Patents by Inventor Gunter Rosch
Gunter Rosch has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5080687Abstract: Process for working up regenerated sizes by adding oxidative chlorine-containing compounds, in particular sodium chlorite. These compounds have the effect in the regenerated size of oxidatively brightening the interfering dark-colored impurities.Type: GrantFiled: October 13, 1988Date of Patent: January 14, 1992Assignee: Hoechst AktiengesellschaftInventors: Jorg Langer, Gunter Rosch, Heinz E. Schneider
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Patent number: 4753999Abstract: A textile auxiliary for improving the fastness of materials dyed or printed with a dyestuff is a copolymer of a diallylammonium monomer, a vinyl amide monomer and a (meth)acrylic ester monomer.Type: GrantFiled: January 6, 1987Date of Patent: June 28, 1988Assignee: Cassella AktiengesellschaftInventors: Karl-Heinz Keil, Fritz Engelhardt, Klaus Sternberger, Gunter Rosch
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Patent number: 4595756Abstract: Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion, process for their manufacture and their use.Type: GrantFiled: May 24, 1984Date of Patent: June 17, 1986Assignee: Hoechst AktiengesellschaftInventors: Norbert Schonberger, Erich Schinzel, Thomas Martini, Gunter Rosch
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Patent number: 4539007Abstract: A process for the simultaneous desizing and bleaching of textile material made from cellulose fibers, which comprises treating the textile material with a liquor containing per liter of water(a) from 1 to 10 grams of a peroxide activator,(b) from 10 to 80 ml of hydrogen peroxide,(c) from 1 to 10 grams of urea,(d) from 1 to 10 grams of a surfactant and a compound of weakly alkaline reaction in such an amount that the pH of the liquor is 7 to 8.Type: GrantFiled: May 9, 1983Date of Patent: September 3, 1985Assignee: Hoechst AktiengesellschaftInventors: Gunter Rosch, Gerhard Sauer
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Patent number: 4508900Abstract: Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion,process for their manufacture and their use.Type: GrantFiled: September 13, 1982Date of Patent: April 2, 1985Assignee: Hoechst AktiengesellschaftInventors: Norbert Schonberger, Erich Schinzel, Thomas Martini, Gunter Rosch
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Patent number: 4478737Abstract: Oxidative desizing agent consisting substantially of from 5 to 20 weight % of sodium or ammonium persulfate or potassium, sodium, ammonium or calcium peroxodiphosphate, from 20 to 50 weight % of one or more surfactants selected from the group of C.sub.8 -C.sub.20 -sec.-alkanesulfonates, C.sub.4 -C.sub.12 -alkylphenol-oxethylates having 6 to 12 ethylene oxide moieties, or C.sub.10 -C.sub.18 -fatty alcohol-oxethylates having 3 to 8 ethylene oxide moieties, and water in the amount remaining to give 100%. The advantage of this desizing agent resides in the fact that a substantially smaller amount of persulfate is required than for desizing with persulfate alone. Moreover, this desizing agent is liquid and thus easy to be dosed.Type: GrantFiled: March 24, 1983Date of Patent: October 23, 1984Assignee: Hoechst AktiengesellschaftInventors: Klaus Adrian, Gunter Rosch
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Patent number: 4400294Abstract: Mixtures of optical brighteners consisting of(a) 1 to 99 weight % of one or several compounds of the formula 1 ##STR1## (b) 99 to 1 weight % of one or several compounds of the formula 2 ##STR2## wherein n is 0 or 1,X is oxygen or sulfur,B is a group of the formulae ##STR3## and the other substituents are defined a specified in the description.Type: GrantFiled: November 8, 1982Date of Patent: August 23, 1983Assignee: Hoechst AktiengesellschaftInventors: Thomas Martini, Gunter Rosch
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Patent number: 4363744Abstract: Mixtures of optical brighteners consisting of from (a) 0.98 to 0.50 part by weight of a mixture consisting of from 0.05 to 0.95 part by weight of a brightener of the series of the benzoxazolyl-stilbenes and of from 0.95 to 0.05 part by weight of a brightener of the series of the aryltriazoles and (b) of from 0.02 to 0.5 part by weight of a brightener of the series of the bis-benzoxazolyl-stilbenes or of the bis-benzothiazolyl-stilbenes.Type: GrantFiled: March 2, 1981Date of Patent: December 14, 1982Assignee: Hoechst AktiengesellschaftInventors: Dieter Gunther, Rudiger Erckel, Gunter Rosch, Heinz Probst
