —(OCh2Ch2)m- group, or an —(N(CH3)CH2CH2)m- group, m being an integer of between 0 and 15, provided that m is different from 0 when X represents a covalent bond, and —R4 represents a cyano, cyanate, isocyanate, thiocyanate or isothiocyanate group.Type: ApplicationFiled: March 14, 2016Publication date: February 1, 2018Applicant: ARKEMA FRANCEInventor: Grégory SCHMIDT
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Patent number: 9725318Abstract: A fluorination process for obtaining fluorinated compounds including at least one fluorosulfonyl group. More particularly, a process for preparing a fluorinated compound of formula (II), including at least one step of reacting a compound of formula (I) with anhydrous hydrofluoric acid in at least one organic solvent, in which R1 is equal to R2 except in the specific case where R1?Cl, then R2?F, and when R1 is equal to R2, R1 and R2 represent an electron-withdrawing group which has a Hammett parameter ?p of greater than 0, such as F, CF3, CHF2, CH2F, C2HF4, C2H2F3, C2H3F2, C2F5, C3F7, C3H2F5, C3H4F3, C3HF6, C4F9, C4H2F7, C4H4F5, C5F11, C3F5OCF3, C2F4OCF3, C2H2F2OCF3, CF2OCF3, C6F13, C7F15, C8F17 or C9F19, and M represents a hydrogen atom, an alkali metal, an alkaline-earth metal or a quaternary ammonium cation.Type: GrantFiled: November 19, 2013Date of Patent: August 8, 2017Assignee: ARKEMA FRANCEInventors: Sophie Audureau, Grégory Schmidt
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Publication number: 20170200977Abstract: The present invention relates to a lithium-sulphur cell comprising an anode comprising lithium metal or lithium metal alloy;a cathode comprising a mixture of electroactive sulphur material and solid electroconductive material; and a liquid electrolyte comprising at least one lithium salt and a solvent comprising a dinitrile.Type: ApplicationFiled: May 21, 2015Publication date: July 13, 2017Inventors: Sebastian Desilani, Ashley Cooke, Gregory Schmidt
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Publication number: 20170047607Abstract: The invention relates to a process for preparing a fluoro compound of formula: R2—(SO2)—NX—(SO2)—F ??(III) comprising: (a) a first step for obtaining the chloro compound of formula: R1—(SO2)—NX—(SO2)—Cl; ??(II) this first step comprising the reaction of the sulfamide of formula: R0—(SO2)—NH2 ??(I) with a sulfureous acid and a chlorinating agent; and (b) a second step for obtaining the fluoro compound of formula (III), this second step comprising the reaction of the chloro compound of formula (II) with anhydrous hydrofluoric acid in at least one organic solvent; in which: X represents either a hydrogen atom or a monovalent cation M; R1 represents an electron-withdrawing group having a positive Hammett parameter ?p; if R1 represents Cl, then R0 represents OH; otherwise, R0 is identical to R1; and if R1 represents Cl, then R2 represents F; otherwise, R2 is identical to R1.Type: ApplicationFiled: April 1, 2015Publication date: February 16, 2017Applicant: ARKEMA FRANCEInventors: Gregory SCHMIDT, Sophie AUDUREAU
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Publication number: 20170040640Abstract: A composition including: (i) a lithium salt of imidazole compound of formula (I): wherein Rf is a fluorinated alkyl group having 1 to 5 carbon atoms, or a fluorine atom; and (ii) at least one cation selected from the group A including sodium, potassium, calcium, iron, magnesium, manganese, strontium, vanadium, ammonium, silver, aluminium, arsenic, barium, silicon, cadmium, cobalt, chromium, copper, nickel, lead, antimony, selenium, tin, strontium and titanium; and (iii) at least one anion chosen from the group B including fluoride, chloride, nitrate, sulphate, phosphate, trifluoroacetate, pentafluoroacetate and the anion of formula (II), with all the cation(s) and anion(s) being more than 0 wt % and at most 1 wt % of the composition. Also, the preparation of the composition as well as to the use of the composition as a battery electrolyte.Type: ApplicationFiled: September 22, 2014Publication date: February 9, 2017Applicant: ARKEMA FRANCEInventors: Grégory SCHMIDT, Bruno VAN HEMELRYCK