Abstract: Provided herein is a method of producing cathode materials. The method can include heating precursors in a first vessel to a first temperature to form heated precursors. The first temperature can be below a melting point of a solid including a compound formed from the precursors. The method can include transferring the heated precursors from the first vessel to a second vessel. The method can include heating the heated precursors to a second temperature to form a liquid. The second temperature can be at or above the melting point of the solid including the compound formed from the precursors.

Abstract: Described are embodiments of a lithium metal phosphate production methods and systems. The systems and methods can include combining lithium extraction from spodumene, lithium recycling from lithium ion battery (“LIB”) black mass, and/or lithium metal phosphate synthesis from metal phosphates.

Abstract: Described are embodiments of a lithium metal phosphate production methods and systems. The systems and methods can include combining lithium extraction from spodumene, lithium recycling from lithium ion battery (“LIB”) black mass, and/or lithium metal phosphate synthesis from metal phosphates.

Abstract: A Lithium-transition-metal-phosphate compound of formula Li0.9+xFe1-yMyPO4) in the form of secondary particles made of agglomerates of spherical primary particles wherein the primary particles have a size in the range of 0.02-2 pm and the secondary particles a mean size in the range of 10-40 pm and a BET surface of 16-40 m2/g, a process for its manufacture and the use thereof.

Abstract: There is provided a process for producing LiMXO4, comprising the steps of reacting a source of lithium, a source of M, and a source of X together, in a melted state at a reaction temperature between 900 to 1450 C, in the presence of an excess of (A) a solid-solid reducing couple having an oxygen partial process at equilibrium (pO2) comprised between 10?8 and 10?15 atm at said reaction temperature according to an Ellingham-Richardson diagram for oxides, or (B) one component of the solid-solid reducing couple together with a gas-gas reducing couple having an oxygen partial pressure equilibrium (pO2) between 10?8 and 10?15 atm at said reaction temperature according to an Ellingham-Richardson diagram of oxides, and under thermic equilibrium and thermodynamic equilibrium. There is also provided a LiMXO4 melt-solidified product free from off-composition impurities.

Abstract: A method for preparing an electrode material, said material comprising complex oxide particles having a non-powdery conductive carbon deposit on at least part of their surface, said method comprising: grinding into nanometer size complex oxide particles or particles of complex oxide precursors, wherein the grinding is performed in a bead mill on particles dispersed in a carrier solvent, adding an organic carbon precursor to the oxide particles or oxide precursor particles before, during or after said grinding, and pyrolysing the mixture thus obtained, selecting the size of the particles to grind, the size of the beads used to grind, and the size of the resulting particles such that: 0.004<MS(SP)/MS(B)<0.12 and 0.0025<MS(FP)/MS(SP)<0.25, wherein MS(SP) represents the mean size diameter of the particles before grinding, MS(FP) represents the mean size diameter of the particles after grinding, and MS(B) is the mean size diameter of the beads.

Abstract: There is provided a process for preparing a crystalline electrode material, the process comprising: providing a liquid bath comprising the electrode material in a melted state; and introducing a precursor of the electrode material into the liquid bath, wherein the electrode material comprises lithium, a metal and phosphate. There is also provided a crystalline electrode material, comprising lithium substituted by less than 0.1 atomic of Na or K; Fe and/or Mn, substituted by less than 0.1 atomic ratio of: (a) Mg, Ca, Al and B, (b) Nb, Zr, Mo, V and Cr, (c) Fe(III), or (d) any combinations thereof; and PO4, substituted by less than 20% atomic weight of an oxyanion selected from SO4, SiO4, BO4, P2O7, and any combinations thereof, the material being in the form of particles having a non-carbon and non-olivine phase on at least a portion of the surface thereof.

Abstract: An alkali metal oxyanion cathode material comprising particles, where the particles carry, on at least a portion of the particle surface, carbon deposit by pyrolysis is described. The particles have the general formula A:M:M?:XO4 where the average valency of M is +2 or greater; A is at least one alkali metal selected from Li, Na and K; M is at least Fe and/or Mn; and M? is a metal of valency of 2+ or more.

Abstract: There is provided a process for producing LiMXO4, comprising the steps of reacting a source of lithium, a source of M, and a source of X together, in a melted state at a reaction temperature between 900 to 1450 C, in the presence of an excess of (A) a solid-solid reducing couple having an oxygen partial process at equilibrium (pO2) comprised between 10?8 and 10?15 atm at said reaction temperature according to an Ellingham-Richardson diagram for oxides, or (B) one component of the solid-solid reducing couple together with a gas-gas reducing couple having an oxygen partial pressure equilibrium (pO2) between 10?8 and 10?15 atm at said reaction temperature according to an Ellingham-Richardson diagram of oxides, and under thermic equilibrium and thermodynamic equilibrium. There is also provided a LiMXO4 melt-solidified product free from off-composition impurities.

Abstract: The present invention relates to a process for the synthesis of a carbon-deposited alkali metal oxyanion cathode material comprising particles, wherein said particles carry, on at least a portion of the particle surface, carbon deposited by pyrolysis, said process comprising a dry high-energy milling step performed on precursors of said carbon-deposited alkali metal oxyanion prior to a solid-state thermal reaction.

