Patents by Inventor Guy Rabilloud

Guy Rabilloud has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5104968
    Abstract: Polyimide precursor compositions incorporating at least one compound of fula (1), at least one compound of formula (2), at least one compound of formula (3) and at least one compound of formula (4) ##STR1## in which one of the groups R.sup.3 and R.sup.4 represents a hydrogen atom and the other, in the same way as the groups R.sup.1 and R.sup.2, which can be the same or different, in each case represent a hydrocarbon group having 1 to 16 carbon atoms, m is a number between 5 and 20, n is an integer between 1 and 5 and R.sup.5 represents a hydrogen atom, a halogen atom, a hydrocarbon group with 1 to 16 carbon atoms, or a group of formula R.sup.6 --O-- in which R.sup.6 represents a hydrocarbon group having 1 to 16 carbon atoms. The preferred composition contains 30 to 70% by weight of dry matter of compounds of formulas (1), (2) and (3), in which the groups R.sup.1, R.sup.2 and one of the groups R.sup.3 and R.sup.4 is a methyl or ethyl group and the compound of formula (4) is benzyl alcohol.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: April 14, 1992
    Assignee: Centre d'Etude des Materiaux Organiques pour Technologies Avancees
    Inventors: Serge Gonzalez, Paul Mariaggi, Guy Rabilloud, Bernard Sillion
  • Patent number: 5093202
    Abstract: Adhesive compositions are described comprising at least an arylaliphatic olyimide with ether chain formations, obtained by the polycondensation reaction of a tetracarboxylic aromatic acid or of one of its derivatives with at least two primary diamines, one of these diamines consisting of a polyether chain ending with the two amine functional groups and at least an epoxy resin possessing more than one epoxy group per molecular.These adhesive compositions can be used particularly for the gluing of films of polymers to thin metal sheets.
    Type: Grant
    Filed: August 2, 1990
    Date of Patent: March 3, 1992
    Assignee: Centre d'Etude des Materiaux Organiques pour Technologies Avancees
    Inventors: Paul Mariaggi, Serge Gonzalez, Guy Rabilloud, Bernard Sillion
  • Patent number: 5036111
    Abstract: Expanded material obtained by heating a composition comprising at least one hermosetting nadimide resin, said heating being performed at a temperature and during a period which are sufficient to cause the expansion of said composition by release of cyclopentadiene. A nadimide resin of the polyimide type and having a number average molecular weight of 600 to 10,000 is preferably used. The composition further comprises preferably 1% to 50% by weight of a linear, preferably thermostable polymer.
    Type: Grant
    Filed: October 17, 1990
    Date of Patent: July 30, 1991
    Assignee: Centre D'Etude des Materiaux Organiques pour Technologies Avancees
    Inventors: Michel Senneron, Gilbert Parrain, Guy Rabilloud, Bernard Sillion
  • Patent number: 4987218
    Abstract: Polymer compositions comprising poly(benzhydrolimide) chains ending with ethylenic unsaturated groups complying with the general formula: ##STR1## wherein Ar is a divalent aromatic radical and R a hydrogen atom or a monovalent hydrocarbon radical. They can be prepared by reacting, under imidation condition, at least one primary diamine with at least one benzydrol 3,3', 4,4'-tetracarboxylic acid, a bis (ortho-acid-ester) or a tetraester of such acid and with an anhydride, an acid-ester or a diester of dicarboxylic cycloaliphatic acid with ethylenic unsaturation. These compositions may be converted to cross-linked polymides by thermal polyemrization. They can be used in particular for manufacturing composite materials, adhesives, molded articles and protective coatings withstanding high temperatures.
    Type: Grant
    Filed: May 29, 1987
    Date of Patent: January 22, 1991
    Assignee: Centre d'Etude des Materiaux Organiques pour Technologies Avances (Cemota)
    Inventors: Jean Malinge, Guy Rabilloud, Bernard Sillion
  • Patent number: 4814403
    Abstract: Oligomer compositions of polyaryloxypyridine with acetylenic end groups are btained by formation of an oligomer composition of polyaryloxypyridine with halogenated end groups from an alkaline diphenolate and a dihalogenopyridine, followed with an ethynylation reaction. The average polycondensation degree may range from 1 to 50. Theses compositions can be used to form cross-linked lattices by polyaddition of the ethynyl groups.
