Patents by Inventor Gunter Helling
Gunter Helling has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6080536Abstract: A method has been described of preparing a photosensitive emulsion comprising tabular silver halide grains rich in silver bromide, having {100} major faces and an aspect ratio more than 1.5, wherein at least 50% of the projected area of all grains is provided by said {100} tabular grains, said method comprising the step of running in a reaction vessel an aqueous silver salt solution and an aqueous alkali halide solution rich in alkali bromide, characterized in that before starting running said reaction vessel comprises in an aqueous solution of gelatin an amount of amino-modified polyvinyl alcohol as an aqueous soluble polymer.Type: GrantFiled: March 15, 1999Date of Patent: June 27, 2000Assignee: Agfa-Gevaert, N.V.Inventors: Kathy Elst, Eddy Michiels, Gunter Helling
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Patent number: 6074809Abstract: A color photographic silver halide material having a support, at least one photosensitive silver halide emulsion layer and a polymeric cyan coupler associated with the photosensitive silver halide emulsion layer, which coupler contains polymerised units of the formula (I) ##STR1## in which X means a hydrogen atom or a group eliminable under chromogenic development conditions,R.sub.1 means a hydrogen or halogen atom, an optionally substituted alkyl, aryl or acylamino group,R.sub.2 means an optionally substituted alkyl, aryl or heterocyclic group andn means a number from 0 to 3, is distinguished by improved stability of the cyan dye.Type: GrantFiled: December 9, 1998Date of Patent: June 13, 2000Assignee: Agfa-Gevaert N.V.Inventors: Lydia Simon, Gunter Helling, Beate Weber
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Patent number: 6045988Abstract: A color photographic recording material which contains on a support at least one blue-sensitive silver halide emulsion layer, which is associated with a yellow coupler, at least one green-sensitive silver halide emulsion layer, which is associated with a magenta coupler, and at least one red-sensitive silver halide emulsion layer, which is associated with a cyan coupler, together with non-photosensitive interlayers between the layers of differing color sensitivity, characterised in that at least one green-sensitive silver halide layer contains a 2-equivalent pyrazolone and/or a pyrazolotriazole coupler as the magenta coupler and at least one interlayer adjacent to this layer contains as a DOP scavenger a polyester comprising at least one dicarboxylic acid of the formula I ##STR1## in which L.sub.1, L.sub.2 are optionally substituted, divalent organic residues andR.sub.1, R.sub.Type: GrantFiled: June 11, 1998Date of Patent: April 4, 2000Assignee: Agfa-Gevaert NVInventors: Gunter Helling, Markus Geiger
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Patent number: 5935773Abstract: A colour photographic silver halide material with a support, at last one silver halide emulsion layer containing at least one yellow coupler and at least one silver halide emulsion layer containing a cyan coupler applied thereon, in which material the silver halide emulsion layer, of which there is at least one, containing at least one yellow coupler and/or the silver halide emulsion layer, of which there is at least one, containing at least one cyan coupler contains a compound of the formula (I) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 mean alkyl, alkenyl or acyl andn means 6, 7 or 8,is distinguished by improved stability of the image dyes produced by processing.Type: GrantFiled: April 29, 1996Date of Patent: August 10, 1999Assignee: Agfa-Gevaert AGInventors: Jorg Hagemann, Gunter Helling
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Patent number: 5888719Abstract: A color photographic material with a support and at least one spectrally sensitised silver halide emulsion layer containing at least one color coupler, which layer contains a polymer with repeat units of the structure I ##STR1## in which R.sub.1, R.sub.2, R.sub.3 are identical or different and mean hydrogen, alkyl or halogen,L means a chemical bond or a linking member andX means a group which reacts with NH.sub.2 --, COOH-- or OH-- groups in an addition or condensation reaction,in dispersed form with an average particle size of <300 nm, is distinguished by improved "dark fading" stability.Type: GrantFiled: July 29, 1996Date of Patent: March 30, 1999Assignee: AGFA-Gevaert AGInventor: Gunter Helling