Abstract: The invention relates to a process for the preparation of a carbon-treated complex oxide having a very low water content and to its use as cathode material. The carbon-treated complex oxide is composed of particles of a compound AMXO4 having an olivine structure which carry, on at least a portion of their surface, a film of carbon deposited by pyrolysis. A represents Li, alone or partially replaced by at most 10% as atoms of Na or K. M represents Fe(II), alone or partially replaced by at most 50% as atoms of one or more other metals chosen from Mn, Ni and Co, and/or by at most 10% as atoms of one or more aliovalent or isovalent metals other than Mn, Ni or Co, and/or by at most 5% as atoms of Fe(III). X4 represents PO4, alone or partially replaced by at most 10 mol % of SO4 and SiO4. Said material has a water content <1000 ppm.

Abstract: A material C-AxM(XO4)y that is of particles of a compound of the formula AxM(XO4)y, wherein said particles include a carbon deposit deposited by means of pyrolysis on at least a portion of the surface thereof, and where: A is Li alone or partially replaced by at most 10 atomic % of Na or K; M is Fe(II), or Mn(II), or mixtures thereof alone or partially replaced by at most 30 atomic % of one or more metals selected from Mn, Ni and Co and/or at most 5% of Fe(III); XO4 is PO4 alone or partially replaced by at most 10 molar % of at least one group selected from SO4, SiO4 and MoO4; and where said material has a calcium impurity content of lower than about 1000 ppm.

Abstract: An alkali metal oxyanion cathode material comprising particles, where the particles carry, on at least a portion of the particle surface, carbon deposit by pyrolysis is described. The particles have the general formula A: M:M?:X04 where the average valency of M is ?2 or greater; A is at least one alkali metal selected from Li, Na and K; M is at least Fe and/or Mn; and M? is a metal of valency of 2+ or more.

Abstract: A Lithium-transition-metal-phosphate compound of formula Li0.9+xFe1-yMyPO4) in the form of secondary particles made of agglomerates of spherical primary particles wherein the primary particles have a size in the range of 0.02-2 pm and the secondary particles a mean size in the range of 10-40 pm and a BET surface of 16-40 m2/g, a process for its manufacture and the use thereof.

Abstract: The present invention relates to a nanoparticulate composition comprising nanoparticles with a particle-size distribution of d90?10 ?m, and optionally a surface-active agent. The present invention further relates to a method for the production of such a nanoparticulate composition.

Abstract: A method for preparing an electrode material, said material comprising complex oxide particles having a non-powdery conductive carbon deposit on at least part of their surface, said method comprising: grinding into nanometer size complex oxide particles or particles of complex oxide precursors, wherein the grinding is performed in a bead mill on particles dispersed in a carrier solvent, adding an organic carbon precursor to the oxide particles or oxide precursor particles before, during or after said grinding, and pyrolysing the mixture thus obtained, selecting the size of the particles to grind, the size of the beads used to grind, and the size of the resulting particles such that: 0.004 <MS(SP)/MS(B)<0.12 and 0.0025<MS(FP)/MS(SP)<0.25, wherein MS(SP) represents the mean size diameter of the particles before grinding, MS(FP) represents the mean size diameter of the particles after grinding, and MS(B) is the mean size diameter of the beads.

Abstract: There is provided a process for preparing a crystalline electrode material, the process comprising: providing a liquid bath comprising the electrode material in a melted state; and introducing a precursor of the electrode material into the liquid bath, wherein the electrode material comprises lithium, a metal and phosphate. There is also provided a crystalline electrode material, comprising lithium substituted by less than 0.1 atomic of Na or K; Fe and/or Mn, substituted by less than 0.1 atomic ratio of: (a) Mg, Ca, Al and B, (b) Nb, Zr, Mo, V and Cr, (c) Fe(III), or (d) any combinations thereof; and PO4, substituted by less than 20% atomic weight of an oxyanion selected from SO4, SiO4, BO4, P2O7, and any combinations thereof, the material being in the form of particles having a non-carbon and non-olivine phase on at least a portion of the surface thereof.

Abstract: The present invention relates to a process for the synthesis of a carbon-deposited alkali metal oxyanion cathode material comprising particles, wherein said particles carry, on at least a portion of the particle surface, carbon deposited by pyrolysis, said process comprising a dry high-energy milling step performed on precursors of said carbon-deposited alkali metal oxyanion prior to a solid-state thermal reaction.

Abstract: An alkali metal oxyanion cathode material comprising particles, where the particles carry, on at least a portion of the particle surface, carbon deposit by pyrolysis is described. The particles have the general formula A:M:M?:XO4 where the average valency of M is +2 or greater; A is at least one alkali metal selected from Li, Na and K; M is at least Fe and/or Mn; and M? is a metal of valency of 2+ or more.

Abstract: The present invention relates to a process for making an alkali metal oxyanion comprising iron. In one aspect of the invention, hydrothermal methods are used with a nanoscale iron precursor in order to provide desirably low particle size and high purity and crystallinity.