Abstract: Described are conjugated polymer fibers and nanofibers, methods of making, and methods of use thereof. The conjugated polymer fibers and nanofibers can be prepared by an electrostatic spinning process followed by crosslinking.

Abstract: Disclosed herein are precursor polymers containing units of heteroaryls and units of Si, Sn, Ge, or Pb, methods of producing the precursor polymers, and applications utilizing these precursor polymers to prepare conductive polymers.

Abstract: Described are conjugated polymer fibers and nanofibers, methods of making, and methods of use thereof. The conjugated polymer fibers and nanofibers can be prepared by an electrostatic spinning process followed by crosslinking.

Abstract: Inexpensive and facile methods of preparing fused heterocycles such as thieno[3,4-b]thiophene, thieno[3,4-b]furan, related compounds, and their derivatives are disclosed. Also disclosed are regioregular polymers prepared from the fused heterocycles.

Abstract: An electrochromic fiber or fabric is disclosed. The fiber or fabric includes a flexible, electrically conductive fiber, and a layer comprising an electrochromic material disposed on and surrounding the flexible, electrically conductive fiber. In one embodiment, the fiber or fabric is both flexible and elastic. The fibers and fabrics are of particular utility in electrochromic devices, particularly those which form or are a part of garments.

Abstract: An electrochromic fiber or fabric is disclosed. The fiber or fabric includes a flexible, electrically conductive fiber, wherein the fiber comprises a non-electrically conductive organic polymer coated with an electrically conductive polymer; and; a layer comprising an electrochromic material disposed on and surrounding the flexible, electrically conductive fiber; wherein the electrically conductive polymer is PEDOT-PSS, poly(vinylpyridine), a poly(thiophene), a poly(pyrrole), a poly(aniline), a poly(acetylene), a poly(p-phenylenevinylene), a sulfonated polythieno[3,4-b]thiophene, polystyrenesulfonate, or a combination thereof. In one embodiment, the fiber or fabric is both flexible and elastic. The fibers and fabrics are of particular utility in electrochromic devices, particularly those which form or are a part of garments.

Abstract: Disclosed herein is a facile process for the formation of conjugated polymers inside or outside assembled solid-state devices. One process generally involves applying a voltage to a device comprising at least two electrodes, a combination of an electrolyte composition and a electroactive monomer disposed between the electrodes, and a potential source in electrical connection with the at least two electrodes; wherein the applying voltage polymerizes the electroactive monomer into a conjugated polymer. Also disclosed are electrochromic articles prepared from the process and solid-state devices comprising a composite of an electrolyte composition and a conjugated polymer.

Abstract: Polymers and copolymers having units derived from substituted 3,4-propylenedioxythiophene are disclosed. Also provided are methods of making and using the same.

Abstract: Disclosed herein are thermally stable conducting polymers prepared by template polymerization of a conducting monomer in the presence of a sulfonated poly(amic acid). The resulting conducting polymer-sulfonated poly(amic acid) complex can be thermally converted to a conducting polymer-sulfonated poly(imide) complex having high thermal stability and high conductivity. Also disclosed are articles prepared from the thermally stable conducting polymer.

Abstract: Polymers and copolymers having units derived from substituted 3,4-propylenedioxythiophene are disclosed. Also provided are methods of making and using the same.

Abstract: Photovoltaic cells containing nucleic acid materials and methods of production and use are provided. The nucleic acid materials have photovoltaic donor and acceptor molecules incorporated therein and define a spatial organization and orientation for these molecules that inhibits recombination of excitons and promotes efficiency in the photovoltaic cell. Preferred nucleic acid materials contain nucleic acid molecules complexed with ionic surfactants and are in the form of films, fibers, nanofibers, or non-woven meshes.

Abstract: An electrochromic fiber or fabric is disclosed. The fiber or fabric includes a flexible, electrically conductive fiber, and a layer comprising an electrochromic material disposed on and surrounding the flexible, electrically conductive fiber. In one embodiment, the fiber or fabric is both flexible and elastic. The fibers and fabrics are of particular utility in electrochromic devices, particularly those which form or are a part of garments.

Abstract: An electrochromic cell of the present invention may include a first electrically conducting transparent electrode bonded to an electrochemically formed first electrochromic electrode on the surface of the electrode; a second electrically conducting transparent electrode bonded to an electrochemically formed second electrochromic electrode on the surface of the second electrode and a transparent gel polymer electrolyte formed from one or more macromomoners mixed with a plasticizer and an electrolyte salt, the gel polymer containing ionic liquids in contact with both the first and second electrochromic electrodes; the first and second electrochromic electrodes are separated from each other.

Abstract: Disclosed herein are electrochromic devices using a very low band-gap conjugated polymer having a band gap (Eg) of less than or equal to about 1.5 eV, and having little or no electrochromism in the visible region of the electromagnetic spectrum.

Abstract: Polymers and copolymers having units derived from unsubstituted or substituted thieno[3,4-b]furan are disclosed. Also provided are methods of making and using the same.

Abstract: Inexpensive and facile methods of preparing fused heterocycles such as thieno[3,4-b]thiophene, thieno[3,4-b]furan, related compounds, and their derivatives are disclosed. Also disclosed are regioregular polymers prepared from the fused heterocycles.

Abstract: Nucleic acid materials for FRET-based luminescence and methods of making and using the nucleic acid materials are provided. The nucleic acid materials provide an innovative and synergistic combination of three disparate elements: a nucleic acid material, the processing technique for forming a nucleic acid material into films, fibers, nanofibers, or non-woven meshes, and nonradiative energy transfer. This combination can be formed into electrospun fibers, nanofibers, and non-woven meshes of a nucleic acid material-cationic lipid complex with encapsulated chromophores capable of nonradiative energy transfer such as efficient Förster Resonance Energy Transfer (FRET).

Abstract: An electrochromic cell of the present invention may include a first electrically conducting transparent electrode bonded to an electrochemically formed first electrochromic electrode on the surface of the electrode; a second electrically conducting transparent electrode bonded to an electrochemically formed second electrochromic electrode on the surface of the second electrode and a transparent gel polymer electrolyte formed from one or more macromonomers mixed with a plasticizer and an electrolyte salt, the gel polymer containing ionic liquids in contact with both the first and second electrochromic electrodes; the first and second electrochromic electrodes are separated from each other.

Abstract: An electrochromic cell is disclosed which can include a first electrically conducting transparent electrode bonded to an electrochemically formed first electrochromic electrode on the surface of the electrode; a second electrically conducting transparent electrode bonded to an electrochemically formed second electrochromic electrode on the surface of the second electrode and a transparent gel polymer electrolyte formed from one or more macromomoners mixed with a plasticizer and an electrolyte salt, the gel polymer electrolyte in contact with both the first and second electrochromic electrodes; the first and second electrochromic electrodes are separated from each other.

Abstract: An electrochromic cell is disclosed which can include a first electrically conducting transparent electrode bonded to an electrochemically formed first electrochromic electrode on the surface of the electrode; a second electrically conducting transparent electrode bonded to an electrochemically formed second electrochromic electrode on the surface of the second electrode and a transparent gel polymer electrolyte formed from one or more macromomoners mixed with a plasticizer and an electrolyte salt, the gel polymer electrolyte in contact with both the first and second electrochromic electrodes; the first and second electrochromic electrodes are separated from each other.