Patents by Inventor Hachirou Hirano

Hachirou Hirano has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8236268
    Abstract: A process for producing sodium hydrogencarbonate crystal particles having a low caking property, which entails subjecting sodium hydrogencarbonate crystal particles having an average particle size of from 50 to 500 ?m based on the mass to heat treatment at a temperature of from 70 to 95° C. by a heating gas having a carbon dioxide gas concentration of at most the concentration calculated by the formula: Carbon dioxide gas concentration=0.071×e(0.1×T)×R(?0.0005×T?0.9574), where T (° C.) is the temperature of sodium hydrogencarbonate crystals, and R (%) is the relative humidity around the crystals at the temperature of the crystals, provided that the upper limit of the carbon dioxide gas concentration is 100 vol % to form anhydrous sodium carbonate on the surface of the sodium hydrogencarbonate crystal particles with a content of anhydrous sodium carbonate of from 0.03 to 0.4 mass % in the sodium hydrogencarbonate crystals.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: August 7, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Hachirou Hirano, Takako Hirano, legal representative, Shintaro Kikuchi, Fumiaki Nakashima, Hisakazu Arima, Shigeru Sakurai
  • Patent number: 7485369
    Abstract: Sodium hydrogencarbonate crystal particles, which comprise sodium hydrogencarbonate crystal particles having an average particle size of from 50 to 500 ?m based on the mass, and anhydrous sodium carbonate, and sodium carbonate monohydrate and/or Wegscheider's salt, present on the surface of the sodium hydrogencarbonate crystal particles in such amounts that the total content of anhydrous sodium carbonate, sodium carbonate monohydrate, Wegscheider's salt and sodium sesquicarbonate in the sodium hydrogencarbonate crystal particles is from 0.04 to 1 mass % as calculated as anhydrous sodium carbonate, anhydrous sodium carbonate accounts for at least 40 mass % of the total content, and sodium carbonate monohydrate and/or Wegscheider's salt accounts for from 5 to 60 mass % of the total content. Sodium hydrogencarbonate crystal particles having a low caking property, which are useful in the field of food products, pharmaceuticals, bath additives, etc.
    Type: Grant
    Filed: January 3, 2007
    Date of Patent: February 3, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Takako Hirano, legal representative, Shintaro Kikuchi, Fumiaki Nakashima, Hisakazu Arima, Shigeru Sakurai, Hachirou Hirano
  • Publication number: 20090016949
    Abstract: Sodium hydrogencarbonate crystal particles excellent in anti-caking property and anti-thermal decomposition property, and its production process, are provided. Sodium hydrogencarbonate crystal particles whose color 1 second after dropping of a phenolphthalein solution having a predetermined composition, is R=245 to 255, G=243 to 255 and B=245 to 255 in RGB 256 tone notation. The sodium hydrogencarbonate crystal particles are produced by subjecting sodium hydrogencarbonate crystal particles to a bicarbonation treatment in a humidified carbon dioxide gas atmosphere.
    Type: Application
    Filed: September 12, 2008
    Publication date: January 15, 2009
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Hachirou Hirano, Takako Hirano, Hisakazu Arima, Shintaro Kikuchi, Fumiaki Nakashima, Shigeru Sakurai
  • Publication number: 20070253879
    Abstract: To provide a method for removing a halogen series gas, which has high capability of treating a halogen series gas, can prevent ignition of an adsorbing agent, is free from formation of carbon dioxide and can reduce generation of wastes, and a removing agent to be used for the method. The method for removing a halogen series gas comprises bringing a gas comprising at least one halogen series gas selected from the group consisting of F2, Cl2, Br2, I2 and a compound which undergoes hydrolysis to form a hydrogen halide or hypohalogenous acid into contact with a granulated product comprising from 80 to 99.9 mass % of an alkali metal base and from 0.1 to 20 mass % of a thiosulfate based on the total mass of the granulated product, in the presence of water, to remove the halogen series gas.
    Type: Application
    Filed: June 13, 2007
    Publication date: November 1, 2007
    Applicant: Asahi Glass Company, Limited
    Inventors: Shigeru SAKURAI, Hachirou Hirano, Takako Hirano, Hisakazu Arima
  • Publication number: 20070178037
    Abstract: A process for producing sodium hydrogencarbonate crystals, which comprise subjecting sodium hydrogencarbonate crystal powder having an average particle size of from 50 to 500 ?m based on the mass to heat treatment at a temperature of from 70 to 95° C. by a heating gas having a carbon dioxide gas concentration of at most the concentration calculated by the following formula (1): Carbon dioxide gas concentration=0.07l×e(0.1×T)×R(?0.0005×T?0.9574)??(1) (wherein T is the temperature (%) of sodium hydrogencarbonate crystals, and R is the relative humidity (%), provided that the upper limit of the carbon dioxide gas concentration is 100 vol %) with reference to the graph of FIG. 1 wherein the horizontal axis (X-axis) represents the relative humidity and the vertical axis (Y-axis) represents the carbon dioxide gas concentration, to form anhydrous sodium carbonate on the surface of the sodium hydrogencarbonate crystal particles with a content of anhydrous sodium carbonate of from 0.03 to 0.
