Patents by Inventor Guido Protzmann

Guido Protzmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9701846
    Abstract: A radiation-reflecting road marking, comprising: metal particles having a diameter of between 0.5-2.5 mm, wherein the metal particles are particles comprising aluminum, magnesium, zinc or an alloy thereof. Also, a method for producing the radiation-reflecting road marking, where the radiation-reflecting road marking is a cold plastic, by mixing components of a two-part system, if necessary, to form a mixture, applying the mixture to a road surface, and adding the metal particles and optionally glass beads during or directly after an application of the cold plastic to the road surface.
    Type: Grant
    Filed: November 6, 2013
    Date of Patent: July 11, 2017
    Assignee: EVONIK ROEHM GmbH
    Inventors: Guido Protzmann, Joern Kiwitt, Dominik Kiefer, Guenter Schmitt, Marita Kaufmann, Michael Olapoju
  • Patent number: 9688601
    Abstract: Process for preparing (meth)acrylates of the formula (I) CH2?C(R1)—CO—O—R2??(I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2?C(R1)—CO—OR3??(II) with an alcohol of the formula (III) HO—R2??(III) in the presence of an amount of a suitable catalyst which catalyzes the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.
    Type: Grant
    Filed: October 27, 2015
    Date of Patent: June 27, 2017
    Assignee: Evonik Roehm GmbH
    Inventors: Joachim Knebel, Ralf Merbach, Guido Protzmann, Klaus Gottmann, John Hirsh, Gerold Schmitt, Dieter Tessmer, Wilhelm Karnbrock, Wolfgang Klesse, Volker Kerscher
  • Publication number: 20160046556
    Abstract: Process for preparing (meth)acrylates of the formula (I) CH2?C(R1)—CO—O—R2 ??(I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2?C(R1)—CO—OR3 ??(II) with an alcohol of the formula (III) HO—R2 ??(III) in the presence of an amount of a suitable catalyst which catalyses the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.
    Type: Application
    Filed: October 27, 2015
    Publication date: February 18, 2016
    Applicant: Evonik Roehm GmbH
    Inventors: Joachim KNEBEL, Ralf MERBACH, Guido PROTZMANN, Klaus GOTTMANN, John HIRSH, Gerold SCHMITT, Dieter TESSMER, Wilhelm KARNBROCK, Wolfgang KLESSE, Volker KERSCHER
  • Publication number: 20160017151
    Abstract: The present invention encompasses an innovative concept for the marking of trafficways, more particularly roads. The application qualities and lifetime of these new markings are comparable with those of the prior art. The markings also possess properties comparable with those of the prior art in respect of night visibility, back-in-service time, and surface quality. An additional contribution of the markings of the present invention, however, is that they can be used to support modern driver assistance systems and autonomous driving. With this in mind, the present invention relates more particularly to road markings which, building on established systems, are equipped with additional reflection capacity for electromagnetic radiation, more particular for microwaves and/or infrared radiation.
    Type: Application
    Filed: March 13, 2014
    Publication date: January 21, 2016
    Applicant: EVONIK ROEHM GMBH
    Inventors: Guido PROTZMANN, Jörn KIWITT, Dominik KIEFER, Günter SCHMITT, Marita KAUFMANN, Michael OLAPOJU
  • Patent number: 9206270
    Abstract: Process for preparing (meth)acrylates of the formula (I) CH2?C(R1)—CO—O—R2??(I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2?C(R1)—CO—OR3??(II) with an alcohol of the formula (III) HO—R2??(III) in the presence of an amount of a suitable catalyst which catalyzes the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: December 8, 2015
    Assignee: Evonik Roehm GmbH
    Inventors: Joachim Knebel, Ralf Merbach, Guido Protzmann, Klaus Gottmann, John Hirsh, Gerold Schmitt, Dieter Tessmer, Wilhelm Karnbrock, Wolfgang Klesse, Volker Kerscher
  • Publication number: 20150247297
    Abstract: The present invention encompasses an innovative concept for the marking of trafficways, more particularly roads. The application qualities and lifetime of these new markings are comparable with those of the prior art. The markings also possess properties comparable with those of the prior art in respect of night visibility, back-in-service time, and surface quality. An additional contribution of the markings of the present invention, however, is that they can be used to support modern driver assistance systems and autonomous driving. With this in mind, the present invention relates more particularly to road markings which, building on established systems, are equipped with additional reflection capacity for electromagnetic radiation, more particular for microwaves and/or infrared radiation.