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Patent number: 5795707Abstract: A photographic silver halide material having a support and at least one layer which is deposited thereon and which contains a polypeptide, at least 90 mole % of which consists of structural units of formula I, ##STR1## where R represents OH, NH.sub.2, NHR.sub.1, NR.sub.1 R.sub.2, NH-- or NR.sub.1 --R.sub.1, R.sub.2 represent a hydrocarbon radical, which is optionally substituted,R.sub.4 represents NH or N--, andm represents 0 or 1,wherein the bond between two structural units of formula I is always an --N--C bond and m is equal to 1 in 2 to 35% of the structural units of formula I, is characterised by improved photographic properties.Type: GrantFiled: February 19, 1997Date of Patent: August 18, 1998Assignee: Agfa-GevaertInventors: Klaus Wagner, Gunter Helling, Torsten Groth, Winfried Joentgen
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Patent number: 5731138Abstract: A color photographic material which contains in at least one layer a stabilizer of the formula (I) ##STR1## in which R.sub.1 means H, alkyl, aryl or acyl;R.sub.2 means --OR.sub.1, --COOH, alkyl, aryl, dialkylamino, acylamino, sulphonamido, acyl or sulphonyl;R.sub.3, R.sub.4, R.sub.5 and R.sub.6 independently of one another mean H, halogen or a residue as R.sub.2 or two adjacent residues --OR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 may together complete a 5- to 8-membered ring, and a polymer insoluble in water as pH 5 and soluble at pH 11 with an acid value of 30 to 300 and a Tg of.ltoreq.40.degree. C. of the formula (II) ##STR2## in which R.sub.7 mutually independently mean hydrogen, C.sub.1 -C.sub.4 alkyl or CH.sub.2 --COOH,R.sub.8 means alkyl, aryl or aralkyla means 80 to 95 mol. % andb means 5 to 20 mol. %, is distinguished by improved stability of the image dyes.Type: GrantFiled: January 26, 1996Date of Patent: March 24, 1998Assignee: Agfa-Gevaert AGInventors: Gunter Helling, Beate Weber, Markus Geiger
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Patent number: 5674668Abstract: A color photographic recording material having at least one silver halide emulsion layer, which material contains in at least one of its layers a combination of at least one UV absorber of the formula I and at least one low molecular weight or polymeric oil formula containing acid groups, for example of the formula T--?R.sup.21 --(Q.sup.1).sub.p !.sub.q --X.sup.21 --OH (II), exhibits improved absorption for UV light. ##STR1## In the formula I: R.sup.1 and R.sup.3 mean H, halogen, hydroxy, mercapto, alkyl, aryl, alkoxy, aryloxy, acyloxy, alkylthio, arylthio, --NR.sup.5 --R.sup.6, alkoxycarbonyl, carbamoyl or sulphamoyl;R.sup.2 means H, hydroxy, halogen or alkyl;R.sup.4 means alkyl, alkoxy, alkylthio, aryloxy, arylthio or a residue of the formula ##STR2## R.sup.5 means H, alkyl or aryl; R.sup.6 means H, alkyl, aryl, acyl, alkoxycarbonyl, carbamoyl, sulphamoyl or sulphonyl;m, n and o mean 1, 2, 3 or 4,wherein two or more residues R.sup.1, R.sup.2 and R.sup.3 are identical or different;in the formula II:X.sup.Type: GrantFiled: August 26, 1996Date of Patent: October 7, 1997Assignee: Agfa-GevaertInventors: Jorg Hagemann, Gunter Helling, Beate Weber
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Patent number: 5518877Abstract: Improved photographic properties are obtained if the photographic silver halide material contains a copolymer with polypeptide segments, wherein the polypeptide segments are derived from polypeptides with an average molecular weight M.sub.w of 2000 to 40000.Type: GrantFiled: January 27, 1995Date of Patent: May 21, 1996Assignee: Agfa-Gevaert AGInventors: Gunter Helling, Klaus Wagner
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Patent number: 5508157Abstract: A color photographic silver halide material in which at least one coupler is dissolved or dispersed in a coupler solvent corresponding to the following formula: ##STR1## in which R.sub.1 is alkyl, alkenyl, cycloalkyl or cycloalkenyl,R.sub.2 and R.sub.3 are alkylene or alkenylene,X is CO, NHCO or SO.sub.2,n is 0 or 1 andl, m are numbers of 1 to 5,is distinguished by steep gradation and improved maximum density.Type: GrantFiled: May 30, 1995Date of Patent: April 16, 1996Assignee: Agfa-Gevaert AGInventors: Beate Weber, Markus Geiger, Gunter Helling, Jorg Hagemann
