Abstract: An anode active material and a lithium battery employing the same are provided. In one embodiment of the anode active material, a —(CH2CH2O)— repeating unit is bonded to the surface of metal particles that contain metals that can be alloyed with lithium. The repeating unit prevents reactions between the metal particles and the electrolyte solution. Also, due to its elasticity, the repeating unit absorbs part of the volume expansion of the metal particles. The repeating unit also prevents the metal particles from condensing, thereby enhancing dispersion properties. Accordingly, the inventive anode active material has high capacity and excellent capacity retention during repeated charging and discharging, thereby providing a lithium battery with a long cycle life.

Abstract: A negative electrode including: a current collector; a negative active material layer formed on the current collector; and a polymer coating layer that is formed on the negative active material layer and comprises a fluorinated acrylate type polymer.

Abstract: An anode includes an anode active material including a lithium titanium oxide, a binder, and 0 to about 2 parts by weight of a carbon-based conductive agent based on 100 parts by weight of the lithium titanium oxide.

Abstract: A surface treated anode and a lithium battery using the same are provided. The surface treated anode includes a current collector, and an anode active material layer formed on the current collector. The anode active material layer is treated with an amine group containing compound.

Abstract: An anode active material comprises graphite core particles, and a first coating layer and a second coating layer formed on the surface of the graphite core particles. The first coating layer comprises silicon microparticles and the second coating layer comprises carbon fiber.

Abstract: A cathode active material, a cathode including the cathode active material, a lithium battery including the cathode, and a method of preparing the cathode active material, the cathode active material including a lithium-containing metal oxide and an organic material coated on the lithium-containing metal oxide, the organic material including an acrylate or methacrylate organic material including an alkyleneglycol unit.

Abstract: An anode active material including a metal core and a coating layer formed on a surface of the metal core is provided. The coating layer includes a conductive metal material. The coating layer covering the metal core is carbon-based and includes a conductive metal material. The anode active material has good electron conductivity and elasticity, thereby enhancing charge/discharge capacity and reducing the stress caused by expansion of the carbon-based coating layer and the metal core during charge/discharge cycles. Direct contact between the metal core and the electrolyte solution is remarkably reduced. In addition, anodes and lithium batteries including the anode active material exhibit excellent charge/discharge characteristics, such as discharge capacity and initial charge/discharge efficiency.

Abstract: An organic electrolytic solution is provided which includes a lithium salt, an organic solvent including a first solvent having high permittivity and a second solvent having a low boiling point, and a phosphine oxide compound The phosphine oxide compound imparts flame resistance and good charge/discharge properties, thereby producing a lithium battery that is highly stable and reliable and that has good charge/discharge efficiency.

Abstract: An anode active material comprises metal core particles, metal nano wires formed on the metal core particles, pores between the metal core particles and the metal nano wires, and a carbon-based coating layer formed on a surface of the metal core particles and metal nano wires. In the anode active material according to the present invention, the metal core particles and metal nano wires are combined to form a single body, and a carbon-based coating layer is formed on the surface of the metal nano wires and metal core particles. Thus, volume changes in the pulverized metal core particles can be effectively buffered during charging and discharging, and the metal core particles are electrically connected through the metal nano wires. As a result, volume changes in the anode active material and degradation of the electrode can be prevented, thereby providing excellent initial charge/discharge efficiency and enhanced charge/discharge capacity.

Abstract: An anode active material comprises metal core particles, metal nano wires formed on the metal core particles, pores between the metal core particles and the metal nano wires, and a carbon-based coating layer formed on a surface of the metal core particles and metal nano wires. In the anode active material according to the present invention, the metal core particles and metal nano wires are combined to form a single body, and a carbon-based coating layer is formed on the surface of the metal nano wires and metal core particles. Thus, volume changes in the pulverized metal core particles can be effectively buffered during charging and discharging, and the metal core particles are electrically connected through the metal nano wires. As a result, volume changes in the anode active material and degradation of the electrode can be prevented, thereby providing excellent initial charge/discharge efficiency and enhanced charge/discharge capacity.