    Type: Grant
    Filed: October 8, 1987
    Date of Patent: March 21, 1989
    Assignee: Centre d'Etude des Materiaux Organiques pour Technologies Avancees
    Inventors: Annie Dussart-Lermusiaux, Michel Senneron, Guy Rabilloud, Bernard Sillion
  • Patent number: 4764578
    Abstract: The disclosed compositions of polyaryloxypyridine oligomers with phthalonile end groups are obtained by formation of a composition of polyaryloxypyridine oligomers with alkali phenolate end groups, followed with the reaction of said composition with 4-nitrophthalonitrile. Their average polycondensation degree may range from 1 to 50. They can be used in combination with a co-reactant derived from benzhydrol and containing one or two ortho-dinitrile functional groups, to constitute polyaryloxypyridine co-polyphthalocyanine lattices.
    Type: Grant
    Filed: September 16, 1986
    Date of Patent: August 16, 1988
    Assignee: Centre d'Etude des Materiaux Organiques pour Technologies Avancees
    Inventors: Jean Malinge, Guy Rabilloud, Bernard Sillion
  • Patent number: 4736015
    Abstract: Aromatic polyimide compositions, useful in particular for manufacturing adhesive materials, varnishes and films withstanding high temperatures, having a high solubility in organic solvents, particularly polar solvents and which are manufactured by reacting, in such a solvent, a tetraester or diacid-diester of benzhydrol 3,3', 4, 4' tetracarboxylic acid with an aromatic diamine for a sufficient time to obtain a polycondensation reaction product having an inherent viscosity at 30.degree. C., at a concentration of 5 g/liter in N-methyl pyrrolidone, ranging from 0.1 to 2 dl/g.
    Type: Grant
    Filed: October 19, 1982
    Date of Patent: April 5, 1988
    Assignee: Institut Francais du Petrole
    Inventors: Guy Rabilloud, Michel Senneron, Choua Cohen, Paul Mariaggi, Bernard Sillion
  • Patent number: 4720539
    Abstract: Polyimide precursor compositions are described which may be prepared by rting a biprimary aromatic diamine with a diester-diacid or an aromatic tetraacid, and then with the substantially stoichiometrical complement of an aromatic dianhydride.The polyimide precursor compositions are used in the manufacture of insulating coatings, films, impregnating or enamelling varnishes for electric wires etc., and have excellent qualities of flexibility, adhesiveness and heat resistance.
    Type: Grant
    Filed: September 10, 1986
    Date of Patent: January 19, 1988
    Assignee: Centre d'Etudes des Materiaux Organiques pour Technologies Avancees
    Inventors: Guy Rabilloud, Paul Marriagi, Serge Gonzales, Bernard Sillion
  • Patent number: 4645821
    Abstract: Aromatic polyimide compositions, precursors of copolyphthalocyanine-imides, heir manufacturing process and the resultant copolyphthalocyanine-imides, are described.These compositions may result for the reaction of 80.degree.-300.degree. C. of an aromatic tetra acid, diester-diacid, tetraester or dianhydride compound of formula: ##STR1## with an aromatic amino-dinitrile ##STR2## and optionally an aromatic diamine NH.sub.2 --Ar--NH.sub.2. A subsequent heating at 200.degree.-300.degree. C. provides, by cross-linking, copolyphthalocyanine-imides, which are hardened resins, stable at 250.degree.-300.degree. C. in continuous use.
    Type: Grant
    Filed: July 25, 1985
    Date of Patent: February 24, 1987
    Assignee: Centre d'Etude des Materiaux Organiques pour Technologies Avancees
    Inventors: Jean Malinge, Guy Rabilloud, Bernard Sillion
  • Patent number: 4310699
    Abstract: Bis (phenylglyoxyloyl) benzenes are manufactured by a method comprising the reaction of terephthalic or isophthalic aldehyde first with a low proportion of an alkali metal cyanide in a solvent, and then with benzaldehyde; the resultant product is oxidized to the desired bis (phenylglyoxyloyl) benzene.
