Patents by Inventor Guizhe Zhao

Guizhe Zhao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20220289934
    Abstract: A method for preparing a graphene masterbatch by an aqueous phase synergistic aggregating precipitating process and a method for molding a long-lifespan tire for a loading wheel of a heavy-duty vehicle. In this application, a graphene oxide aqueous dispersion and natural rubber latex are taken as raw materials, and subjected to co-precipitating in a water medium to prepare a high-graphene content masterbatch with individual components evenly dispersed. The graphene masterbatch is further subjected to two-stage high-temperature mechanical blending with a natural rubber block to achieve the uniform dispersion of graphene in a rubber composites.
    Type: Application
    Filed: June 2, 2022
    Publication date: September 15, 2022
    Inventors: Yaqing LIU, Xiaoyuan DUAN, Shuaishuai CHENG, Guizhe ZHAO
  • Publication number: 20220289639
    Abstract: Disclosed is a method for preparing a nitrogen-rich or nutritious straw-based slow-release fertilizer through In-Situ straw modification/reactive extrusion integrated continuous process. In the method, the liquid reaction precursor of a nitrogen-containing biodegradable slow-release fertilizer is mixed with crop straw to obtain a reaction mixture, or the liquid reaction precursor of a nitrogen-containing biodegradable slow-release fertilizer, crop straw and a soluble fertilizer are mixed to obtain a reaction mixture. The reaction mixture is subjected to extrusion in a screw extruder to produce the nitrogen-rich or nutritious straw-based slow-release fertilizer.
    Type: Application
    Filed: May 31, 2022
    Publication date: September 15, 2022
    Inventors: Yaqing LIU, Guizhe ZHAO, Yang XIANG
  • Publication number: 20220250997
    Abstract: The present invention discloses a highly efficient and environment-friendly reactive extrusion integrated continuous preparation process for a biodegradable polymeric multi-nutrient elements nano slow/controlled-release fertilizer and a biodegradable polymeric multi-nutrient elements nano slow/controlled-release fertilizer prepared by the process consisting of urea-formaldehyde macromolecular chains and nano-phosphate. Firstly preparing a methylolurea solution, and then feeding the same into a reactive extrusion integrated machine, adding a phosphate, starting the reaction unit of the reactive extrusion integrated machine to carry out the reaction, and simultaneously starting the vacuumizing devolatilization apparatus to remove moisture from the reaction system; after completing the reaction, starting the extrusion unit of the reactive extrusion integrated machine, extruding to obtain a strip-shaped product, and drying and granulating the same to obtain a finished product.
    Type: Application
    Filed: December 28, 2021
    Publication date: August 11, 2022
    Applicant: North University of China
    Inventors: Yaqing Liu, Yang Xiang, Guizhe Zhao
  • Publication number: 20220146489
    Abstract: A device for determining degradation rate of biodegradable polymers in soil, including a micro compressed air pump, a first CO2 absorption vessel filled with dry soda lime or an aqueous strong alkali solution, a CO2 indicator vessel filled with a barium hydroxide solution, a hollow leaching device, a second CO2 absorption vessel and a third CO2 absorption vessel connected in sequence through connecting pipes. A top of the hollow leaching device is provided with an end cover. An external water distributor filled with a leaching solution and a mechanical stirring device is arranged above the end cover. The external water distributor is in communication with an inner cavity of the hollow leaching device through a pipeline. A stirring shaft of the mechanical stirring device extends into the inner cavity. A stirring shaft is provided with a stirring paddle.
    Type: Application
    Filed: January 22, 2022
    Publication date: May 12, 2022
    Inventors: Yaqing LIU, Taian CHEN, Yang XIANG, Guizhe ZHAO
  • Publication number: 20220095498
    Abstract: A gradient electrically conductive-uniform thermally conductive dual network structure-based electromagnetic shielding polymer composite with low reflection and high absorption and a preparation method thereof. The electromagnetic shielding polymer composite includes a gradient conductive carbon nanotube network with a vertically oriented cell structure and a uniformly thermally conductive hexagonal boron nitride/carbon nanotube network constructed by the hexagonal boron nitride dispersed uniformly in the carbon nanotube network and the gradient carbon nanotube network. The gradient electrically conductive carbon nanotube network and the uniformly thermally conductive hexagonal boron nitride/carbon nanotube network form a composite synergistic dual function network structure so as to make the electromagnetic shielding polymer composite have a low reflection and high absorption and excellent thermal conductivity.
    Type: Application
    Filed: December 2, 2021
    Publication date: March 24, 2022
    Inventors: Yaqing LIU, Hongji DUAN, Guizhe ZHAO
  • Publication number: 20210261709
    Abstract: The invention relates to the field of preparing biodegradable polymer slow/controlled release composite, in particular to a biodegradable polymer slow/controlled release binary composite urea-formaldehyde/poly(butylene succinate) and a biodegradable polymer slow/controlled release ternary nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate. The following steps are included: uniformly mixing two components poly(butylene succinate) and methylol-urea or three components poly(butylene succinate), methylol-urea and potassium dihydrogen phosphate, and then extruding the resulting mixture by an extruder, and the biodegradable polymer slow/controlled release composite urea-formaldehyde/poly(butylene succinate) containing nutrient N and the biodegradable polymer slow/controlled release nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate containing nutrients of N, P and K are obtained respectively.