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Patent number: 5472838Abstract: Silver halide emulsions with tabular grains showing increased aspect ratio are produced by adding to the precipitiation vessel a compound of the formula I: ##STR1## in which R.sub.1 means H or optionally substituted alkyl, aralkyl or cycloalkylR.sub.2 means H or optionally substituted alkyl, aryl or aralkyl or a polymer chainR.sub.3 means H, OH, alkyl, aryl, aralkyl, halogen, NHR.sub.4, O--CO--R.sub.4, O--CO--NHR.sub.4 or an optionally substituted oxazoline ringR.sub.4 means optionally substituted or alkyl, aralkyl or arylm means 2 or 3,n means 2 to 10,000,or a compound of the formula II ##STR2## in which R.sub.1, R.sub.3, n and m have the meaning stated above and may be identical or different andR.sub.5 means optionally substituted alkene, arylene, aralkene or a polyaddition, polycondensation or polymerisation chain.Type: GrantFiled: July 11, 1994Date of Patent: December 5, 1995Assignee: Agfa-Gevaert AGInventors: Gunter Helling, Klaus Wagner
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Patent number: 5455154Abstract: A photographic silver halide material which has at least one light-sensitive layer and contains in at least one layer a compound corresponding to formula (I) in a quantity of at least 10 mg/m.sup.2 : ##STR1## wherein k stands for 50 to 99% by weight,l stands for 0 to 49% by weight,m stands for 1 to 40% by weight,j stands for 0 to 49% by weight,M denotes a comonomer incorporated by polymerisation,M.sub.1 denotes ##STR2## M.sub.2 denotes ##STR3## R.sub.1 and R.sub.2 denote hydrogen or alkyl, R.sub.3 denotes an acidic group, andB denotes a chemical bond or a bridging member and which is hardened with a rapid or an instant hardener,is distinguished by improved wet scratch resistance and stability in storage.Type: GrantFiled: May 23, 1994Date of Patent: October 3, 1995Assignee: Agfa Gevaert, AGInventors: Gunter Helling, Jean-Marie Dewanckele
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Patent number: 5441862Abstract: A color photographic recording material with at least one silver halide emulsion layer and a color coupler associated with that layer, which contains in the silver halide emulsion layer or in an adjacent non-photosensitive binder layer a combination of a color coupler and a compound corresponding to general formula (I) or (II): ##STR1## in which R.sub.4 is the residue of a polymer produced by polycondensation andR.sub.1 to R.sub.3, m and n are as defined in the specification, ##STR2## in which R.sub.4 is as defined above and L.sub.1, L.sub.2, X, R.sub.5 to R.sub.11, p, q and r are as defined in the specification,is distinguished by improved stability of the image dyes produced from yellow couplers.Type: GrantFiled: October 27, 1994Date of Patent: August 15, 1995Assignee: Agfa-Gevaert AGInventors: Beate Weber, Gunter Helling, Markus Geiger
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Patent number: 5441861Abstract: A color photographic material with at least one silver halide emulsion layer which contains a color coupler distributed in a polymeric oil former and at least one compound of the formula (I) ##STR1## in which R means alkyl, cycloalkyl, alkenyl, aryl, acyl, alkylsulphonyl or arylsulphonyl,R.sub.1 means a chemical bond or a divalent bridging member,R.sub.2 and R.sub.3 mean alkyl, alkoxy, alkenyl, cycloalkyl, aryl or aryloxy or two residues R.sub.2 or R.sub.3 the remaining atoms of a benzene ring condensed with the phenyl residue andm and n mean 0 to 3, wherein all alkyl, alkoxy, cycloalkyl, alkenyl, aryl, aryloxy and acyl residues may be further substituted,is characterized by improved color stability.Type: GrantFiled: August 26, 1993Date of Patent: August 15, 1995Assignee: Agfa-Gevaert ABInventors: Beate Weber, Gunter Helling, Klaus Walz, Markus Geiger, Kaspar Wingender, Jorg Hagemann
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Patent number: 5441855Abstract: A color photographic material which contains in at least one blue-sensitive layer a yellow coupler and a compound of the formula (I) ##STR1## in which R.sub.1 means hydrogen or alkyl,R.sub.2 means hydrogen or alkyl,R.sub.3 means hydrogen or alkyl,1 means 1 to 20X ##STR2## or cycloalkene, R.sub.4 means hydrogen or alkyl,R.sub.5 means hydrogen or alkyl andn means 1 to 6,shows improved light-stability of the yellow dye obtained from said yellow coupler by exposure and processing.Type: GrantFiled: June 9, 1994Date of Patent: August 15, 1995Assignee: Agfa-Gevaert AGInventors: Beate Weber, Jorg Hagemann, Gunter Helling, Markus Geiger
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Patent number: 5354826Abstract: Polymeric color couplers with repeating units of a polymerized monomer K of formula I ##STR1## with R.sup.1 H or an optionally substituted alkyl group;R.sup.2, R.sup.3, R.sup.4 (identical or different) H, Cl, --COOH or optionally substituted alkyl groups; andX H or a group releaseable by coupling provide, during chromogenic development: magenta dye images with high dye yield and advantageous absorption level.Type: GrantFiled: April 28, 1993Date of Patent: October 11, 1994Assignee: Agfa-Gevaert AGInventors: Gunter Helling, Rainer Bialek, Ralf Weimann