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Patent number: 4336155Abstract: Mixtures of optical brighteners consisting of 5 to 95% by weight of a compound of the formula ##STR1## in which A denotes a o- or p-cyanophenyl group, and 95 to 5% by weight of one or more further optical brighteners.Type: GrantFiled: July 16, 1980Date of Patent: June 22, 1982Assignee: Hoechst AktiengesellschaftInventors: Thomas Martini, Rudiger Erckel, Horst Fruhbeis, Gunter Rosch, Heinz Probst
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Patent number: 4330427Abstract: Mixtures of optical brighteners consisting of 5 to 95 parts by weight of a mixture consisting of 0 to 80% by weight of the compound of the formula 1 ##STR1## 20 to 100% by weight of the compound of the formula 2 ##STR2## and 0 to 80% by weight of the compound of the formula 3 ##STR3## and 95 to 5% by weight of one or more other optical brighteners.Type: GrantFiled: July 16, 1980Date of Patent: May 18, 1982Assignee: Hoechst AktiengesellschaftInventors: Thomas Martini, Rudiger Erckel, Horst Fruhbeis, Gunter Rosch, Heinz Probst
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Patent number: 4323675Abstract: Triazolyl stilbene compounds of the formula ##STR1## wherein A is a benzene or naphthalene ring optionally substituted by non-chromophoric substituents and B is a substituted 1,2,4-oxdiazole (3) or 1,3,5-oxdiazole (2) group, as well as a procedure for their manufacture and their use as optical brighteners.Type: GrantFiled: June 25, 1980Date of Patent: April 6, 1982Assignee: Hoechst AktiengesellschaftInventors: Helmut Eckes, Rudiger Erckel, Thomas Martini, Gunter Rosch
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Patent number: 4310665Abstract: Compounds of the formula ##STR1## wherein X is O or S, R.sub.1 and R.sub.2 each are hydrogen, fluorine, chlorine, phenyl, alkyl, alkoxy, dialkylamino, trialkylammonium, acylamino or optionally functionally modified carboxy or sulfo groups, two adjacent radicals R.sub.1 and R.sub.2 optionally forming together a phenylene, a lower alkylene or a 1,3-dioxapropylene group; and A is a group of the formulae ##STR2## in which R.sub.3 is an alpha-, beta- or gamma-pyridyl, pyridyl-methylene, thiophenyl, furanyl, benzofuranyl, pyrazinyl, pyrimidinyl or pyridazinyl group. These compounds, which are suitable as optical brighteners, are prepared by reaction of a compound of the formula ##STR3## with a compound of the formulaR.sub.3 --Zwherein Y is a ##STR4## group and Z is --COCl or vice versa.Type: GrantFiled: September 26, 1980Date of Patent: January 12, 1982Assignee: Hoechst AktiengesellschaftInventors: Rudiger Erckel, Gunter Rosch
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Patent number: 4309298Abstract: Novel oxidative desizing agent consisting essentially of from 10 to 80, preferably 50 to 80% by weight of a surfactant and from 20 to 90, preferably 20 to 50% by weight of potassium persulfate. This desizing agent may optionally also contain from 5 to 25% by weight of a solubilizer with a simultaneous reduction of the surfactant and persulfate portions.Type: GrantFiled: March 28, 1980Date of Patent: January 5, 1982Assignee: Hoechst AktiengesellschaftInventors: Klaus Adrian, Gunter Rosch
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Patent number: 4309551Abstract: Compounds of the general formula (1) ##STR1## wherein R.sub.1 denotes hydrogen, halogen, alkyl, alkoxy or, conjointly with R.sub.2, a fused benzo ring, R.sub.2 denotes hydrogen, alkyl, alkoxy, halogen, phenyl, cyano, carboalkoxy, carboxyl, carbonamido, monoalkylcarbonamido, dialkylcarbonamido, sulfo, alkylsulfonyl, alkyloxysulfonyl, sulfonamido, monoalkylsulfonamido or dialkylsulfonamido or, conjointly with R.sub.3, a fused benzo ring, R.sub.3 has the same meaning as R.sub.2, R.sub.4 denotes hydrogen, alkyl, alkoxy, halogen or, conjointly with R.sub.3, a fused benzo ring, R.sub.5 denotes alkyl, hydroxyalkyl, alkoxyalkyl, optionally substituted aralkyl, cyanoethyl, cycloalkyl or a group of the formulae --CH.sub.2 CN, --CH.sub.2 CONH.sub.2 or --CH.sub.2 COO--alkyl, A denotes a group of the formulae ##STR2## or--(CH.sub.2).sub.4 --R.sub.6 denotes hydrogen, alkyl, hydroxyalkyl, alkoxyalkyl, aralkyl or optionally substituted phenyl, n denotes 1, 2 or 3 and X.sup.Type: GrantFiled: September 29, 1980Date of Patent: January 5, 1982Assignee: Hoechst AktiengesellschaftInventors: Norbert Schonberger, Erich Schinzel, Thomas Martini, Gunter Rosch
