Abstract: Catalytic dealkoxylation of gem-dialkoxy compounds for synthesizing vinyl ethers is disclosed. Zeolites of the mordenite or ZSM5 type with an Na.sub.2 O/Al.sub.2 O.sub.3 molar ratio of 1:1.05 (.+-.0.25) are used as catalysts.

Abstract: A catalyst is described for the production of unsaturated aldehydes by means of oxidation with a oxygen-containing gas where an active mass, containing at least the elements Mo, Bi, P and O, as well as Si-containing carrier material, is used in the form of a catalyst body with a certain ratio between the outer surface and the volume and with a defined extent in terms of space, porosity, density, specific surface, breaking strength, abrasion, and gas through-flow capability. Also described is a method of making the catalyst.

Abstract: The present invention relates to a process for the production of acrolein by catalytic gas-phase oxidation of propene with air in the presence of steam and an inert gas or waste gas from the reaction, the starting materials being passed in defined quantitative ratios at 300.degree. to 380.degree. C. under 1.4 to 2.2 bar pressure over a catalyst containing the combination of elements MoFeCoNiBiP(As)K(Rb,Cs)SmSiO in the form of a bed of individual elements, the catalyst elements fulfilling certain geometric conditions and a number of critical physico-chemical parameters and a specific load of 2 to 8 mol propene/dm.sup.3 catalyst bed/h being adjusted.

Abstract: Rhenium-oxo complexes withoctaethyl porphyrin or5,10,15,20-tetraphenyl porphyrins or5,10,15,20-tetra(4-pyridyl)-porphyrins as ligandswhich optionally carry an anion on the central atom. Methods of preparing the complexes are also disclosed.

Abstract: A method for the catalytic epoxidation of olefins with hydrogen peroxide in the presence of rhenium-oxo-complexes or of a binuclear compound of the type .mu.-oxobis [porphyrinato-oxo-rhenium(V)] with octaethyl porphyrin or 5,10,15,20-tetraphenyl porphyrin or 5,10,15,20-tetra(4-pyridyl)-porphyrin as ligands.

Abstract: A method for the preparation of tetrahydrofurfuryl-(2)-methacrylate by transesterification of methyl methacrylate or ethyl methacrylate with tetrahydrofurfuryl-(2)-methyl alcohol in the presence of the corresponding alkali metal or alkaline earth metal as a catalyst and while air or oxygen is passed through the reaction mixture.

Abstract: Aliphatic epoxides of the formula: ##STR1## can be prepared in a technically efficient manner from the corresponding olefins by means of perpropionic acid in a benzene solution. The benzene solution can also be 1.5 weight percent of hydrogen peroxide, 1.5 weight percent of water and about 800 ppm of mineral acid.

Abstract: Epoxidized polybutadienes with an average molecular weight of 500 to 100,000 and a certain content of epoxide oxygen were prepared from the corresponding polybutadienes with use of perpropionic acid in a benzene solution. The solution can also be employed in unpurified form with maximum contents of 1.5 weight percent hydrogen peroxide 1.5 weight percent of water, and about 800 ppm of mineral acid.

Abstract: The diepoxide of the formula: ##STR1## can be prepared from the corresponding diolefin in a technically simple manner by means of perpropionic acid in a benzene solution. The solution can also be employed in unpurified form with certain maximum contents of 1.5 weight percent of hydrogen peroxide, 1.5 weight percent of water, and of about 800 ppm of mineral acid.

Abstract: A method for the catalytic epoxidation of olefines with hydrogen peroxide in the presence of tungsten oxo complexes or of a binuclear compound of the type .mu.-oxobis [porphyrinato-oxo tungsten (V)] or cis-oxo peroxo tungsten (VI) prophyrin or cis-dioxo porphyrinatotungsten (VI) with octaethyl porphyrin or 5,10,15,20-tetraphenyl porphyrin or 5,10,15,20-tetra(4-pyridyl)-porphyrin as ligands.