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Patent number: 5340709Abstract: Compounds of Formula I are suitable as light stabilizers for the image dyes produced by chromogenic development from pyrazoloazole couplers ##STR1## In Formula I, R.sup.1 represents H, a group that can be split off under alkaline conditions, alkyl or aryl;R.sup.2 represents --OH, alkyl, aryl, alkoxy or ##STR2## R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent H, --OH, --COOH, --SO.sub.3 H, --SO.sub.2 H, alkyl, aryl, alkoxy, sulphonyl, sulphamoyl, acylamino or ##STR3## at least one of the groups R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 being a group of the formula ##STR4## A represents alkylene with 1-6 C atoms; n represents 0 or 1,R.sup.7 represents H or alkyl, optionally substituted alkyl,R.sup.8 represents optionally substituted alkyl, cycloalkyl or aryl with 4-20 C atoms;R.sup.1 and R.sup.3 can form a 5- or 6-membered ring, in which case R.sup.2 =--OH or alkoy;R.sup.2 and R.sup.4 can form a 5- or 6-membered carbocyclic ring.Type: GrantFiled: March 10, 1993Date of Patent: August 23, 1994Assignee: AGFA-Gevaert AGInventors: Jorg Hagemann, Gunter Helling
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Patent number: 5330886Abstract: A color photographic recording material having a support, at least one light-sensitive silver halide emulsion layer containing a pyrazoloazole magenta coupler, at least one other layer which is arranged closer to the source of light and at least one other layer arranged further away from the source of light than the silver halide emulsion layer containing the pyrazoloazole magenta coupler, these other layers containing gelatine and a randomly or alternatingly structured copolymer of vinyl alcohol and an unsaturated carboxylic acid or a graft polymer of vinyl acetate on polyalkylene oxide followed by saponification of the acetate groups is distinguished by improved stability to light of the magenta dye obtained after processing.Type: GrantFiled: January 27, 1993Date of Patent: July 19, 1994Assignee: AGFA-Gevaert AGInventors: Gunter Helling, Gunter Renner
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Patent number: 5310643Abstract: Compounds corresponding to Formula I are suitable as light stabilizers for the image dyes produced from colour couplers by chromogenic development. They are also suitable as oil formers for the colour couplers. In a colour photographic recording material, they are preferably used in combination with a pyrazoloazole coupler and associated with a light-sensitive silver halide emulsion layer. ##STR1## In Formula I, R.sup.1 denotes H, a group which can be split off under alkaline conditions, alkyl or aryl;R.sup.2 denotes OH, alkyl, aryl, alkoxy or ##STR2## R.sup.3, R.sup.4, R.sup.5 and R.sup.6 denote H, OH, COOH, SO.sub.3 H, SO.sub.2 H, alkyl, aryl, alkoxy, sulphonyl, sulphamoyl, acylamino or ##STR3## and at least one of the groups R.sup.2, R.sup.3, R.sup.4 R.sup.5 and R.sup.6 is a group of the formula ##STR4## A denotes an alkylene group having 1-6 carbon atoms, n stands for 0 or 1,R.sup.7 denotes H or an optionally substituted alkyl group,R.sup.Type: GrantFiled: October 28, 1992Date of Patent: May 10, 1994Assignee: Agfa Gevaert AktiangesellschaftInventors: Gunter Helling, Jorg Hagemann
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Patent number: 5292610Abstract: Microcapsules containing at least one leuco dye, at least one photopolymerisation initiator and at least one photopolymerisable monomer corresponding to the following formulaA[--NHCO--X--L.sub.1 --(OCO--CR.sub.1 =CH.sub.2).sub.1 ].sub.mwhereinA stands for a 3- to 6-valent organic group having the following meanings:a) a saturated hydrocarbon group having 5 to 25 carbon atoms orb) ##STR1## or c) ##STR2## wherein A.sub.1, A.sub.2, R.sub.3, R.sub.4, o and p have the meanings indicated in the description,X denotes O or NR.sub.2,L.sub.1 denotes a divalent or trivalent aliphatic hydrocarbon group whose carbon chain may be interrupted by 1 to 3 oxygen atoms,R.sub.1 denotes hydrogen or methyl,R.sub.2 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl,l denotes 1 or 2 andm denotes a number from 3 to 6,are distinguished by improved sensitivity.Type: GrantFiled: March 6, 1992Date of Patent: March 8, 1994Assignee: AGFA Gevaert AGInventors: Gunter Helling, Michael Muller, Wolfgang Podszun