    Type: Application
    Filed: July 22, 2020
    Publication date: August 26, 2021
    Applicant: North University of China
    Inventors: Yaqing Liu, Guizhe Zhao, Wei Zhang, Yang Xiang
  • Patent number: 10906843
    Abstract: The invention relates to the field of slow/controlled release fertilizer, in particular to a urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer and a preparation method thereof. The urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer comprises ammonium polyphosphate, inorganic silica gel and urea-formaldehyde, wherein the phosphorus-oxygen double bond of ammonium polyphosphate can at least form hydrogen bond linkage with a urea-formaldehyde molecule chain, the hydroxyl group of the inorganic silica gel can at least form hydrogen bond linkage with the urea-formaldehyde molecular chain, and ammonium polyphosphate, inorganic silica gel and urea-formaldehyde together form a hydrogen bond associated polymer network structure.
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: February 2, 2021
    Assignee: North University of China
    Inventors: Guizhe Zhao, Yang Xiang, Yaqing Liu
  • Patent number: 10865161
    Abstract: This disclosure relates to water-absorbing and slow/controlled release fertilizer, in particular to a water-absorbing and water-retaining multi-nutrient biodegradable polymeric slow/controlled release fertilizer having a semi-interpenetrating network structure, and preparation methods thereof. The method can comprises the steps of: reacting formaldehyde with urea to obtain a hydroxymethyl urea solution; adding acrylic acid and acrylamide monomers into another reactor, and adding a KOH solution to adjust the neutralization degree of acrylic acid, then adding one of inorganic clay, pretreated crop straw or cellulose, then adding initiator, monopotassium phosphate and the prepared hydroxymethyl urea solution sequentially; allowing to react at temperature after being mixed uniformly to obtain a viscous product; and granulating the viscous product and oven drying the same to obtain the fertilizer.
    Type: Grant
    Filed: March 2, 2018
    Date of Patent: December 15, 2020
    Assignee: NORTH UNIVERSITY OF CHINA
    Inventors: Yaqing Liu, Yang Xiang, Guizhe Zhao
  • Publication number: 20190218152
    Abstract: The invention relates to the field of slow/controlled release fertilizer, in particular to a urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer and a preparation method thereof. The urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer comprises ammonium polyphosphate, inorganic silica gel and urea-formaldehyde, wherein the phosphorus-oxygen double bond of ammonium polyphosphate can at least form hydrogen bond linkage with a urea-formaldehyde molecule chain, the hydroxyl group of the inorganic silica gel can at least form hydrogen bond linkage with the urea-formaldehyde molecular chain, and ammonium polyphosphate, inorganic silica gel and urea-formaldehyde together form a hydrogen bond associated polymer network structure.
    Type: Application
    Filed: November 5, 2018
    Publication date: July 18, 2019
    Applicant: North University of China
    Inventors: Guizhe Zhao, Yang Xiang, Yaqing Liu
  • Publication number: 20190031574
    Abstract: This disclosure relates to water-absorbing and slow/controlled release fertilizer, in particular to a water-absorbing and water-retaining multi-nutrient biodegradable polymeric slow/controlled release fertilizer having a semi-interpenetrating network structure, and preparation methods thereof. The method can comprises the steps of: reacting formaldehyde with urea to obtain a hydroxymethyl urea solution; adding acrylic acid and acrylamide monomers into another reactor, and adding a KOH solution to adjust the neutralization degree of acrylic acid, then adding one of inorganic clay, pretreated crop straw or cellulose, then adding initiator, monopotassium phosphate and the prepared hydroxymethyl urea solution sequentially; allowing to react at temperature after being mixed uniformly to obtain a viscous product; and granulating the viscous product and oven drying the same to obtain the fertilizer.
    Type: Application
    Filed: March 2, 2018
    Publication date: January 31, 2019
    Applicant: NORTH UNIVERSITY OF CHINA
    Inventors: Yaqing Liu, Yang Xiang, Guizhe Zhao
  • Patent number: 9051222
    Abstract: The present invention provides a slow and controlled release polymeric sulfur fertilizer containing multiple nutrient elements. The slow and controlled release polymeric sulfur fertilizer is represented by the following formula, in which m=1-4, and n=100-210. The element sulfur in the slow and controlled release polymeric sulfur fertilizer according to embodiments of the present invention has very high utilization rate.
    Type: Grant
    Filed: October 21, 2014
    Date of Patent: June 9, 2015
    Assignee: North University of China
    Inventors: Yaqing Liu, Guizhe Zhao, Dongdong Cheng, Lifeng Zhou, Denghui Wu
  • Patent number: 7753984
    Abstract: This invention relates to a slow and controlled-release polymeric fertilizer with multiple nutrients having the following general formula: wherein n, m and M are defined in the description. The polymeric fertilizer of this invention is an environment-friendly slow and controlled-release fertilizer. Its slow and controlled release action lies in self-degradation and hydrolysis. This invention also relates to the preparing process for the fertilizer and the use method of the fertilizer in agriculture.
    Type: Grant
    Filed: April 7, 2006
    Date of Patent: July 13, 2010
    Inventors: Yaqing Liu, Guizhe Zhao, Futian Zhu, Xueyi Liu
  • Publication number: 20060260372
    Abstract: This invention relates to a slow and controlled-release polymeric fertilizer with multiple nutrients having the following general formula: wherein n, m and M are defined in the description. The polymeric fertilizer of this invention is an environment-friendly slow and controlled-release fertilizer. Its slow and controlled release action lies in self-degradation and hydrolysis. This invention also relates to the preparing process for the fertilizer and the use method of the fertilizer in agriculture.
    Type: Application
    Filed: April 7, 2006
    Publication date: November 23, 2006
    Inventors: Yaqing Liu, Guizhe Zhao, Futian Zhu, Xueyi Liu