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Patent number: 4263176Abstract: Brighteners for detergents consisting of a mixture of 4,4'-bis-(2-morpholino-4-anilino-1,3,5-triazinylamino)-stilbene-2,2'-disul fonic acid-di-Na salt and from 5 to 50% by weight, calculated on said brightener, of another brightener of the formula ##STR1## in the above formula, M is an alkali metal cation, preferably sodium, X is a group of the formula --COR.sub.2 or --SO.sub.2 R.sub.3, R.sub.2 being C.sub.1 -C.sub.8 -alkyl and R.sub.3 being C.sub.1 -C.sub.5 -alkyl, C.sub.4 -C.sub.8 -cycloalkyl, phenyl or toluyl, Y is hydrogen or C.sub.1 -C.sub.5 -alkyl, A is C.sub.3 -C.sub.6 -alkylene, R.sub.1 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.4 -C.sub.8 -cycloalkyl, or a group of the formula ##STR2## and Z is an anilino group, a chloroanilino group or a morpholino group. Said brightener mixtures are color-stable and do not show any green discoloration even after a prolonged storage in a moist atmosphere.Type: GrantFiled: November 16, 1979Date of Patent: April 21, 1981Assignee: Hoechst AktiengesellschaftInventors: Thomas Martini, Helmut Mengler, Gunter Rosch, Gunter Hohlfeld
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Patent number: 4263441Abstract: Compounds of the general formula ##STR1## in which X represents a trifluoromethyl group or a fluorine atom, n is 1 or 2, Z is an oxygen atom or a NR grouping, in which R is hydrogen or an optionally substituted alkyl group, the benzo rings optionally containing further nonchromophoric substituents. These compounds may be prepared by reacting the dichloride of 1,4-naphthalene-dicarboxylic acid with 2 mols of an o-aminophenol or of an o-nitroaniline and by subsequently cyclizing the acylamino compound obtained. The products are suitable as optical brighteners.Type: GrantFiled: November 13, 1978Date of Patent: April 21, 1981Assignee: Hoechst AktiengesellschaftInventors: Ulrich Pintschovius, Erich Schinzel, Gunter Rosch
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Patent number: 4246403Abstract: Novel 1,3,4-oxadiazolone-(2) compounds of the formula ##STR1## wherein Y denotes carboxy optionally functionally modified or optionally substituted phenyl or a five-membered heterocycle optionally substituted and selected from the group consisting of: furan, thiophen, oxazole, imidazole, oxadiazole, oxadiazolone, triazole, benzofuran, thionaphthalene, benzoxazole, benzimidazole, and benzotriazole, R denotes hydrogen, alkyl or optionally substituted phenyl, n denotes 0 and 1 and the rings A and B carry optionally further non-chromophoric substituents. These compounds may be used as optical brighteners.Type: GrantFiled: July 25, 1979Date of Patent: January 20, 1981Assignee: Hoechst AktiengesellschaftInventors: Gunter Prossel, Erich Schinzel, Norbert Schonberger, Thomas Martini, Gunter Rosch
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Patent number: 4231741Abstract: Mixture of optical brighteners consisting of from 0.5 to 0.95 part by weight of a brightener of the series of the benzoxazolyl-stilbenes and of from 0.95 to 0.05 part by weight of a brightener of the series of the aryltriazoles.Type: GrantFiled: December 21, 1978Date of Patent: November 4, 1980Assignee: Hoechst AktiengesellschaftInventors: Dieter Gunther, Rudiger Erckel, Gunter Rosch, Heinz Probst
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Patent number: 4197401Abstract: Compounds of the formula I ##STR1## in which X is O or S, R.sub.1 and R.sub.2, being identical or different, are radicals selected from the group of hydrogen, fluorine or chlorine atoms, phenyl, C.sub.1 -C.sub.9 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -dialkyl-amino, acylamino radicals, or optionally functionally modified carboxy or sulfo groups, two adjacent radicals R.sub.1 and R.sub.2 together optionally representing a benzo ring, a lower alkylene or a 1,3-dioxapropylene group, and A is a group of the formulae ##STR2## in which R.sub.3 and R.sub.4, independently from each other, are hydrogen, fluorine or chlorine atoms or C.sub.1 -C.sub.4 -alkyl groups.Type: GrantFiled: March 20, 1978Date of Patent: April 8, 1980Assignee: Hoechst AktiengesellschaftInventors: Dieter Gunther, Rudiger Erckel, Gunter Rosch
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Patent number: 4169810Abstract: A mixture of optical brighteners containing 0.05 to 0.95 part by weight of a compound from the benzoxazolyl- or benzothiazolylstilbene series and 0.95 to 0.05 part by weight of a compound of the bis-benzoxazolyl- or bis-benzothiazolylstilbene series or of the benzoxazolyl- or benzothiazolyl-stilbene oxazolo[5,4-6]pyridinyl or oxazolo[2,3-b]pyridinyl series. These mixtures show an enhanced degree of whiteness as compared to the same amount of the single components.Type: GrantFiled: May 8, 1978Date of Patent: October 2, 1979Assignee: Hoechst AktiengesellschaftInventors: Dieter Gunther, Rudiger Erckel, Gunter Rosch, Heinz Probst