    Type: Application
    Filed: November 6, 2013
    Publication date: September 3, 2015
    Applicant: EVONIK INDUSTRIES AG
    Inventors: Guido Protzmann, Joern Kiwitt, Dominik Kiefer, Guenter Schmitt, Marita Kaufmann, Michael Olapoju
  • Patent number: 8686181
    Abstract: The present invention relates to a process for preparing ethylene glycol dimethacrylate, which comprises transesterification of ethylene glycol with an ester of methacrylic acid in the presence of catalysts, wherein a combination comprising lithium amide (LiNH2) and lithium chloride (LiCl) is used as catalyst. The process of the invention makes it possible to prepare ethylene glycol dimethacrylate particularly inexpensively and in a very high purity.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: April 1, 2014
    Assignee: Evonik Roehm GmbH
    Inventors: Joachim Knebel, Thorben Schuetz, Guido Protzmann, Harald Trauthwein, Guenther Lauster, Thomas Kehr, Gerhard Koelbl, Guenter Westhaeuser
  • Patent number: 8674133
    Abstract: The invention relates to a process for continuously preparing N-alkyl(meth)acrylamides by reacting alkyl(meth)acrylates with high-boiling amines. A catalyst activation and specific workup technique achieve product qualities which have not been achieved to date. In addition, very high space-time yields and overall yields can be achieved.
    Type: Grant
    Filed: March 3, 2010
    Date of Patent: March 18, 2014
    Assignee: Evonik Röhm GmbH
    Inventors: Bardo Schmitt, Wolfgang Klesse, Martina Ebert, Dirk Broell, Guido Protzmann, Joachim Knebel, Thomas Kehr, Hans-Gerhard Stadler, Gerhard Koelbl, Benedikt Laux
  • Patent number: 8575388
    Abstract: The present invention relates to a method for producing methacrylic acid by reacting methacrylamide with water, wherein said reaction is performed continuously in a tube reactor and a pressure differential exists in the flow direction of the reaction mixture inside said tube reactor. Furthermore, the present invention discloses a facility for carrying out the method according to the invention.
    Type: Grant
    Filed: January 13, 2009
    Date of Patent: November 5, 2013
    Assignee: Evonik Roehm GmbH
    Inventors: Udo Gropp, Stefanie Sohnemann, Guido Protzmann, Thomas Mertz
  • Publication number: 20130172598
    Abstract: The present invention relates to a process for preparing ethylene glycol dimethacrylate, which comprises transesterification of ethylene glycol with an ester of methacrylic acid in the presence of catalysts, wherein a combination comprising lithium amide (LiNH2) and lithium chloride (LiCl) is used as catalyst. The process of the invention makes it possible to prepare ethylene glycol dimethacrylate particularly inexpensively and in a very high purity.
    Type: Application
    Filed: May 8, 2008
    Publication date: July 4, 2013
    Applicant: Evonik Roehm GmbH
    Inventors: Joachim Knebel, Thorben Schuetz, Guido Protzmann, Harald Trauthwein, Guenther Lauster, Thomas Kehr, Gerhard Koelbl, Guenter Westhaeuser
  • Patent number: 8389762
    Abstract: The present invention relates to a process for purifying methacrylic acid, wherein the reaction mixture obtained by a reaction of methacrylamide with water is cooled by mixing with an aqueous medium and then passed into a phase separator. The present invention further describes a system for performing the process according to the invention.
    Type: Grant
    Filed: January 13, 2009
    Date of Patent: March 5, 2013
    Assignee: Evonik Röhm GmbH
    Inventors: Udo Gropp, Stefanie Sohnemann, Guido Protzmann, Thomas Mertz
  • Patent number: 8129563
    Abstract: The present invention relates to a process for preparing allyl methacrylate, comprising the reaction of allyl alcohol with an ester of methacrylic acid, wherein the reaction is catalyzed by zirconium acetylacetonate. The process according to the invention enables particularly favorable preparation of allyl methacrylate with a very high purity.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: March 6, 2012
    Assignee: Evonik Roehm GmbH
    Inventors: Bardo Schmitt, Guido Protzmann, Thorben Schuetz, Harald Trauthwein, Reinhold Martin, Joachim Knebel, Ingo Sander, Klaus Gottmann, Thomas Kehr, Dieter Bathen, Christian Maul
  • Publication number: 20120004460
    Abstract: The present invention relates to a method for producing methacrylic acid by reacting methacrylamide with water, wherein said reaction is performed continuously in a tube reactor and a pressure differential exists in the flow direction of the reaction mixture inside said tube reactor. Furthermore, the present invention discloses a facility for carrying out the method according to the invention.
    Type: Application
    Filed: January 13, 2009
    Publication date: January 5, 2012
    Applicant: Evonik Roehm GmbH
    Inventors: Udo Gropp, Stefanie Sohnemann, Guido Protzmann, Thomas Mertz
  • Publication number: 20110313195
    Abstract: The invention relates to a process for continuously preparing N-alkyl(meth)acrylamides by reacting alkyl (meth)acrylates with high-boiling amines. A catalyst activation and specific workup technique achieve product qualities which have not been achieved to date. In addition, very high space-time yields and overall yields can be achieved.