Abstract: A composite anode active material includes a first intermetallic compound, a second intermetallic compound, a metal that is incapable of alloy formation with lithium, and carbon. In the composite anode active material, an amorphous carbon is present between the first intermetallic compound and the second intermetallic compound, and the metal that is incapable of alloy formation with lithium is uniformly distributed throughout in the composite anode active material. The composite anode active material may be used as an anode of a lithium rechargeable battery.

Abstract: Composite cathode active materials having a large diameter active material and a small diameter active material are provided. The ratio of the average particle diameter of the large diameter active material to the average particle diameter of the small diameter active material ranges from about 6:1 to about 100:1. Mixing the large and small diameter active materials in a proper weight ratio improves packing density Additionally, including highly stable materials and highly conductive materials in the composite cathode active materials improves volume density, discharge capacity and high rate discharge capacity.

Abstract: Composite cathode active materials having a large diameter active material and a small diameter active material are provided. The ratio of the average particle diameter of the large diameter active material to the average particle diameter of the small diameter active material ranges from about 6:1 to about 100:1. Mixing the large and small diameter active materials in a proper weight ratio improves packing density Additionally, including highly stable materials and highly conductive materials in the composite cathode active materials improves volume density, discharge capacity and high rate discharge capacity.

Abstract: A cathode active material for a lithium rechargeable battery is provided. The cathode active material is used for a lithium rechargeable battery containing a cathode, an anode, and an electrolytic solution. The cathode active material is composed of 0.5% by weight or less carbonate ion (CO32?) plus bicarbonate ion (HCO3?) and 0.1% by weight or less hydroxyl ion (OH?). The swelling of lithium battery containing the cathode active material is substantially suppressed when is placed at 60° C. or more.

Abstract: An anode includes a collector; and an anode active material layer disposed on the collector comprises an anode active material, which is lithium oxide coated Li4Ti5O12, a conductive material, and a binder, wherein the lithium oxide intercalates and/or deintercalates lithium ions into and from the lattice structure of Li4Ti5O12. By coating the surface of the anode active material with lithium oxide, an anode including the surface-treated anode active material has a high capacity, high-rate properties, and a high initial efficiency.

Abstract: Composite cathode active materials comprising a composite oxide and an acid treated with an organic solvent are provided. The composite cathode active materials are prepared by treating mixtures of nickel-based composite oxides and organic acids with organic solvents. The active materials suppress gelation of the electrode slurries for a long period of time, even when the active materials are mixed with fluorine-based polymers, by decreasing the basicity of the slurries and the amount of lithium present on the surfaces of the active materials. As a result, electrode slurries having high stability can be prepared. Cathodes and lithium batteries comprising the slurries have excellent charge-discharge characteristics, including high capacity and excellent high rate discharge characteristics.

Abstract: An electrode includes a current collector and an active material layer on top of the current collector, wherein the active material layer includes an active material and a binder, and a complex of a first conductive agent and a binding agent is formed on a surface of the active material; a method of manufacturing the same, and a lithium battery including the electrode.

Abstract: A surface treated anode and a lithium battery using the same are provided. The surface treated anode includes a current collector, and an anode active material layer formed on the current collector. The anode active material layer is treated with an amine group containing compound.

Abstract: Anode active materials and methods of preparing the same are provided. One anode active material includes a carbonaceous material capable of improving battery cycle characteristics. The carbonaceous material bonds to and coats metal active material particles and fibrous metallic particles to suppress volumetric changes.

Abstract: An organic electrolytic solution containing an organic solvent and a compound that contains an anionic polymerization monomer with an added component capable of being chelated with a lithium metal cation. A lithium battery may utilize the organic electrolytic solution. The lithium battery may have improved stability to reductive decomposition, reduced first cycle irreversible capacity, and improved charging/discharging efficiency and lifespan. Moreover, reliability of the battery may be improved because the battery, after formation and standard charging at room temperature, may not swell beyond a predetermined thickness. Even when the lithium battery swells significantly at a high temperature, the capacity of the lithium battery may be high enough for practical applications due to its recovery capacity.