    Type: Application
    Filed: December 27, 2006
    Publication date: August 2, 2007
    Applicant: ASAHI GLASS CO., LTD.
    Inventors: Hachirou Hirano, Takako Hirano, Shintaro Kikuchi, Fumiaki Nakashima, Hisakazu Arima, Shigeru Sakurai
  • Publication number: 20070105226
    Abstract: A method for evaluating the caking property of sodium hydrogencarbonate crystal particles, characterized in that sodium hydrogencarbonate crystal particles are hermetically sealed in a packaging material having a water vapor transmission rate of at least 3 g/(m2·24h) (at 40° C. with a relative humidity difference of 90%) as stipulated in JIS K7129 and left at rest at a temperature of from 17 to 35° C. at a carbon dioxide gas concentration of from 0.03 to 0.05 vol % at a relative humidity of from 40 to 95% for from 2 weeks to 3 months, and the proportion of agglomerated sodium hydrogencarbonate crystal particles is determined to evaluate the caking tendency. A novel test method for evaluating the caking property of sodium hydrogencarbonate crystal particles, capable of providing results of the caking property test with high reproducibility, quantitatively with high versatility, can be provided.
    Type: Application
    Filed: January 3, 2007
    Publication date: May 10, 2007
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Hachirou HIRANO, Takako Hirano, Shintaro Kikuchi, Fumiaki Nakashima, Hisakazu Arima, Shigeru Sakurai
  • Publication number: 20070104635
    Abstract: Sodium hydrogencarbonate crystal particles, which comprise sodium hydrogencarbonate crystal particles having an average particle size of from 50 to 500 ?m based on the mass, and anhydrous sodium carbonate, and sodium carbonate monohydrate and/or Wegscheider's salt, present on the surface of the sodium hydrogencarbonate crystal particles in such amounts that the total content of anhydrous sodium carbonate, sodium carbonate monohydrate, Wegscheider's salt and sodium sesquicarbonate in the sodium hydrogencarbonate crystal particles is from 0.04 to 1 mass % as calculated as anhydrous sodium carbonate, anhydrous sodium carbonate accounts for at least 40 mass % of the total content, and sodium carbonate monohydrate and/or Wegscheider's salt accounts for from 5 to 60 mass % of the total content. Sodium hydrogencarbonate crystal particles having a low caking property, which are useful in the field of food products, pharmaceuticals, bath additives, etc.
    Type: Application
    Filed: January 3, 2007
    Publication date: May 10, 2007
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Hachirou Hirano, Takako Hirano, Shintaro Kikuchi, Fumiaki Nakashima, Hisakazu Arima, Shigeru Sakurai
  • Patent number: 6630213
    Abstract: A process for producing a silica-alumina composite sol, which comprises mixing a silica hydrogel and an aluminum salt which, when dissolved in water, gives an acidic solution.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: October 7, 2003
    Assignee: Asahi Glass Company, Limited
    Inventors: Katsumasa Nakahara, Hisao Inokuma, Hachirou Hirano, Toshiya Matsubara, Masako Wakabayashi, Yoshinori Kon
  • Publication number: 20010008688
    Abstract: A process for producing a silica-alumina composite sol, which comprises mixing a silica hydrogel and an aluminum salt which, when dissolved in water, gives an acidic solution.
    Type: Application
    Filed: December 26, 2000
    Publication date: July 19, 2001
    Applicant: Asahi Glass Company, Limited
    Inventors: Katsumasa Nakahara, Hisao Inokuma, Hachirou Hirano, Toshiya Matsubara, Masako Wakabayashi, Yoshinori Kon
  • Patent number: 5756001
    Abstract: An alumina sol having an alumina solid content of at least 10 wt % and a viscosity of not higher than 5 Pa.s measured by a Brookfield viscometer and containing a cation other than a hydrogen ion in a total ion equivalent concentration in the range of from 2.0.times.10.sup.-4 to 1.0.times.10.sup.-1 N and a method of preparing the same.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: May 26, 1998
    Assignee: Asahi Glass Company Ltd.
    Inventors: Hiroo Mori, Hachirou Hirano, Masaharu Tanaka, Kunihiko Terase
  • Patent number: 5738718
    Abstract: A process for producing zinc oxide-containing spherical silica, which comprises emulsifying, in an organic solvent containing a surfactant, a dispersion having zinc oxide with a particle size of from 0.005 to 0.5 .mu.m dispersed in an aqueous alkali metal silicate solution in an amount of from 10 to 70 wt % based on the total amount of zinc oxide and SiO.sub.2 in the aqueous alkali metal silicate solution, followed by gelation of the resulting emulsion with carbon dioxide gas.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: April 14, 1998
    Assignee: Asahi Glass Company Ltd.
    Inventors: Hiroo Mori, Hiroshi Funaki, Kunihiko Terase, Hachirou Hirano