    Type: Application
    Filed: March 3, 2010
    Publication date: December 22, 2011
    Inventors: Bardo Schmitt, Wolfgang Klesse, Martina Ebert, Dirk Broell, Guido Protzmann, Joachim Knebel, Thomas Kehr, Hans-Gerhard Stadler, Gerhard Koelbl, Benedikt Laux
  • Patent number: 8049030
    Abstract: The present invention relates to a process for preparing (meth)acrylates, which comprises the transesterification of an alcohol with a low-boiling ester of (meth)acrylic acid in the presence of catalysts, with the alcohol liberated from the low-boiling ester of (meth)acrylic acid being separated off by distillation, characterized in that the molar ratio of low-boiling ester of (meth)acrylic acid to starting alcohol present in the reaction mixture is increased during the reaction by addition of low-boiling ester of (meth)acrylic acid. The process of the invention makes a particularly inexpensive preparation of (meth)acrylates having a very high purity possible.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: November 1, 2011
    Assignee: Evonik Röhm GmbH
    Inventors: Guido Protzmann, Harald Trauthwein, Joachim Knebel, Thorben Schuetz, Gerhard Koelbl, Thomas Kehr, Guenther Lauster
  • Patent number: 8039664
    Abstract: The present invention relates to a process for preparing butanediol dimethacrylates, which comprises the transesterification of butanediol with an ester of methacrylic acid in the presence of catalysts, wherein a combination comprising at least one lithium compound and at least one calcium compound is used as catalyst, at least one of the compounds of lithium and/or of calcium is an oxide, a hydroxide, an alkoxide having from 1 to 4 carbon atoms or a carboxylate having from 1 to 4 carbon atoms and at least part of the reaction is carried out in the presence of an effective amount of water. The process of the invention makes a particularly inexpensive preparation of butanediol dimethacrylates having a very high purity possible.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: October 18, 2011
    Assignee: Evonik Roehm GmbH
    Inventors: Joachim Knebel, Thorben Schuetz, Harald Trauthwein, Thomas Kehr, Guenther Lauster, Guido Protzmann, Gerhard Koelbl, Guenter Westhaeuser
  • Publication number: 20100331572
    Abstract: The present invention relates to a method for producing methacrylic acid by reacting methacrylamide with water, wherein said reaction is performed continuously in a tube reactor and a pressure differential exists in the flow direction of the reaction mixture inside said tube reactor. Furthermore, the present invention discloses a facility for carrying out the method according to the invention.
    Type: Application
    Filed: January 3, 2009
    Publication date: December 30, 2010
    Applicant: Evonik Roehm GmbH
    Inventors: Udo Gropp, Stefanie Sohnemann, Guido Protzmann, Thomas Mertz
  • Publication number: 20100314239
    Abstract: The present invention relates to a process for purifying methacrylic acid, wherein the reaction mixture obtained by a reaction of methacrylamide with water is cooled by mixing with an aqueous medium and then passed into a phase separator. The present invention further describes a system for performing the process according to the invention.
    Type: Application
    Filed: January 13, 2009
    Publication date: December 16, 2010
    Applicant: EVONIK ROEHM GMBH
    Inventors: Udo Gropp, Stefanie Sohnemann, Guido Protzmann, Thomas Mertz
  • Publication number: 20100280205
    Abstract: Process for preparing (meth)acrylates of the formula (I) CH2?C(R1)—CO—O—R2 ??(I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2?C(R1)—CO—OR3 ??(II) with an alcohol of the formula (III) HO—R2 ??(III) in the presence of an amount of a suitable catalyst which catalyses the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.
    Type: Application
    Filed: September 29, 2008
    Publication date: November 4, 2010
    Applicant: Evonik Roehm GmbH
    Inventors: Joachim Knebel, Ralf Merbach, Guido Protzmann, Klaus Gottmann, John Hirsh, Gerold Schmitt, Dieter Tessmer, Wilhelm Karnbrock, Wolfgang Klesse, Volker Kerscher
  • Publication number: 20100204509
    Abstract: The present invention relates to a process for preparing (meth)acrylates, which comprises the transesterification of an alcohol with a low-boiling ester of (meth)acrylic acid in the presence of catalysts, with the alcohol liberated from the low-boiling ester of (meth)acrylic acid being separated off by distillation, characterized in that the molar ratio of low-boiling ester of (meth)acrylic acid to starting alcohol present in the reaction mixture is increased during the reaction by addition of low-boiling ester of (meth)acrylic acid. The process of the invention makes a particularly inexpensive preparation of (meth)acrylates having a very high purity possible.
    Type: Application
    Filed: May 8, 2008
    Publication date: August 12, 2010
    Applicant: EVONIK ROEHM GMBH
    Inventors: Guido Protzmann, Harald Trauthwein, Joachim Knebel, Thorben Schuetz, Gerhard Koelbl, Thomas Kehr, Guenther Lauster