    Type: Grant
    Filed: May 23, 1980
    Date of Patent: January 12, 1982
    Assignee: Institut Francais du Petrole
    Inventors: Guy Rabilloud, Bernard Sillion
  • Patent number: 4304898
    Abstract: Enameling varnishes are made from particular polyarylquinoxaline resins; these resins comprise, in addition to arylquinoxaline groups, biphenylene or biquinoxalylene groups and their inherent viscosity at 30.degree. C. and 0.5 g/dl concentration in m-cresol is from 0.5 to 1.3 dl/g.
    Type: Grant
    Filed: January 18, 1980
    Date of Patent: December 8, 1981
    Assignee: Institut Francais du Petrole
    Inventors: Guy Rabilloud, Bernard Sillion
  • Patent number: 4202960
    Abstract: Thermostable, infusible and insoluble polymer obtained by thermosetting aromatic oligomers of low molecular weight in the presence of an acid catalyst, said aromatic oligomers having an average molecular weight up to about 5000, a softening temperature from 80.degree. to 400.degree. C. and being obtained by separation from the reaction mixture produced by reacting meta-terphenyl with acetyl chloride and aluminum chloride.
    Type: Grant
    Filed: September 16, 1977
    Date of Patent: May 13, 1980
    Assignee: Institut Francais du Petrole
    Inventors: Guy Rabilloud, Bernard Masson, Pierre Giuliani, Bernard Sillion
  • Patent number: 4147728
    Abstract: New tetracarbonyl compounds of the formulae: ##STR1## where R is a hydrogen atom, an alkyl radical or an aryl radical. The invention also contemplates the thermostable polymers obtained by reacting an aromatic tetra-amine with at least one of the above tetracarbonyl compounds.
    Type: Grant
    Filed: December 18, 1974
    Date of Patent: April 3, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Guy Rabilloud, Bernard Sillion
  • Patent number: 4143077
    Abstract: New aromatic compounds with ether functions particularly useful as power transmission fluids and as lubricants withstanding high temperatures, containing at least a major proportion of a compound of the formula: ##STR1## WHEREIN EACH Ar is selected from phenyl and metaphenoxy phenyl and optionally a minor proportion of at least one compound selected from those complying with the general formulas: ##STR2## WHEREIN Ar is defined as above.
    Type: Grant
    Filed: September 8, 1977
    Date of Patent: March 6, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Bernard Masson, Guy Rabilloud, Bernard Sillion
  • Patent number: 4064176
    Abstract: New tetracarbonyl compounds of the formula ##STR1## where R is a hydrogen atom, an alkyl radical or an aryl radical. The invention also contemplates the thermostable polymers obtained by reacting an aromatic tetra-amine with at least one of the above tetracarbonyl compounds.
    Type: Grant
    Filed: December 23, 1975
    Date of Patent: December 20, 1977
    Assignee: Institut Francais du Petrole
    Inventors: Guy Rabilloud, Bernard Sillion
  • Patent number: 4045414
    Abstract: New tetracarbonyl compounds of the formulae: ##STR1## where R is a hydrogen atom, an alkyl radical or an aryl radical. The invention also contemplates the thermostable polymers obtained by reacting an aromatic tetra-amine with at least one of the above tetracarbonyl compounds.
    Type: Grant
    Filed: December 23, 1975
    Date of Patent: August 30, 1977
    Assignee: Institut Francais du Petrole
    Inventors: Guy Rabilloud, Bernard Sillion
  • Patent number: 3968085
    Abstract: The invention concerns new aromatic polyamine compositions useful as hardening agents containing a major proportion of polyamines of the formula: ##EQU1## IN WHICH Ar and Ar' are divalent aromatic radicals having from 1 to 6 rings, R.sub.1 is a divalent hydrocarbon radical or a radical (R.sub.4 -O).sub.m R.sub.4, R.sub.4 being an alkylene and m an integer from 1 to 100.
    Type: Grant
    Filed: August 29, 1974
    Date of Patent: July 6, 1976
    Assignee: Institut Francais du Petrole, des Carburants et Lubrifiants
    Inventors: Guy Rabilloud, Bernard Sillion