Abstract: A method for the production of substituted 1,2,3- and 1,2,4-trihydroxybenzenes in a single process reaction step, wherein the corresponding substituted resorcinol which is a substituted 1,3-dihydroxybenzene is contacted with an aqueous hydrogen peroxide solution and through control of the water content of the initial reaction condition and control of the reaction temperature the desired products are obtained.

Abstract: Method for the conversion of resorcinol with aqueous hydrogen peroxide to obtain a mixture of 1,2,3- and 1,2,4-trihydroxybenzenes wherein the amount of water present in the initial reaction mixture is controlled to small amounts.

Abstract: Resorcinol and substituted resorcinols are converted in one single step reaction into 1,2,3- and 1,2,4-trihydroxybenzenes and substituted hydroxy resorcinol compounds with a benzene solution of peroxypropionic acid.

Abstract: The method for the isomerization of oxiranes of the general formula: ##STR1## wherein R.sub.1 and R.sub.3 are hydrogen; R.sub.2 is alkyl or alkylene groups of 3 to 26 carbon atoms or the phenyl group which may also be substituted, and R.sub.4 is hydrogen or alkyl from 1 to 26 carbon atoms and in which the carbon atoms of the epoxy ring can also form components of a cyclic system, wherein as a catalyst there is used alkali iodide and a polyethyleneglycol with an average mol mass of 400 to 10,000 with a boiling point, preferably above the boiling point of the carbonyl compounds that are formed.

Abstract: A process for the production of 1,12-dodecanoic diacid by hydroformylating an olefin in the presence of a rhodium catalyst and oxidation with oxygen of the aldehyde which is thus formed wherein 1,9-decadiene is hydroformylated in the presence of hydridotris-triphenylphosphine-rhodium-carbonyl combined with triphenylphospine and/or triphenylphosphite, and the 1,12-dodecanedialdehyde which was thus formed is oxidized with oxygen in the presence of inorganic or organic Co(II) salts.

Abstract: A process for the production of 1,12-dodecanoic diacid by hydroformylating an unsaturated carboxy compound in the presence of a rhodium catalyst and oxidation of the aldehyde with oxygen, wherein undecyl-10-ene-acid is hydroformylated in the presence of hydridotristriphenylphosphine-rhodium-carbonyl combined with triphenylphosphine and/or triphenylphosphite, and the 11-formyl undecanioc acid which is thus formed is oxidized with oxygen in the presence of inorganic and organic Co(II) salts.

Abstract: The continuous preparation of .DELTA. 3-tetrahydrobenzoic acid- .DELTA. 3-tetrahydrobenzyl ester by reaction of 3-cyclohexene-1-carboxaldehyde is disclosed. The reaction is carried out in the presence of an aluminum mixed alcoholate, in which half of the alcohol components consists of isopropylate groups and the other half of sec-butylate groups.

Abstract: A process for the preparation of expoxidized organosilicon compounds by reacting the corresponding unsaturated organosilicon compounds with perpropionic acid in benzene solution. The said solution can also be employed in purified form with maximum contents of hydrogen peroxide, water, or mineral acid.

Abstract: A process is disclosed for the preparation of 2-alkyl-1,4-butanedial by hydroformylation of acetals of a 2-alkyl-substituted-1-propenal in the presence of a complex rhodium catalyst. The 3-alkyl-4,4-dialkoxybutanal obtained in this manner is separated and hydrolyzed to the desired compound.

Abstract: A continuous process for the production of 3-cyclohexene-1-carboxaldehyde by reaction of acrolein with butadiene at an elevated temperature and increased pressure is described in which good yields are obtained by establishing the weight ratio of the starting substances fed per time unit into a circulation reactor in relation to the reaction mixture circulated per time unit in the range of 1:5 to 1:60 and by carrying out a secondary reaction in successive reactors.